US4215029A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Crosslinkable polymer coating compositions and process for preparing the same using tetrachloroethylene or 1,1,1-trichloroethylene solvent
Assignee: Dow Chemical Co
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Filing: 1978-11-02
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Granted: 1980-07-29
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Expires: 1998-11-02
Abstract
Abstract Lacquers of crosslinkable polymers are prepared by an improved process wherein a monomer composition of an olefinically unsaturated carboxylic acid, a hydroxyalkyl acrylate and at least one other monomer from the group of alkenyl aromatic monomers, alkyl acrylates or mixtures thereof is dissolved in tetrachloroethylene or 1,1,1-trichloroethane or mixtures thereof and caused to polymerize.
Inventors
- 👤 Frank L. Saunders
- 👤 Victor E. Meyer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 18:45
CPC Classifications
C; C08; C08F; C08F212/00; C08F212/02; C08F212/04; C08F212/06; C08F212/08; C08F220/00; C08F220/02; C08F220/10; C08F220/12; C08F220/16; C08F220/18; C08F220/1804; C08L; C08L2666/00; C08L2666/28; C08L2666/32; C09; C09D; C09D125/00; C09D125/02; C09D125/04; C09D125/08; C09D125/14; C09D133/00; C09D133/04; C09D133/06; C09D133/08
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
151 words
In the process for preparing a lacquer from crosslinkable polymers, the improvement wherein a monomer composition consisting essentially of (1) from about 1 to 15 weight percent of an alpha,beta-olefinically unsaturated carboxylic acid; (2) from about 10 to 25 weight percent of a hydroxyalkyl acrylate or methacrylate wherein the hydroxyalkyl group has from 2 to 4 carbon atoms in the alkyl group and; (3) the remainder needed to make 100 weight percent of at least one comonomer selected from the group consisting of an alkenyl aromatic monomer, an alkyl acrylate having from 1 to 8 carbon atoms in the alkyl group and mixtures thereof, is dissolved in tetrachloroethylene, 1,1,1-trichloroethane or mixtures thereof and subjected to thermal and catalytic inducement of free radical polymerization, and thereafter a crosslinking agent having at least 2 functional moieties reactive with the hydroxyalkyl groups or the carboxyl groups is dissolved in the solution of the interpolymer.
Claim 2
Dependent Claim
151 words
In the process for preparing a lacquer from crosslinkable polymers, the improvement wherein a monomer composition consisting essentially of (1) from about 1 to 15 weight percent of an alpha,beta-olefinically unsaturated carboxylic acid; (2) from about 10 to 25 weight percent of a hydroxyalkyl acrylate or methacrylate wherein the hydroxyalkyl group has from 2 to 4 carbon atoms in the alkyl group and; (3) the remainder needed to make 100 weight percent of at least one comonomer selected from the group consisting of an alkenyl aromatic monomer, an alkyl acrylate having from 1 to 8 carbon atoms in the alkyl group and mixtures thereof, is dissolved in tetrachloroethylene, 1,1,1-trichloroethane or mixtures thereof and subjected to thermal and catalytic inducement of free radical polymerization, and thereafter a crosslinking agent having at least 2 functional moieties reactive with the hydroxyalkyl groups or the carboxyl groups is dissolved in the solution of the interpolymer.
Claim 3
Dependent Claim
17 words
The process of claim 1 wherein said comonomer is a mixture of styrene and an alkyl acrylate.
Claim 4
Dependent Claim
34 words
The process of claim 2 wherein said styrene is from about 15 to 40 weight percent of the composition and said alkyl acrylate is from about 20 to 75 weight percent of the composition.
Claim 5
Dependent Claim
12 words
The process of claim 1 wherein said hydroxyalkyl acrylate is hydroxyethyl acrylate.
Claim 6
Dependent Claim
12 words
The process of claim 1 wherein said hydroxyalkyl acrylate is hydroxypropyl acrylate.
Claim 7
Dependent Claim
12 words
The process of claim 1 wherein said unsaturated acid is acrylic acid.
Claim 8
Dependent Claim
22 words
The process of claim 1 wherein the polymerizable monomers are dissolved in the solvent in an amount up to 60 weight percent.
Claim 9
Dependent Claim
15 words
The process of claim 1 wherein said crosslinking agent is an alkylated amino crosslinking agent.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-07-29 | 1984-01-28 | 1984-07-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-07-29 | 1988-01-28 | 1988-07-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-07-29 | 1992-01-28 | 1992-07-29 | $7700.00 | Window Closed / Lapsed |