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US4221893A Expired / Lapsed US ⏱️ 0.0 years remaining

Brominated bisphenol-a epoxy compositions

Assignee: Adama Makhteshim Ltd
•
Filing: 1978-12-20
•
Granted: 1980-09-09
•
Expires: 1998-12-20
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Abstract

Abstract According to the present invention there are provided novel flame retardant brominated bisphenol epoxy compositions comprising the reaction product of the residue of the production of tetrabromo-bisphenol A (TBBA) with epichlorohydrin, and a process for the production of such compositions which comprises dissolving such residue in an excess of aqueous alkali, reacting the residue with epichlorohydrin at elevated temperature, neutralizing excess of alkali remaining after the reaction and recovering the brominated epoxy compositions. The compositions thus obtained are useful as flame retardants. There may be optionally incorporated in same compounds such as antimony trioxide.

Inventors

  • 👤 Meir Behar
  • 👤 Ori Peshes
  • 👤 Aharon Liebersohn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:43
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/30; C08L; C08L67/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 21 words
A flame retardant brominated bisphenol epoxy composition comprising the reaction product between the residue from the manufacture of tetrabromo-bisphenol-A with epichlorohydrin.
Claim 2
Dependent Claim 21 words
A flame retardant brominated bisphenol epoxy composition comprising the reaction product between the residue from the manufacture of tetrabromo-bisphenol-A with epichlorohydrin.
Claim 3
Dependent Claim 19 words
A composition according to claim 1 wherein the mole ratio of residue to epichlorohydrin is from 1:1 to 1:10.
Claim 4
Dependent Claim 42 words
A flame retardant brominated-bisphenol epoxy composition according to claim 1 comprising from 60% to 99% by weight of a reaction product between the residue from the manufacture of tetrabromo-bisphenol-A with epichlorohydrin and from 5% to 25% by weight of a crosslinking monomer.
Claim 5
Dependent Claim 19 words
A flame retardant brominated bisphenol epoxy composition according to claim 1 comprising 3% to 25% by weight antimony trioxide.
Claim 6
Dependent Claim 25 words
A flame retardant brominated-bisphenol epoxy composition according to claim 1 comprising 10 to 15% by weight antimony trioxide and 10 to 15% by weight styrene.
Claim 7
Dependent Claim 51 words
A process for preparing a flame retardant brominated bisphenol epoxy composition according to claim 1 which comprises dissolving the residue remaining after the production of tetrabromo-bisphenol-A in an excess of aqueous alkali, reacting this solution with epichlorohydrin at elevated temperature, neutralizing the excess of alkali and recovering the brominated epoxy composition.
Claim 8
Dependent Claim 25 words
A process according to claim 6 wherein the alkali is sodium hydroxide and the mole ratio of the residue to epichlorohydrin is 1:1 to 1:10.
Claim 9
Dependent Claim 50 words
A self extinguishing polyester resin composition comprising as flame retardant additive 10 to 35 parts by weight per hundred parts of resin of a brominated bisphenol epoxy composition, comprising the reaction product according to claim 1, being the reaction product of the residue of the manufacture of tetrabromo-bisphenol-A with epichlorohydrin.
Claim 10
Dependent Claim 24 words
A polyester resin composition according to claim 8 containing 1 to 10 parts by weight antimony trioxide per 100 parts by weight of resin.

References Cited (Backward Citations)

US2939859A Cited
US3016362A Cited
US3058946A Cited
US3182088A Cited
US3234289A Cited
US3546302A Cited
US3363007A Cited
GB1316415A Cited
US3929908A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-09 1984-03-10 1984-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-09 1988-03-10 1988-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-09 1992-03-10 1992-09-09 $7700.00 Window Closed / Lapsed

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