US4228055A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Aqueous coating compositions containing flatting agents and low molecular weight polyethers
Assignee: PPG Industries Inc
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Filing: 1978-09-06
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Granted: 1980-10-14
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Expires: 1998-09-06
Abstract
Abstract Aqueous coating compositions consist essentially of: (a) a water-insoluble film-forming polymeric resin; (b) water-insoluble agglomerated particulate beads of urea, melamine or phenol and formaldehyde; (c) polyethers having the formula H(OC.sub.x H.sub.2x).sub.n OH where x is from 2 to 4 and n is a number such that the polyether has a weight average molecular weight of from about 200 to about 1000; (d) pigments; and (e) water. The aqueous coating compositions are especially useful for imparting to metal coil a low gloss pigmented protective finish having good metal marking resistance.
Inventors
- 👤 David R. Wallace
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 19:16
CPC Classifications
C; C09; C09D; C09D157/00; C09D7/00; C09D7/40; C09D7/42; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31688
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
211 words
An aqueous coating composition useful for imparting to metal coil a low gloss pigmented protective finish having good metal marking resistance, said composition consisting essentially of: (a) from about 10 percent to about 50 percent of a water-insoluble film-forming acrylic resin, vinyl resin or mixture thereof; (b) from about 0.5 percent to about 7 percent of flatting agent, said agent being water-insoluble agglomerated particulate beads having a gross particle diameter of from about 1 micron to about 60 microns, wherein said beads consist essentially of the reaction product of urea, melamine or phenol and formaldehyde having a molar ratio of the urea to the formaldehyde of from about 1:1 to about 6:1, a molar ratio of the melamine to the formaldehyde of from about 1:1 to about 1:4, and a molar ratio of the phenol to the formaldehyde of from about 1:1 to about 1:3; (c) from about 0.5 percent to about 7 percent of polyether having the formula H(OC x H 2x ) n OH, wherein x is from 2 to 4 and n is a number such that the polyether has a weight average molecular weight of from about 300 to about 700; (d) from about 5 percent to about 40 percent of pigment; and (e) the balance water.
Claim 2
Dependent Claim
211 words
An aqueous coating composition useful for imparting to metal coil a low gloss pigmented protective finish having good metal marking resistance, said composition consisting essentially of: (a) from about 10 percent to about 50 percent of a water-insoluble film-forming acrylic resin, vinyl resin or mixture thereof; (b) from about 0.5 percent to about 7 percent of flatting agent, said agent being water-insoluble agglomerated particulate beads having a gross particle diameter of from about 1 micron to about 60 microns, wherein said beads consist essentially of the reaction product of urea, melamine or phenol and formaldehyde having a molar ratio of the urea to the formaldehyde of from about 1:1 to about 6:1, a molar ratio of the melamine to the formaldehyde of from about 1:1 to about 1:4, and a molar ratio of the phenol to the formaldehyde of from about 1:1 to about 1:3; (c) from about 0.5 percent to about 7 percent of polyether having the formula H(OC x H 2x ) n OH, wherein x is from 2 to 4 and n is a number such that the polyether has a weight average molecular weight of from about 300 to about 700; (d) from about 5 percent to about 40 percent of pigment; and (e) the balance water.
Claim 3
Dependent Claim
25 words
The aqueous coating composition of claim 1, wherein the film-forming resin is an acrylic resin having a particle diameter of less than about 1 micron.
Claim 4
Dependent Claim
14 words
The aqueous coating composition of claim 2 wherein the polyether is a polyethylene glycol.
Claim 5
Dependent Claim
14 words
The aqueous coating composition of claim 2, wherein the polyether is a polypropylene glycol.
Claim 6
Dependent Claim
14 words
The aqueous coating composition of claim 2, wherein the polyether is a polytetramethylene glycol.
Claim 7
Dependent Claim
19 words
The aqueous coating composition of claim 1, wherein the flatting agent is the reaction product of urea and formaldehyde.
Claim 8
Dependent Claim
24 words
The aqueous coating composition of claim 6, wherein the molar ratio of the urea to the formaldehyde is from about 2:1 to about 4:1.
Claim 9
Dependent Claim
19 words
The aqueous coating composition of claim 1, wherein the flatting agent is the reaction product of melamine and formaldehyde.
Claim 10
Dependent Claim
24 words
The aqueous coating composition of claim 8, wherein the molar ratio of the melamine to the formaldehyde is from about 1:2 to about 1:3.
Claim 11
Dependent Claim
19 words
The aqueous coating composition of claim 1, wherein the flatting agent is the reaction product of phenol and formaldehyde.
Claim 12
Dependent Claim
24 words
The aqueous coating composition of claim 10 wherein the molar ratio of the phenol to the formaldehyde is from about 1:2 to about 1:3.
Claim 13
Dependent Claim
27 words
The aqueous coating composition of claims 7, 9 or 11 wherein the gross particle diameter of the beads is from about 5 microns to about 35 microns.
Claim 14
Dependent Claim
65 words
The aqueous coating composition of claim 2 consisting essentially of: (a) from about 20 percent to about 35 percent of the film-forming resin; (b) from about 1 percent to about 4 percent of the flatting agent; (c) from about 1 percent to about 3 percent of the polyether; (d) from about 15 percent to about 25 percent of the pigment; and (e) the balance water.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-10-14 | 1984-04-14 | 1984-10-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-10-14 | 1988-04-14 | 1988-10-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-10-14 | 1992-04-14 | 1992-10-14 | $7700.00 | Window Closed / Lapsed |