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US4216163A Expired / Lapsed US ⏱️ 0.0 years remaining

N-Sulfo alkane amino alkane phosphoric acids and their alkali metal salts, and a process of producing same

Assignee: BK Giulini Chemie GmbH
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Filing: 1978-03-28
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Granted: 1980-08-05
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Expires: 1998-03-28
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Abstract

Abstract Novel and highly advantageous N-sulfo alkane amino alkane phosphonic acids and their alkali metal salts are provided. Said phosphonic acids are produced by reacting an alkali metal salt of an amino phosphonic acid with a halo, preferably chloro, or hydroxy alkane sulfonic acid or their alkali metal salts in an alkaline medium, while heating. In place of the halo and especially chloro or hydroxy alkane sulfonic acid reactants, there can also be used compounds which are capable of producing hydroxy alkane sulfonates such as carbylsulfate or aldehydes or, respectively, ethylene oxide with alkali metal bisulfites or metasulfites. The reaction is preferably carried out in a molar proportion of about 1:1 to about 1:2. The novel compounds are excellent complexing or sequestering agents especially with respect to polyvalent metal ions. They are highly resistant against hydrolysis and high temperatures and are of a very high water solubility.

Inventors

  • 👤 Klaus Sommer
  • 👤 Hermann Weber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 22:13
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/38; C07F9/3804; C07F9/3839; C07F9/3873; C02; C02F; C02F1/00; C02F1/68; C02F1/683; C02F5/00; C02F5/08; C02F5/10; C02F5/14

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 99 words
An N-sulfo alkane amino alkane phosphonic acid of the formula ##STR5## in which R 1 indicates hydrogen, alkyl with 1 to 11 carbon atoms, aryl, amino lower alkylene, or a lower alkylene phosphonic acid group; R 2 indicates the phosphonic acid group; R 3 indicates an alkylene sulfonic acid group of the formula C n H 2n SO 3 H; R 4 indicates hydrogen or an alkylene sulfonic acid group of the formula C n H 2n SO 3 H; and n indicates one of the numerals 1 to 11; and the alkali metal salts of said phosphonic acids.
Claim 2
Dependent Claim 99 words
An N-sulfo alkane amino alkane phosphonic acid of the formula ##STR5## in which R 1 indicates hydrogen, alkyl with 1 to 11 carbon atoms, aryl, amino lower alkylene, or a lower alkylene phosphonic acid group; R 2 indicates the phosphonic acid group; R 3 indicates an alkylene sulfonic acid group of the formula C n H 2n SO 3 H; R 4 indicates hydrogen or an alkylene sulfonic acid group of the formula C n H 2n SO 3 H; and n indicates one of the numerals 1 to 11; and the alkali metal salts of said phosphonic acids.
Claim 3
Dependent Claim 44 words
The N-sulfo alkane amino alkane sulfonic acid of claim 1, in which R 1 is hydrogen, R 2 is the phosphonic acid group; R 3 is the sulfo ethane group; and R 4 is hydrogen, said acid being N-sulfo ethane amino methane diphosphonic acid.
Claim 4
Dependent Claim 43 words
The N-sulfo alkane amino alkane phosphonic acid of claim 1, in which R 1 is hydrogen; R 2 is the phosphonic acid group; R 3 and R 4 are the sulfo ethane group, said acid being the N,N-bis-sulfo ethane amino methane diphosphonic acid.
Claim 5
Dependent Claim 44 words
The N-sulfo alkane amino alkane phosphonic acid of claim 1, in which R 1 is methyl; R 2 is the phosphonic acid group; R 3 is the sulfo ethane group; and R 4 is hydrogen, said acid being the N-sulfo ethane 1-amino ethane-1,1-diphosphonic acid.
Claim 6
Dependent Claim 44 words
The N-sulfo alkane amino alkane phosphonic acid of claim 1, in which R 1 is methyl; R 2 is the phosphonic acid group; R 3 is the sulfo butane group; and R 4 is hydrogen, said acid being the N-sulfo butane 1-amino ethane-1,1-diphosphonic acid.
Claim 7
Dependent Claim 43 words
The N-sulfo alkane amino alkane phosphonic acid of claim 1, in which R 1 is methyl; R 2 is the phosphonic acid group; R 3 is the sulfo octane group; R 4 is hydrogen, said acid being the N-sulfo octane 1-amino ethane-1,1-diphosphonic acid.
Claim 8
Dependent Claim 46 words
The N-sulfo alkane amino alkane phosphonic acid of claim 1, in which R 1 is the ethylene phosphonic acid group; R 2 is the phosphonic acid group; R 3 is the sulfo ethane group; and R 4 is hydrogen, said acid being the N-sulfo ethane-1-aminopropane-1,1,3-triphosphonic acid.
Claim 9
Dependent Claim 43 words
The N-sulfo alkane amino alkane phosphonic acid of claim 1, in which R 1 is ethyl; R 2 is the phosphonic acid group; R 3 is the sulfo propane group; and R 4 is hydrogen, said acid being the N-sulfo propane-1-amino propane-1,1-diphosphonic acid.
Claim 10
Dependent Claim 46 words
The N-sulfo alkane amino alkane phosphonic acid of claim 1, in which R 1 is phenyl, R 2 is the phosphonic acid group; R 3 is the sulfo ethane group; and R 4 is hydrogen, said acid being the N-sulfo ethane phenyl amino methane diphosphonic acid.
Claim 11
Dependent Claim 88 words
The sulfo alkane amino alkane phosphonic acid of the formula as given in claim 1, in which formula R 1 indicates hydrogen, methyl, ethyl, amino methylene, phenyl, or the ethylene phosphonic acid group; R 2 indicates the phosphonic acid group; R 3 indicates an alkylene sulfonic acid group of the formula C n H 2n SO 3 H, R 4 indicates hydrogen or an alkylene sulfonic acid group of the formula C n H 2n SO 3 H; and n indicates one of the numerals 1 to 11.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-08-05 1984-02-04 1984-08-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-08-05 1988-02-04 1988-08-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-08-05 1992-02-04 1992-08-05 $7700.00 Window Closed / Lapsed

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