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US4228254A Expired / Lapsed US ⏱️ 0.0 years remaining

Functional group containing cyclic diolefin butyl rubbers

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1978-08-07
•
Granted: 1980-10-14
•
Expires: 1998-08-07
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Abstract

Abstract Isobutylene-based elastomers containing 3-15 mol percent enchained cyclic diolefin such as cyclopentadiene, and other comonomers such as isoprene, piperylene and butadiene to allow for chemical modification with anhydride, carboxy, hydroxy, etc. to produce a one package through cure system.

Inventors

  • 👤 Kenneth W. Powers
  • 👤 Robert Roper
  • 👤 Martin L. Gorbaty

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 00:56
CPC Classifications
C; C08; C08F; C08F8/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 108 words
A tack-free, air dryable, self-curing elastomeric terpolymer coating having a viscosity average molecular weight of about 15,000 to 80,000 which consists essentially of about 85 to 95 mol % isobutylene, about 5 to 9 mol % C 5 -C 12 cyclic diolefin and about 0.5 to 5 mol % conjugated diolefin represented by the formula ##STR6## where each R is are independently hydrogen or acyclic or alicyclic hydrocarbon radicals having from 1 to 12 carbon atoms and wherein the terpolymer has attached thereto a functional group selected from the group consisting of anhydride, carboxy or hydroxy said coating being self-curing through surface oxidative crosslinking of said cyclic diolefin.
Claim 2
Dependent Claim 108 words
A tack-free, air dryable, self-curing elastomeric terpolymer coating having a viscosity average molecular weight of about 15,000 to 80,000 which consists essentially of about 85 to 95 mol % isobutylene, about 5 to 9 mol % C 5 -C 12 cyclic diolefin and about 0.5 to 5 mol % conjugated diolefin represented by the formula ##STR6## where each R is are independently hydrogen or acyclic or alicyclic hydrocarbon radicals having from 1 to 12 carbon atoms and wherein the terpolymer has attached thereto a functional group selected from the group consisting of anhydride, carboxy or hydroxy said coating being self-curing through surface oxidative crosslinking of said cyclic diolefin.
Claim 3
Dependent Claim 11 words
The composition of claim 1 wherein the cyclic diolefin is cyclopentadiene.
Claim 4
Dependent Claim 25 words
The composition of claim 1 wherein the cyclic diolefin is a mono or polyalkylated cyclopentadiene wherein each alkyl group contains less than 6 carbon atoms.
Claim 5
Dependent Claim 24 words
The composition of claim 2 wherein the mono or polyalkylated cyclopentadiene is selected from the group consisting of methyl cyclopentadiene, ethyl cyclopentadiene and 1,3-dimethylcyclopentadiene.
Claim 6
Dependent Claim 20 words
The composition of claim 1 wherein the conjugated diolefin is selected from the group consisting of isoprene, butadiene and piperylene.
Claim 7
Dependent Claim 11 words
The composition of claim 1 wherein the cyclic diolefin is cyclopentadiene.
Claim 8
Dependent Claim 11 words
The composition of claim 6 wherein the functional groups are anhydride.

References Cited (Backward Citations)

GB1062266A Cited
FR1396141A Cited
US3808177A Cited
US3856763A Cited
US3928297A Cited
US4151343A Cited
US3954912A Cited
US4031300A Cited
US4145490A Cited
US4153773A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-14 1984-04-14 1984-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-14 1988-04-14 1988-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-14 1992-04-14 1992-10-14 $7700.00 Window Closed / Lapsed

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