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US4229491A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing cadmium stannate layers

Assignee: Schott AG
•
Filing: 1978-12-13
•
Granted: 1980-10-21
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Expires: 1998-12-13
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Abstract

Abstract A dipping process for the production of cadmium stannate layers on a substrate, preferably glass, which comprises: (a) dipping said substrate into an alcoholic solution of a reaction product containing cadmium and tin, said solution consisting essentially of compounds having hydrolyzable and pyrolyzable residues; (b) withdrawing the substrate from said solution in a humid atmosphere; and (c) gradually heating the coated substrate to 650° C., whereby hydrolysis and pyrolysis removes said residues from the coated substrate to form a coated substrate in which the molar ratio Cd:Sn corresponds to that of said alcoholic dipping solution.

Inventors

  • 👤 Helmut Dislich
  • 👤 Paul Hinz
  • 👤 Gunther Wolf

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 13:43
CPC Classifications
C; C01; C01G; C01G19/00; C03; C03C; C03C17/00; C03C17/22; C03C17/23; C03C17/25; C03C17/253; C03C2217/00; C03C2217/20; C03C2217/21; C03C2217/23; C03C2217/232; C03C2217/24; C03C2218/00; C03C2218/10; C03C2218/11; C03C2218/111

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 110 words
In a dipping process for the production of cadmium stannate layers on a substrate, the improvement which comprises: (a) dipping said substrate into an alcoholic solution of a reaction product containing cadmium and tin derived from a cadmium compound and a tin compound, said solution consisting essentially of compounds having hydrolyzable and pyrolyzable residues; (b) withdrawing the substrate from said solution in an atmosphere sufficiently humid for the subsequent hydrolysis; and (c) gradually heating the coated substrate to 650° C., whereby hydrolysis and pyrolysis removes said residues from the coated substrate to form a coated substrate in which the molar ratio Cd:Sn corresponds to that of said alcoholic dipping solution.
Claim 2
Dependent Claim 110 words
In a dipping process for the production of cadmium stannate layers on a substrate, the improvement which comprises: (a) dipping said substrate into an alcoholic solution of a reaction product containing cadmium and tin derived from a cadmium compound and a tin compound, said solution consisting essentially of compounds having hydrolyzable and pyrolyzable residues; (b) withdrawing the substrate from said solution in an atmosphere sufficiently humid for the subsequent hydrolysis; and (c) gradually heating the coated substrate to 650° C., whereby hydrolysis and pyrolysis removes said residues from the coated substrate to form a coated substrate in which the molar ratio Cd:Sn corresponds to that of said alcoholic dipping solution.
Claim 3
Dependent Claim 13 words
A process according to claim 1, wherein said hydrolyzable groups are alkanol residues.
Claim 4
Dependent Claim 24 words
A process according to claim 2, wherein said alkanol residues are selected from the group consisting of methoxy, ethoxy, propoxy, butoxy and mixtures thereof.
Claim 5
Dependent Claim 25 words
A process according to claim 2, wherein the pyrolyzable residues are selected from the group consisting of formate, acetate, propionate or higher carboxylic acid residues.
Claim 6
Dependent Claim 34 words
A process according to one of claims 2 to 4, wherein said dipping solution further contains an additive selected from the group consisting of hydrolyzable or pyrolyzable indium, lead, aluminium, titanium or niobium compounds.
Claim 7
Dependent Claim 17 words
A process according to claim 5 wherein the molar ratio of Cd:Sn in the layer is 1:1.
Claim 8
Dependent Claim 17 words
A process according to claim 5 wherein the molar ratio of Cd:Sn in the layer is 2:1.
Claim 9
Dependent Claim 21 words
A process according to one of claims 1 to 4, wherein the molar ratio of Cd:Sn in the layer is 1:1.
Claim 10
Dependent Claim 21 words
A process according to one of claims 1 to 4, wherein the molar ratio of Cd:Sn in the layer is 2:1.

References Cited (Backward Citations)

US3811953A Cited
US4048372A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-21 1984-04-21 1984-10-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-21 1988-04-21 1988-10-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-21 1992-04-21 1992-10-21 $7700.00 Window Closed / Lapsed

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