US4214928A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Dimethyl hydantoin bonding agents in solid propellants
Assignee: United States Department of the Navy
•
Filing: 1976-11-29
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Granted: 1980-07-29
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Expires: 1996-11-29
Abstract
Abstract A dimethyl hydantoin bonding agent is incorporated into a propellant systemo as to interact with and bond various filler materials into a cured binder system.
Inventors
- 👤 John P. Consaga
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 13:16
CPC Classifications
C; C06; C06B; C06B45/00; C06B45/04; C06B45/06; C06B45/10
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
187 words
In combination with a composition which is selected from the group consisting of a propellant and an explosive and wherein said composition comprises a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminatal groups, mercaptyl terminal groups, and episulfide terminal groups, and an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotetramethylene tetranitramine (HMX) and cyclotrimethylene trinitramine (RDX), wherein the improvement comprises: means for preventing dewetting of said composition by the addition of a dimethylhydantoin bonding agent of the formula ##STR5## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR6## --CH 2 CH═CH 2 , and --CH 2 CH 2 COOH and wherein, said bonding agent prevents dewetting by complexing with said binder and said oxidizer.
Claim 2
Dependent Claim
187 words
In combination with a composition which is selected from the group consisting of a propellant and an explosive and wherein said composition comprises a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminatal groups, mercaptyl terminal groups, and episulfide terminal groups, and an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotetramethylene tetranitramine (HMX) and cyclotrimethylene trinitramine (RDX), wherein the improvement comprises: means for preventing dewetting of said composition by the addition of a dimethylhydantoin bonding agent of the formula ##STR5## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR6## --CH 2 CH═CH 2 , and --CH 2 CH 2 COOH and wherein, said bonding agent prevents dewetting by complexing with said binder and said oxidizer.
Claim 3
Dependent Claim
13 words
The composition of claim 1 wherein R is --CH 2 CH 2 OH.
Claim 4
Dependent Claim
20 words
The composition of claim 2, wherein the oxidizer is selected from the group consisting of cyclotetramethylene tetranitramine and cyclotrimethylene trinitramine.
Claim 5
Dependent Claim
20 words
The composition of claim 2 wherein the oxidizer is selected from the group consisting of ammonium perchlorate or potassium perchlorate.
Claim 6
Dependent Claim
147 words
A composition being selected from the group consisting of a propellant and an explosive, comprising: a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminal groups, mercaptyl terminal groups, and episulfide terminal groups; an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotrimethylene trinitramine and cyclotetramethylene tetranitramine; and a dimethylhydantoin bonding agent of the formula ##STR7## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR8## --CH 2 --CH═CH 2 , and --CH 2 CH 2 COOH.
Claim 7
Dependent Claim
147 words
A composition being selected from the group consisting of a propellant and an explosive, comprising: a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminal groups, mercaptyl terminal groups, and episulfide terminal groups; an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotrimethylene trinitramine and cyclotetramethylene tetranitramine; and a dimethylhydantoin bonding agent of the formula ##STR7## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR8## --CH 2 --CH═CH 2 , and --CH 2 CH 2 COOH.
Claim 8
Dependent Claim
35 words
The composition of claim 5 wherein the binder comprises 10% of 25%, the oxidizer comprises 75% to 90%, and the agent comprises up to 5% all percentages being based on the weight of the propellant.
Claim 9
Dependent Claim
12 words
The composition of claim 5 wherein the binder is hydroxyl terminated polybutadiene.
References Cited (Backward Citations)
US3278352A
Cited
US3449353A
Cited
US3631221A
Cited
US3834957A
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US3790416A
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US3801385A
Cited
US3734786A
Cited
US3843675A
Cited
US3894038A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-07-29 | 1984-01-28 | 1984-07-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-07-29 | 1988-01-28 | 1988-07-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-07-29 | 1992-01-28 | 1992-07-29 | $7700.00 | Window Closed / Lapsed |