US4224216A
Expired / Lapsed
US
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Polypropylene/glass fiber/imide/thermoplastic elastomer based compositions
Assignee: Rhone Poulenc Industries SA
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Filing: 1978-11-17
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Granted: 1980-09-23
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Expires: 1998-11-17
Abstract
Abstract A molding composition is comprised of (A) polypropylene, (B) glass fibers, (C) an unsaturated dicarboxylic acid imide, and (D) a thermoplastic elastomer, and is useful for the fabrication of a variety of shaped articles, especially for the automotive industry [e.g., radiators, battery casings, fans, etc.].
Inventors
- 👤 Jean-Louis Locatelli
- 👤 Louis Macabrey
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 20:45
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/16; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K7/00; C08K7/02; C08K7/04; C08K7/14; C08L23/10; C08L23/12; C08L23/14; C08L23/142; C08L53/00; C08L2205/00; C08L2205/02; C08L2205/03; C08L2314/00; C08L2314/02; C08L79/00; C08L79/04; C08L79/08
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
22 words
A composition of matter, comprising (A) polypropylene, (B) an unsaturated dicarboxylic acid imide, (C) glass fibers, and (D) a thermoplastic ethylene elastomer.
Claim 2
Dependent Claim
22 words
A composition of matter, comprising (A) polypropylene, (B) an unsaturated dicarboxylic acid imide, (C) glass fibers, and (D) a thermoplastic ethylene elastomer.
Claim 3
Dependent Claim
63 words
The composition of matter as defined by claim 1, wherein the amount of polypropylene (A) constitutes 30 to 99% by weight of the total weight of the mixture of polypropylene (A) and elastomer (D), and wherein the amount of imide (B) constitutes 0.01 to 10% by weight of the total weight of the mixture of polypropylene (A), elastomer (D) and glass fibers (C).
Claim 4
Dependent Claim
33 words
The composition of matter as defined by claim 2, wherein the polypropylene is a crystalline polypropylene, being at least 50% by weight isotactic and having a molecular weight of from 250,000 to 700,000.
Claim 5
Dependent Claim
47 words
The composition of matter as defined by claim 3, wherein the thermoplastic elastomer is a copolymer based on ethylene and at least one other olefinically unsaturated comonomer copolymerizable therewith, having an essentially amorphous structure, and having a MOONEY ML--4 viscosity between 20 and 120 at 121° C.
Claim 6
Dependent Claim
26 words
The composition of matter as defined by claim 4, wherein the elastomer is an ethylene/propylene copolymer containing 40 to 80% by weight of recurring ethylene units.
Claim 7
Dependent Claim
33 words
The composition of matter as defined by claim 4, wherein the elastomer is a terpolymer of ethylene, propylene and a comonomer selected from the group comprising unsaturated carboxylic acids or nonconjugated aliphatic dienes.
Claim 8
Dependent Claim
58 words
The composition of matter as defined by claim 4, wherein the imide (B) comprises n recurring units of the structural formula: ##STR9## wherein n represents an average value of from 1.2 to 5 and G is one of the radicals: ##STR10## wherein Y represents H, CH 3 or Cl and z is equal to 0, 1 or 2.
Claim 9
Dependent Claim
43 words
The composition of matter as defined by claims 4 or 7, wherein the imide (B) is selected from the group comprising bis-imides, polyimides containing 3 to 5 imide groups, mixtures of bis- and/or polyimides with mono-imides, and macromolecular compounds comprising bis-polyimide reaction products.
Claim 10
Dependent Claim
31 words
The composition of matter as defined by claim 8, wherein the imide (B) is a macromolecular compound reaction product of a bis- and/or polyimide with a polyamine, N-vinyl-2-pyrrolidone or a polyisocyanate.
Claim 11
Dependent Claim
26 words
The composition of matter as defined by claim 4, wherein the glass fibers (C) are of Type E and have lengths between 100μ and 12 mm.
Claim 12
Dependent Claim
16 words
The composition of matter as defined by claim 10, wherein the glass fibers (C) are bundled.
Claim 13
Dependent Claim
41 words
The composition of matter as defined by claim 11, wherein the glass fibers (C) are bundled by means of a binder selected from the group consisting of polyvinyl acetate, copolymers of ethylene and acrylic esters, epoxy resins, polyethers and aromatic polyesters.
Claim 14
Dependent Claim
23 words
The composition of matter as defined by claim 10, wherein the glass fibers (C) have been treated with a sizing or coupling agent.
Claim 15
Dependent Claim
28 words
The composition of matter as defined by claim 13, wherein the sizing or coupling agent is selected from the group consisting of aminosilanes, vinylsilanes and complexes of chromium.
Claim 16
Dependent Claim
13 words
A shaped article comprising the composition of matter as defined by claim 1.
Claim 17
Dependent Claim
14 words
A molded shaped article comprising the composition of matter as defined by claim 1.
Claim 18
Dependent Claim
98 words
The composition of matter as defined by claim 4, wherein the imide (B) is a bis-imide having the structural formula: ##STR11## wherein R is selected from the group consisting of a linear or branched chain alkylene radical containing up to 13 carbon atoms; cyclohexylene; cyclopentylene; a member selected from the group consisting of ##STR12## wherein s is equal to 1, 2 or 3; and a member comprising two phenylene radicals linked together by a member selected from the group consisting of a valence bond, --CH 2 --, --O--, --C(CH 3 ) 2 --, --SO 2 -- and --S--.
Claim 19
Dependent Claim
28 words
The composition of matter as defined by claim 17, wherein the bis-imide is selected from the group consisting of N,N'-ethylene-bis-maleimide; N,N'-metaphenylene-bis-maleimide; N,N'-paraphenylene-bis-maleimide; N,N',4,4'-diphenylmethane-bis-maleimide; N,N',4,4'-diphenylether-bis-maleimide; N,N',4,4'-diphenylsulfone-bis-maleimide; N,N',4,4'-diphenylmethane-bis-tetrahydrophthalimide; and N,N',4,4'-diphenylmethane-bis-chloromaleimide.
References Cited (Backward Citations)
US3853808A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-23 | 1984-03-24 | 1984-09-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-23 | 1988-03-24 | 1988-09-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-23 | 1992-03-24 | 1992-09-23 | $7700.00 | Window Closed / Lapsed |