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US4218342A Expired / Lapsed US ⏱️ 0.0 years remaining

Composition for catalytic removal of hydrogen sulfide from gases

Assignee: Air Resources Inc
•
Filing: 1979-07-02
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Granted: 1980-08-19
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Expires: 1999-07-02
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Abstract

Abstract A composition for use in an oxidation-reduction process for effecting the catalytic oxidation of hydrogen sulfide gas comprising a water soluble ferric iron salt and at least two iron chelating agents, preferably as an alkaline aqueous chelated iron solution, with at least one of said iron chelating agents being an amine compound selected from the group consisting of polyamino polycarboxylic acids, polyamino alkyl polycarboxylic acids, polyamino hydroxyalkyl polycarboxylic acids, and poly(phosphonoalkyl) amines, and their alkali metal salts, such as the sodium salt of ethylenediamine tetraacetic acid, and another of said iron chelating agents being selected from the group of polyhydroxy compounds consisting of monosaccharides, disaccharides, reduced monosaccharides, reduced disaccharides, monosaccharide acids, disaccharide acids, and their alkali metal salts, such as sorbitol. An alkaline aqueous chelated iron solution is prepared by dissolving a water soluble ferric iron salt in water, adding to the solution the required amine-type and polyhydroxy-type iron chelating agents, and to this solution is added an alkaline material, such as sodium hydroxide or sodium carbonate, to provide a concentrate which can be diluted with water as required to obtain an operating solution having the desired pH and iron content for a selected process.

Inventors

  • 👤 Ralph B. Thompson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 23:46
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/14; B01D53/1493; B01D53/1456; B01D53/1468

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 110 words
A composition for use in an oxidation-reduction process for effecting the catalytic oxidation of hydrogen sulfide gas which comprises a water soluble ferric iron salt and at least two water soluble iron chelating agents with at least one of said iron chelating agents being selected from a group of amine chelating agents consisting of polyamino polycarboxylic acids, polyamino alkyl polycarboxylic acids, polyamino hydroxyalkyl polycarboxylic acids, and poly(phosphonoalkyl) amines, and their alkali metal salts, and at least one other of said iron chelating agents being selected from the group of polyhydroxy chelating agents consisting of monosaccharides, disaccharides, reduced monosaccharides, reduced disaccharides, monosaccharide acids, and disaccharide acids, and their alkali metal salts.
Claim 2
Dependent Claim 110 words
A composition for use in an oxidation-reduction process for effecting the catalytic oxidation of hydrogen sulfide gas which comprises a water soluble ferric iron salt and at least two water soluble iron chelating agents with at least one of said iron chelating agents being selected from a group of amine chelating agents consisting of polyamino polycarboxylic acids, polyamino alkyl polycarboxylic acids, polyamino hydroxyalkyl polycarboxylic acids, and poly(phosphonoalkyl) amines, and their alkali metal salts, and at least one other of said iron chelating agents being selected from the group of polyhydroxy chelating agents consisting of monosaccharides, disaccharides, reduced monosaccharides, reduced disaccharides, monosaccharide acids, and disaccharide acids, and their alkali metal salts.
Claim 3
Dependent Claim 23 words
A composition as in claim 1, wherein said ferric iron salt and said iron chelating agents are dissolved in an aqueous alkaline solution.
Claim 4
Dependent Claim 29 words
A composition as in claim 1 or 2, wherein said amine chelating agent is a mixture of the sodium salts of ethylenediamine tetra-acetic acid and N-hydroxy ethylenediamine tri-acetic acid.
Claim 5
Dependent Claim 17 words
A composition as in claim 1 or 2, wherein said amine chelating agent is a poly(phosphonoalkyl) amine.
Claim 6
Dependent Claim 15 words
A composition as in claim 1 or 2, wherein said polyhydroxy chelating agent is sorbitol.
Claim 7
Dependent Claim 15 words
A composition as in claim 1 or 2, wherein said polyhydroxy chelating agent is mannitol.
Claim 8
Dependent Claim 20 words
A composition as in claim 1 or 2, wherein said polyhydroxy chelating agent is a mixture comprising sodium-alpha-d-glucoheptonate and sodium-beta-d-glucoheptonate.
Claim 9
Dependent Claim 21 words
A composition as in claim 2, wherein said solution has an iron concentration ranging between about 5 ppm and 5000 ppm.
Claim 10
Dependent Claim 28 words
A composition as in claim 2, wherein said amine chelating agent and iron are present in said solution in a molar ratio ranging between about 0.5:1 and 2:1.
Claim 11
Dependent Claim 40 words
A composition as in claim 2, wherein said amine chelating agent and iron are present in said solution in a molar ratio of about 9.8:1 and the iron concentration of said solution is between about 5 ppm to 5000 ppm.
Claim 12
Dependent Claim 26 words
A composition as in claim 2, wherein said polyhydroxy chelating agent and iron are present in said solution in a molar ratio of at least 0.167:1.
Claim 13
Dependent Claim 40 words
A composition as in claim 2, wherein said polyhydroxy chelating agent and iron are present in said solution in a molar ratio of about 0.8:1 and the iron concentration of said solution is between about 5 ppm to 5000 ppm.
Claim 14
Dependent Claim 20 words
A composition as in claim 2, wherein said solution has a pH between about pH 8 and about pH 10.5.
Claim 15
Dependent Claim 61 words
A method of preparing an alkaline aqueous chelated iron solution for effecting the catalytic oxidation of hydrogen sulfide gas comprising, dissolving a water soluble ferric iron salt in water, adding to said solution at least one amine-type iron chelating agent and at least one polyhydroxy-type iron chelating agent as defined in claim 1, and adding to said solution an alkalizing material.

References Cited (Backward Citations)

US3068065A Cited
GB999799A Cited
US3496074A Cited
US3666446A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-08-19 1984-02-18 1984-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-08-19 1988-02-18 1988-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-08-19 1992-02-18 1992-08-19 $7700.00 Window Closed / Lapsed

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