Biodegradable cationic surface-active agents containing ester or amide and polyalkoxy group

Claim 2

A compound having the formula ##STR40## wherein each R 1 is C 1 to C 4 alkyl or hydroxyalkyl; each R 2 is either hydrogen or C 1 to C 3 alkyl; R 3 is C 4 to C 30 straight or branched chain alkyl or alkenyl; R 4 is C 1 to C 10 alkylene or alkenylene; n is from 2 to 4; y is from 1 to 20; a is 0 or 1, and t is 0 to 1, but t must be 1 when a is 1; m is from 1 to 5; Z 2 is selected from the group consisting of ##STR41## Z 1 is selected from the group consisting of ##STR42## said selections being made so that ##STR43## is an alkyl or alkenyl group which can be interrupted by only structures selected from the group consisting of: ##STR44## and wherein at least one of said Z 1 or Z 2 groups is selected from the group consisting of ester, reverse ester, amide, and reverse amide; and X is an anion which makes the surfactant at least water-dispersible.

Claim 3

The compound of claim 1 wherein Z 2 is selected from the group consisting of ester, reverse ester, amide and reverse amide.

Claim 4

The compound of claim 2 wherein Z 2 is selected from the group consisting of ester and reverse ester.

Claim 5

The compound of claim 2 wherein Z 2 is selected from the group consisting of amide and reverse amide.

Claim 6

The compound of claim 2 wherein n is 4 and R 2 is hydrogen.

Claim 7

The compound of claim 2 wherein n is 2 and the R 2 groups are CH 3 and hydrogen respectively.

Claim 8

The compound of claim 2 wherein n is 2 and R 2 is hydrogen.

Claim 9

The compound of claim 7 wherein y is from 1 to 10.

Claim 10

The compound of claim 8 wherein R 3 is C 8 to C 18 alkyl.

Claim 11

The compound of claim 7 wherein a is 1 and Z 1 is ##STR45##

Claim 12

The compound of claim 10 wherein t is 1 and R 4 is C 2 alkylene.

Claim 13

The compound of claim 7 wherein a is 0.

Claim 14

The compound of claim 12 wherein m is 2.

Claim 15

The compound of claim 13 wherein t is 1 and R 4 is methylene.

Claim 16

The compound of claim 14 wherein Z 2 is ##STR46##

Claim 17

The compound of claim 15 wherein y is from 1 to 10.

Claim 18

The compound of claim 16 wherein R 3 is C 8 to C 18 alkyl.

Claim 19

The compound of claim 17 wherein R 1 is CH 3 .

Claim 20

The compound of claim 18 wherein X is selected from the group consisting of halides, methyl sulfate, sulfate, and nitrate.

Claim 21

The compound of claim 19 wherein X is selected from the group consisting of chloride, bromide, iodide, sulfate and methyl sulfate.

Claim 22

The compound of claim 20 wherein y is 7.

Claim 23

The compound of claim 21 wherein R 3 is C 12 alkyl.

Claim 24

The compound of claim 7 wherein Z 2 is ##STR47##

Claim 25

The compound of claim 23 wherein y is from 1 to 10.

Claim 26

The compound of claim 24 wherein R 3 is C 8 to C 18 alkyl.

Claim 27

A detergent composition containing from 0 to about 20% of phosphate materials, and having a pH in the laundry solution of not greater than about 11, comprising from about 5 to about 100% of a surfactant mixture consisting essentially of (a) a biodegradable nonionic surfactant having the formula R(OC 2 H 4 ) n OH wherein R is a primary or secondary alkyl chain of from about 8 to about 22 carbon atoms and n is an average of from about 2 to about 12, having an HLB of from about 5 to about 17; and (b) the cationic surfactant of claim 1; said composition having a pH of at least about 6.5 in the aqueous laundry solution, and wherein the ratio of said nonionic to said cationic component is in the range of from about 1:1 to about 100:1.

Claim 28

The composition of claim 26 wherein, in the cationic surfactant, Z 2 is selected from the group consisting of ester, reverse ester, amide, and reverse amide.

Claim 29

The composition of claim 27 wherein the nonionic surfactant is selected from the group consisting of the condensation product of C 10 alcohol with 3 moles of ethylene oxide, the condensation product of coconut alcohol with 5 moles of ethylene oxide, the condensation product of C 12 alcohol with 5 moles of ethylene oxide, the condensation product of C 12-13 alcohol with 3 moles of ethylene oxide, and the same product which is stripped to remove substantially all lower ethoxylate and nonethoxylate fractins, the condensation product of C 12-13 alcohol with 6.5 moles of ethylene oxide, the condensation product of C 12-13 alcohol with 9 moles of ethylene oxide, the condensation product of C 14-15 alcohol with 3 moles of ethylene oxide, the condensation product of C 14-15 alcohol with 4 moles of ethylene oxide, the condensation product of C 14-15 alcohol with 7 moles of ethylene oxide, the condensation product of C 14-15 alcohol with 9 moles of ethylene oxide, and mixtures thereof.

Claim 30

The composition of claim 27 wherein, in the cationic surfactant, Z 2 is ##STR48##

Claim 31

The composition of claim 29 wherein, in the cationic surfactant, n is equal to 2 and R 2 is hydrogen.

Claim 32

The composition of claim 30, wherein, in the cationic surfactant, a is 0 and m is equal to 2.

Claim 33

The composition of claim 31 wherein, in the cationic sufactant, R 4 is methylene and t is equal to 1.

Claim 34

The composition of claim 32 wherein, in the cationic surfactant, y is from 1 to 10.

Claim 35

The composition of claim 33 wherein, in the cationic surfactant, y is from 1 to 10.

Claim 36

The composition of claim 34 wherein, in the cationic surfactant, R 1 is CH 3 .

Claim 37

The composition of claim 35 wherein, in the cationic surfactant, X is selected from the group consisting of chloride, bromide, iodide, methyl sulfate and sulfate.

Claim 38

The composition of claim 36 wherein, in the nonionic surfactant, R is an alkyl chain of from about 10 to about 18 carbon atoms.

Claim 39

The composition of claim 37 wherein, in the cationic surfactant, y is equal to 7.

Claim 40

The composition of claim 38 wherein, in the cationic surfactant, R 3 is C 12 alkyl.

Claim 41

The composition of claim 27 wherein the ratio of nonionic surfactant to cationic surfactant is from about 1:1 to 5:1, and the reduced cationic monomer concentration of the nonionic/cationic surfactant mixture is from about 0.005 to about 0.2.

Claim 42

The composition of claim 36 wherein the ratio of nonionic surfactant to cationic surfactant is from about 1:1 to 5:1, and the reduced cationic monomer concentration of the nonionic/cationic surfactant mixture is from about 0.005 to about 0.2.

Claim 43

The composition of claim 40 wherein the ratio of nonionic surfactant to cationic surfactant is from about 5:3 to 5:1.

Claim 44

The composition of claim 42 which is substantially free of phosphate, polyphosphate, silicate, and polycarboxylate builder anions, carboxymethylcellulose, and anionic surfactants.

Claim 45

The composition of claim 40 which is substantially free of oily hydrocarbon materials.

Claim 46

The composition of claim 27 wherein the ratio of nonionic surfactant to cationic surfactant is from 5.1:1 to about 100:1, the nonionic/cationic surfactant mixture has a cloud point of from about 0° to about 95° C., and the reduced cationic monomer concentration of the nonionic/cationic surfactant mixture is from about 0.002 to about 0.2.

Claim 47

The composition of claim 36 wherein the ratio of nonionic surfactant to cationic surfactant is from 5.1:1 to about 100:1, the nonionic/cationic surfactant mixture has a cloud point of from about 0° to about 95° C., and the reduced cationic monomer concentration of the nonionic/cationic surfactant mixture is from about 0.002 to about 0.2.

Claim 48

The composition of claim 45 which additionally contains from about 1 to about 60% of a detergency builder salt.

Claim 49

The composition of claim 45 wherein said composition forms separated phases when added to water having a temperature of about 45° C., at a concentration of from about 0.01 to about 0.3%.

Claim 50

The composition of claim 45 wherein the ratio of nonionic surfactant to cationic surfactant is from 5.1:1 to about 50:1.

Claim 51

The composition of claim 26 which has a pH of greater than about 7 in the aqueous laundry solution.