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US4214928A Expired / Lapsed US ⏱️ 0.0 years remaining

Dimethyl hydantoin bonding agents in solid propellants

Assignee: United States Department of the Navy
•
Filing: 1976-11-29
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Granted: 1980-07-29
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Expires: 1996-11-29
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Abstract

Abstract A dimethyl hydantoin bonding agent is incorporated into a propellant systemo as to interact with and bond various filler materials into a cured binder system.

Inventors

  • 👤 John P. Consaga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 13:16
CPC Classifications
C; C06; C06B; C06B45/00; C06B45/04; C06B45/06; C06B45/10

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 187 words
In combination with a composition which is selected from the group consisting of a propellant and an explosive and wherein said composition comprises a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminatal groups, mercaptyl terminal groups, and episulfide terminal groups, and an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotetramethylene tetranitramine (HMX) and cyclotrimethylene trinitramine (RDX), wherein the improvement comprises: means for preventing dewetting of said composition by the addition of a dimethylhydantoin bonding agent of the formula ##STR5## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR6## --CH 2 CH═CH 2 , and --CH 2 CH 2 COOH and wherein, said bonding agent prevents dewetting by complexing with said binder and said oxidizer.
Claim 2
Dependent Claim 187 words
In combination with a composition which is selected from the group consisting of a propellant and an explosive and wherein said composition comprises a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminatal groups, mercaptyl terminal groups, and episulfide terminal groups, and an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotetramethylene tetranitramine (HMX) and cyclotrimethylene trinitramine (RDX), wherein the improvement comprises: means for preventing dewetting of said composition by the addition of a dimethylhydantoin bonding agent of the formula ##STR5## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR6## --CH 2 CH═CH 2 , and --CH 2 CH 2 COOH and wherein, said bonding agent prevents dewetting by complexing with said binder and said oxidizer.
Claim 3
Dependent Claim 13 words
The composition of claim 1 wherein R is --CH 2 CH 2 OH.
Claim 4
Dependent Claim 20 words
The composition of claim 2, wherein the oxidizer is selected from the group consisting of cyclotetramethylene tetranitramine and cyclotrimethylene trinitramine.
Claim 5
Dependent Claim 20 words
The composition of claim 2 wherein the oxidizer is selected from the group consisting of ammonium perchlorate or potassium perchlorate.
Claim 6
Dependent Claim 147 words
A composition being selected from the group consisting of a propellant and an explosive, comprising: a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminal groups, mercaptyl terminal groups, and episulfide terminal groups; an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotrimethylene trinitramine and cyclotetramethylene tetranitramine; and a dimethylhydantoin bonding agent of the formula ##STR7## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR8## --CH 2 --CH═CH 2 , and --CH 2 CH 2 COOH.
Claim 7
Dependent Claim 147 words
A composition being selected from the group consisting of a propellant and an explosive, comprising: a polymeric binder selected from the group consisting of epoxy terminated polybutadiene, carboxyl terminated polybutadiene, hydroxyl terminated polybutadiene, mercaptyl terminated polybutadiene, episulfide terminated polybutadiene, epoxy terminated polyether, carboxyl terminated polyether, hydroxyl terminated polyether, mercaptyl terminated polyether, episulfide terminated polyether, and liquid copolymer systems selected from the group consisting of polybutadiene-styrene and polybutadiene-acrylonitrile having functional groups selected from the group which consists of epoxy terminal groups, carboxyl terminal groups, hydroxyl terminal groups, mercaptyl terminal groups, and episulfide terminal groups; an oxidizer selected from the group consisting of ammonium nitrate, potassium perchlorate, ammonium perchlorate, cyclotrimethylene trinitramine and cyclotetramethylene tetranitramine; and a dimethylhydantoin bonding agent of the formula ##STR7## wherein R is selected from the group consisting of --CH 2 CH 2 OH, ##STR8## --CH 2 --CH═CH 2 , and --CH 2 CH 2 COOH.
Claim 8
Dependent Claim 35 words
The composition of claim 5 wherein the binder comprises 10% of 25%, the oxidizer comprises 75% to 90%, and the agent comprises up to 5% all percentages being based on the weight of the propellant.
Claim 9
Dependent Claim 12 words
The composition of claim 5 wherein the binder is hydroxyl terminated polybutadiene.

References Cited (Backward Citations)

US3278352A Cited
US3449353A Cited
US3631221A Cited
US3834957A Cited
US3790416A Cited
US3801385A Cited
US3734786A Cited
US3843675A Cited
US3894038A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-07-29 1984-01-28 1984-07-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-07-29 1988-01-28 1988-07-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-07-29 1992-01-28 1992-07-29 $7700.00 Window Closed / Lapsed

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