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US4210345A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure-sensitive recording or copying material

Assignee: BASF Corp
•
Filing: 1978-05-24
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Granted: 1980-07-01
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Expires: 1998-05-24
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Abstract

Abstract Pressure-sensitive recording or copying materials which contain, in their color reactant system, as developers for the color-forming agent, at least one mono- or poly-aldehyde which is electronegatively substituted, especially by halogen, and/or the reaction products thereof with an organic compound containing hydroxyl groups, or the precursors thereof.

Inventors

  • 👤 Horst Kosche

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 05:25
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/155; Y; Y10; Y10S; Y10S283/00; Y10S283/902; Y10S428/00; Y10S428/913; Y10S428/914; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31942; Y10T428/31949; Y10T428/31964

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 196 words
In a pressure sensitive recording or copying material which contains, in its color reactant system; a color-producing acceptor as the developer for the color-forming agent, the improvement wherein the developer contains at least one member which is the reaction product of an electronegatively substituted aldehyde and an aliphatic organic compound containing hydroxyl groups, such that the aldehyde moiety is bonded to the radical of said aliphatic organic compound via at least one oxygen atom, said electronegatively substituted aldehyde being an electronegatively substituted mono- or polyaldehyde, wherein at least one such electronegative substituents is halo or cyano and interacts electromerically with at least one aldehyde group thereof, said aldehyde having the formula ##STR14## wherein R is a substituted or unsubstituted, saturated or unsaturated aliphatic radical, M is a substituted or unsubstituted aromatic, aromatic-cycloaliphatic, aromatic-heterocyclic or heterocyclic radical with aromatic properties, Y is halo or cyano, Z is hydrogen or an acid group, m and n are independently an integer of 1 to 6. Y 1 is hydrogen or halogen, Y 2 is halogen, and R 1 is hydrogen, carboxyl, alkyl of 1 to 3 carbon atoms, halogenoalkyl of 1 to 3 carbon atoms, phenyl, benzyl or halogenobenzyl.
Claim 2
Dependent Claim 196 words
In a pressure sensitive recording or copying material which contains, in its color reactant system; a color-producing acceptor as the developer for the color-forming agent, the improvement wherein the developer contains at least one member which is the reaction product of an electronegatively substituted aldehyde and an aliphatic organic compound containing hydroxyl groups, such that the aldehyde moiety is bonded to the radical of said aliphatic organic compound via at least one oxygen atom, said electronegatively substituted aldehyde being an electronegatively substituted mono- or polyaldehyde, wherein at least one such electronegative substituents is halo or cyano and interacts electromerically with at least one aldehyde group thereof, said aldehyde having the formula ##STR14## wherein R is a substituted or unsubstituted, saturated or unsaturated aliphatic radical, M is a substituted or unsubstituted aromatic, aromatic-cycloaliphatic, aromatic-heterocyclic or heterocyclic radical with aromatic properties, Y is halo or cyano, Z is hydrogen or an acid group, m and n are independently an integer of 1 to 6. Y 1 is hydrogen or halogen, Y 2 is halogen, and R 1 is hydrogen, carboxyl, alkyl of 1 to 3 carbon atoms, halogenoalkyl of 1 to 3 carbon atoms, phenyl, benzyl or halogenobenzyl.
Claim 3
Dependent Claim 17 words
A material according to claim 1, in which the aldehydes are of one of the formulae ##STR15##
Claim 4
Dependent Claim 16 words
A material according to claim 1, in which the electronegative substituent on the aldehyde is halogen.
Claim 5
Dependent Claim 51 words
A material according to claim 1, in which the aldehyde is of the formula ##STR16## in which Y 1 is hydrogen or halogen, Y 2 is halogen and R 1 is halogen, carboxyl, alkyl having 1 to 3 carbon atoms, halogenoalkyl having 1 to 3 carbon atoms, phenyl, benzyl or halogenobenzyl.
Claim 6
Dependent Claim 23 words
A material according to claim 1, wherein the aldehyde is polymeric trichloroacetaldehyde with at least one free aldehyde group, 2,2,3-dichloropentanal, 2,3-dibromo-3-dichloropropional or trichloroacetaldehyde.
Claim 7
Dependent Claim 32 words
A material according to claim 1, in which the organic hydroxy compounds are substituted or unsubstituted aliphatic alcohols, ether-alcohols, ester-alcohols, halogenoalcohols, half-acetals, hydroxycarboxylic acids, hydroxyaldehydes, hydroxyketones, enols, carboxylic acid anhydrides or carbohydrates.
Claim 8
Dependent Claim 56 words
A material according to claim 1, in which the organic hydroxy compounds are monomeric or polymeric sugars, their ethers, esters or halogenation products, sugar alcohols, uronic acids, aminosugars, sulphhydryl sugars, alginic acid, alginic acid esters, pectins, cellulose, cellulose esters, cellulose ethers or glycolic acid, pentosans or pentosanglycolic acids, starch, starch esters or starch ethers or aminostarch.
Claim 9
Dependent Claim 25 words
A material according to claim 1, in which the organic hydroxy compound is a hexose or a sugar alcohol having 3 to 6 carbon atoms.
Claim 10
Dependent Claim 22 words
A material according to claim 1, which contains developers which are obtained by reacting chloral with glycerol, erythritol, sorbitol, glucose or 1,3-dichloro-2-chloromethylpropan-2-ol.
Claim 11
Dependent Claim 22 words
A material according to claim 1, which contains developers in combination with silicates, silicic acids, cellulose, pigments or aluminas as structure-forming substances.
Claim 12
Dependent Claim 24 words
A material according to claim 1, which contains spiranes, fluoranes, triphenylmethane compounds, flavones, chromans, polymethine compounds and polyimine compounds or phthalides as colour-forming agents.
Claim 13
Dependent Claim 22 words
A material according to claim 1, which contains the developers in combination with chelate-forming metal salts of the transition elements with acids.
Claim 14
Dependent Claim 13 words
A material according to claim 1, which contains the colour-forming agents in microcapsules.
Claim 15
Dependent Claim 33 words
A process for producing recordings with the aid of a pressure-sensitive recording or duplicating system containing a colour-forming agent and a developer, in which the developer has the composition indicated in claim 1.
Claim 16
Dependent Claim 94 words
A material according to claim 1, wherein the developer is a reaction product having one of the formula ##STR17## in which Y, Z, M, R, M, m and n are as defined in claim 1, D is hydrogen or a substituted or unsubstituted alipahtic radical, and E is a substituted or unsubstituted aliphatic radical bonded via oxygen to ##STR18## or is halogen, or D and E are a substituted or unsubstituted aliphatic radical bonded via an ether or ester bridge to ##STR19## and wherein D and E can be bonded direct to one another.
Claim 17
Dependent Claim 29 words
A material according to claim 1, which contains a developer obtained by reacting chloral with glycerol, erythritol, sorbitol, glucose or 1,3-dichloro-2-chloromethyl-propan-2-ol followed by subsequent acetylation of the reaction product.

References Cited (Backward Citations)

US3649357A Cited
US3823022A Cited
US3896255A Cited
US3900218A Cited
US4025399A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-07-01 1983-12-31 1984-07-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-07-01 1987-12-31 1988-07-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-07-01 1991-12-31 1992-07-01 $7700.00 Window Closed / Lapsed

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