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US4223078A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithium electric cell

Assignee: Alcatel Lucent SAS
•
Filing: 1979-03-26
•
Granted: 1980-09-16
•
Expires: 1999-03-26
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Abstract

Abstract A lithium electric cell. Said electric cell includes a positive electrode (1) and a negative electrode (2) in contact with a liquid electrolyte impregnates in a separator (3). The positive electrode comprising an active compound whose general formula is Li x Fe 2 S z with x lying between 0 and 2, and z being not less than 3.

Inventors

  • 👤 Michel Armand
  • 👤 Raymond Brec
  • 👤 Alain Le Mehaute

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 09:50
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/58; H01M4/581; C; C01; C01P; C01P2002/00; C01P2002/70; C01P2002/72; C01P2006/00; C01P2006/40; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 55 words
A electric cell which includes a positive electrode and a negative electrode in contact with a liquid electrolyte, said positive electrode including an active ternary compound of lithium, iron and sulfur whose general formula is Li x Fe 2 S z with x being not more than 2, and z being not less than 3.
Claim 2
Dependent Claim 55 words
A electric cell which includes a positive electrode and a negative electrode in contact with a liquid electrolyte, said positive electrode including an active ternary compound of lithium, iron and sulfur whose general formula is Li x Fe 2 S z with x being not more than 2, and z being not less than 3.
Claim 3
Dependent Claim 19 words
An electric cell according to claim 1, wherein said active compound is Li 2 Fe 2 S z .
Claim 4
Dependent Claim 19 words
An electric cell according to claim 2, wherein said active compound is Li 2 Fe 2 S 3 .
Claim 5
Dependent Claim 26 words
An electric cell according to any of claim 1, claim 2 or claim 3, wherein said positive electrode further includes carbon, graphite, copper, nickel or iron.
Claim 6
Dependent Claim 20 words
An electric cell according to claim 1, claim 2 or claim 3, wherein the negative electrode comprises an alkali metal.
Claim 7
Dependent Claim 21 words
An electric cell according to claim 1, wherein said electrolyte includes an organic solvent in which a lithium salt is dissolved.
Claim 8
Dependent Claim 27 words
An electric cell according to claim 6, wherein said organic solvent is chosen from the group consisting of propylene carbonate, dioxolane, dimethyloxyethane, nitromethane, tetrahydrofurane and cyclic esters.
Claim 9
Dependent Claim 25 words
An electric cell according to claim 6, wherein that said salt is chosen from the group consisting of perchlorates, hexafluoroborates, hexafluoroarseniates, nitrates, sulphates and methylchlorosulfonates.
Claim 10
Dependent Claim 52 words
An electric cell according to claim 1, claim 2, or claim 3, wherein that the positive active compound is prepared by successively: mixing a carbonate of lithium and an oxide or iron; and heating the mixture to a temperature which lies between 200° and 1000° C. in a flow of inert gas;
Claim 11
Dependent Claim 27 words
An electric cell according to any of claim 1, claim 2 or claim 3, wherein said positive electrode further includes a transition element of the periodic table.
Claim 12
Dependent Claim 18 words
An electric cell according to claim 1, claim 2 or claim 3 wherein the negative electrode comprises lithium.
Claim 13
Dependent Claim 64 words
An electric cell according to claim 1, claim 2 or claim 3, wherein that the positive active compound is prepared by successively: mixing a carbonate of lithium and an oxide of iron; and heating the mixture to a temperature which lies between 200° and 1000° C. in a flow of inert gas, said inert gas being argon containing a compound of carbon and sulphur.
Claim 14
Dependent Claim 21 words
An electric cell according to claim 2, wherein said electrolyte includes an organic solvent in which a lithium salt is dissolved.
Claim 15
Dependent Claim 27 words
An electric cell according to claim 13, wherein said organic solvent is chosen from the group consisting of propylene carbonate, dioxolane, dimethyloxyethane, nitromethane, tetrahydrofurane and cyclic esters.
Claim 16
Dependent Claim 25 words
An electric cell according to claim 13, wherein that said salt is chosen from the group consisting of perchlorates, hexafluoroborates, hexafluoroarseniates, nitrates, sulphates and methylchlorosulfonates.
Claim 17
Dependent Claim 21 words
An electric cell according to claim 3, wherein said electrolyte includes an organic solvent in which a lithium salt is dissolved.
Claim 18
Dependent Claim 27 words
An electric cell according to claim 16, wherein said organic solvent is chosen from the group consisting of propylene carbonate, dioxolane, dimethyloxyethane, nitromethane, tetrahydrofurane and cyclic esters.

References Cited (Backward Citations)

US4049879A Cited
US4125687A Cited
US4143217A Cited
US4144383A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-16 1984-03-17 1984-09-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-16 1988-03-17 1988-09-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-16 1992-03-17 1992-09-16 $7700.00 Window Closed / Lapsed

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