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US4226742A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for the hydroconversion of heavy hydrocarbons

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1978-07-14
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Granted: 1980-10-07
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Expires: 1998-07-14
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Abstract

Abstract A catalytic hydroconversion process for a hydrocarbonaceous oil is effected by dissolving an oil-soluble metal compound in the oil, converting the compound to a solid, non-colloidal catalyst within the oil and reacting the oil containing the catalyst with hydrogen. Preferred compounds are molybdenum compounds.

Inventors

  • 👤 Roby Bearden, Jr.
  • 👤 Clyde L. Aldridge

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 16:53
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/16; B01J23/24; B01J23/28; C; C10; C10G; C10G2300/00; C10G2300/10; C10G2300/107

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 178 words
A catalyst prepared by the steps which comprise: (a) adding to a heavy hydrocarbon oil chargestock an oil-soluble metal compound in an amount ranging from about 10 to about 950 weight parts per million, calculated as the elemental metal, based on said oil chargestock, said metal being selected from the group consisting of Groups IVB, VB, VIB, VIIB, and VIII of the Periodic Table of Elements and mixtures thereof; (b) converting said oil-soluble metal compound within said chargestock in the presence of a hydrogen-containing gas by heating said oil to produce a solid, non-colloidal catalyst within said chargestock, said catalyst comprising from about 10 to about 950 wppm of said metal, calculated as the elemental metal, based on said chargestock; (c) reacting the chargestock containing said catalyst with hydrogen under hydroconversion conditions, including a temperature ranging from about 426° C. to about 482° C. in a hydroconversion zone to produce a hydroconversion zone effluent comprising a hydroconverted oil and catalytic solids; (d) separating said catalytic solids from said hydroconversion zone effluent, and (e) recovering the separated catalytic solids.
Claim 2
Dependent Claim 178 words
A catalyst prepared by the steps which comprise: (a) adding to a heavy hydrocarbon oil chargestock an oil-soluble metal compound in an amount ranging from about 10 to about 950 weight parts per million, calculated as the elemental metal, based on said oil chargestock, said metal being selected from the group consisting of Groups IVB, VB, VIB, VIIB, and VIII of the Periodic Table of Elements and mixtures thereof; (b) converting said oil-soluble metal compound within said chargestock in the presence of a hydrogen-containing gas by heating said oil to produce a solid, non-colloidal catalyst within said chargestock, said catalyst comprising from about 10 to about 950 wppm of said metal, calculated as the elemental metal, based on said chargestock; (c) reacting the chargestock containing said catalyst with hydrogen under hydroconversion conditions, including a temperature ranging from about 426° C. to about 482° C. in a hydroconversion zone to produce a hydroconversion zone effluent comprising a hydroconverted oil and catalytic solids; (d) separating said catalytic solids from said hydroconversion zone effluent, and (e) recovering the separated catalytic solids.
Claim 3
Dependent Claim 25 words
The catalyst of claim 1 wherein said catalytic solids recovered in step (e) comprises solid particles having a size greater than 0.5 micron in diameter.
Claim 4
Dependent Claim 27 words
The catalyst of claim 1 wherein said oil-soluble metal compound of step (a) is selected from the group consisting of chromium compounds, molybdenum compounds and vanadium compounds.
Claim 5
Dependent Claim 62 words
The catalyst of claim 1 wherein said oil soluble metal compound is converted to said catalyst of step (a) by first heating the oil chargestock containing the added metal compound to a temperature ranging from about 325° C. to about 415° C. in the presence of a hydrogen-containing gas and subsequently reacting the oil containing said catalyst with hydrogen under hydroconversion conditions.
Claim 6
Dependent Claim 28 words
The catalyst of claim 4 wherein said oil soluble metal compound is converted to said solid catalyst in the presence of a gas containing hydrogen and hydrogen sulfide.
Claim 7
Dependent Claim 16 words
The catalyst of claim 1 wherein said oil soluble compound is a salt of naphthenic acid.
Claim 8
Dependent Claim 48 words
The catalyst of claim 1 wherein said oil soluble metal compound is added to said oil chargestock in an amount ranging from about 50 to about 200 wppm, calculated as the elemental metal, based on said oil chargestock, and wherein said oil soluble metal compound is phosphomolybdic acid.

References Cited (Backward Citations)

US1876270A Cited
US2091831A Cited
US3131142A Cited
US3161584A Cited
US3331769A Cited
US3657111A Cited
US4125455A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-07 1984-04-07 1984-10-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-07 1988-04-07 1988-10-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-07 1992-04-07 1992-10-07 $7700.00 Window Closed / Lapsed

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