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US4228055A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous coating compositions containing flatting agents and low molecular weight polyethers

Assignee: PPG Industries Inc
•
Filing: 1978-09-06
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Granted: 1980-10-14
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Expires: 1998-09-06
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Abstract

Abstract Aqueous coating compositions consist essentially of: (a) a water-insoluble film-forming polymeric resin; (b) water-insoluble agglomerated particulate beads of urea, melamine or phenol and formaldehyde; (c) polyethers having the formula H(OC.sub.x H.sub.2x).sub.n OH where x is from 2 to 4 and n is a number such that the polyether has a weight average molecular weight of from about 200 to about 1000; (d) pigments; and (e) water. The aqueous coating compositions are especially useful for imparting to metal coil a low gloss pigmented protective finish having good metal marking resistance.

Inventors

  • 👤 David R. Wallace

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 19:16
CPC Classifications
C; C09; C09D; C09D157/00; C09D7/00; C09D7/40; C09D7/42; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31688

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 211 words
An aqueous coating composition useful for imparting to metal coil a low gloss pigmented protective finish having good metal marking resistance, said composition consisting essentially of: (a) from about 10 percent to about 50 percent of a water-insoluble film-forming acrylic resin, vinyl resin or mixture thereof; (b) from about 0.5 percent to about 7 percent of flatting agent, said agent being water-insoluble agglomerated particulate beads having a gross particle diameter of from about 1 micron to about 60 microns, wherein said beads consist essentially of the reaction product of urea, melamine or phenol and formaldehyde having a molar ratio of the urea to the formaldehyde of from about 1:1 to about 6:1, a molar ratio of the melamine to the formaldehyde of from about 1:1 to about 1:4, and a molar ratio of the phenol to the formaldehyde of from about 1:1 to about 1:3; (c) from about 0.5 percent to about 7 percent of polyether having the formula H(OC x H 2x ) n OH, wherein x is from 2 to 4 and n is a number such that the polyether has a weight average molecular weight of from about 300 to about 700; (d) from about 5 percent to about 40 percent of pigment; and (e) the balance water.
Claim 2
Dependent Claim 211 words
An aqueous coating composition useful for imparting to metal coil a low gloss pigmented protective finish having good metal marking resistance, said composition consisting essentially of: (a) from about 10 percent to about 50 percent of a water-insoluble film-forming acrylic resin, vinyl resin or mixture thereof; (b) from about 0.5 percent to about 7 percent of flatting agent, said agent being water-insoluble agglomerated particulate beads having a gross particle diameter of from about 1 micron to about 60 microns, wherein said beads consist essentially of the reaction product of urea, melamine or phenol and formaldehyde having a molar ratio of the urea to the formaldehyde of from about 1:1 to about 6:1, a molar ratio of the melamine to the formaldehyde of from about 1:1 to about 1:4, and a molar ratio of the phenol to the formaldehyde of from about 1:1 to about 1:3; (c) from about 0.5 percent to about 7 percent of polyether having the formula H(OC x H 2x ) n OH, wherein x is from 2 to 4 and n is a number such that the polyether has a weight average molecular weight of from about 300 to about 700; (d) from about 5 percent to about 40 percent of pigment; and (e) the balance water.
Claim 3
Dependent Claim 25 words
The aqueous coating composition of claim 1, wherein the film-forming resin is an acrylic resin having a particle diameter of less than about 1 micron.
Claim 4
Dependent Claim 14 words
The aqueous coating composition of claim 2 wherein the polyether is a polyethylene glycol.
Claim 5
Dependent Claim 14 words
The aqueous coating composition of claim 2, wherein the polyether is a polypropylene glycol.
Claim 6
Dependent Claim 14 words
The aqueous coating composition of claim 2, wherein the polyether is a polytetramethylene glycol.
Claim 7
Dependent Claim 19 words
The aqueous coating composition of claim 1, wherein the flatting agent is the reaction product of urea and formaldehyde.
Claim 8
Dependent Claim 24 words
The aqueous coating composition of claim 6, wherein the molar ratio of the urea to the formaldehyde is from about 2:1 to about 4:1.
Claim 9
Dependent Claim 19 words
The aqueous coating composition of claim 1, wherein the flatting agent is the reaction product of melamine and formaldehyde.
Claim 10
Dependent Claim 24 words
The aqueous coating composition of claim 8, wherein the molar ratio of the melamine to the formaldehyde is from about 1:2 to about 1:3.
Claim 11
Dependent Claim 19 words
The aqueous coating composition of claim 1, wherein the flatting agent is the reaction product of phenol and formaldehyde.
Claim 12
Dependent Claim 24 words
The aqueous coating composition of claim 10 wherein the molar ratio of the phenol to the formaldehyde is from about 1:2 to about 1:3.
Claim 13
Dependent Claim 27 words
The aqueous coating composition of claims 7, 9 or 11 wherein the gross particle diameter of the beads is from about 5 microns to about 35 microns.
Claim 14
Dependent Claim 65 words
The aqueous coating composition of claim 2 consisting essentially of: (a) from about 20 percent to about 35 percent of the film-forming resin; (b) from about 1 percent to about 4 percent of the flatting agent; (c) from about 1 percent to about 3 percent of the polyether; (d) from about 15 percent to about 25 percent of the pigment; and (e) the balance water.

References Cited (Backward Citations)

US3627713A Cited
US3839253A Cited
US3959202A Cited
US4062821A Cited
US3943080A Cited
US3928272A Cited
US4137205A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-14 1984-04-14 1984-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-14 1988-04-14 1988-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-14 1992-04-14 1992-10-14 $7700.00 Window Closed / Lapsed

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