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Semiconductive and sensitized photoconductive compositions

Assignee: 3M Co
•
Filing: 1978-11-03
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Granted: 1980-09-16
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Expires: 1998-11-03
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Abstract

Abstract Semiconductive compositions are produced by the inclusion of a particular class of dyes into a polymeric binder. When the binder is an organic photoconductive binder, the dyes act as exceptionally good sensitizers for the photoconductive material.

Inventors

  • 👤 William A. Huffman
  • 👤 Stephen P. Birkeland
  • 👤 Kevin P. O'Leary

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 12:47
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0601; G03G5/0605; G03G5/0607; G03G5/0609; H; H10; H10K; H10K30/00; H10K30/30; H10K85/00; H10K85/10; H10K85/111; H10K85/141; H10K85/146; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/549

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 91 words
A semiconductive composition comprising an organic polymeric binder of high dielectric strength and a dye comprising at least two quinoid benzene rings linked through a bridging moiety selected from the class of cycloproprane, cyclobutane and ═C═C═ n wherein n is 1 or 2, and wherein any ring carbons of the cyclopropane and cyclobutane bridging moieties not directly bonded to quinoid benzene rings are bonded to oxygen atoms to complete a carbonyl group wherein said dye is present in a concentration of at least 0.5×10 31 6 moles of dye/mole of binder.
Claim 2
Dependent Claim 91 words
A semiconductive composition comprising an organic polymeric binder of high dielectric strength and a dye comprising at least two quinoid benzene rings linked through a bridging moiety selected from the class of cycloproprane, cyclobutane and ═C═C═ n wherein n is 1 or 2, and wherein any ring carbons of the cyclopropane and cyclobutane bridging moieties not directly bonded to quinoid benzene rings are bonded to oxygen atoms to complete a carbonyl group wherein said dye is present in a concentration of at least 0.5×10 31 6 moles of dye/mole of binder.
Claim 3
Dependent Claim 27 words
The semiconductive composition of claim 1 wherein said organic polymeric material is selected from the class consisting of polyvinyl toluene, polystyrene, polyhalostyrene, polyacrylates, epoxy resins, and polycarbonates.
Claim 4
Dependent Claim 23 words
The semiconductive composition of claim 1 wherein the bridging moiety of the dye is selected from the group consisting of cyclopropane and cyclobutane.
Claim 5
Dependent Claim 30 words
The semiconductive composition of claim 1 wherein at least one quinoid benzene ring has at least one substituent in the ortho position which is no more electron withdrawing than chloro.
Claim 6
Dependent Claim 30 words
The semiconductive composition of claim 3 wherein at least one quinoid benzene ring has at least one substituent in the ortho position which is no more electron withdrawing than chloro.
Claim 7
Dependent Claim 61 words
The semiconductive composition of claim 1 wherein the dye is represented by any of the formulae: ##STR4## or A═C═C═.sub.n A wherein n is 1 or 2 A is a quinoid benzene ring which may have one or two substituents ortho to the quino oxygen which are no more electron withdrawing than chloro, and B is either A or an oxygen atom.
Claim 8
Dependent Claim 15 words
The semiconductive composition of claim 6 wherein the dye is selected from the formulae: ##STR5##
Claim 9
Dependent Claim 24 words
The semiconductive composition of claim 6 wherein said dye is present in a concentration of at least 0.5×10 -6 moles of dye/mole of binder.
Claim 10
Dependent Claim 24 words
The semiconductive composition of claim 7 wherein said dye is present in a concentration of at least 0.5×10 -6 moles of dye/mole of binder.

References Cited (Backward Citations)

US3037861A Cited
US3567450A Cited
US3552958A Cited
US4052209A Cited
US4134764A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-16 1984-03-17 1984-09-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-16 1988-03-17 1988-09-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-16 1992-03-17 1992-09-16 $7700.00 Window Closed / Lapsed

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