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US4208362A Expired / Lapsed US ⏱️ 0.0 years remaining

Shaped body of at least two polymerized materials and method to make same

Assignee: Bausch and Lomb Inc
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Filing: 1976-03-22
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Granted: 1980-06-17
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Expires: 1996-03-22
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Abstract

Abstract A shaped body is manufactured from at least two polymerized materials with one polymerized material being swellable relative to the other polymerized material. The shaped body is formed having sections of the first material, the second material and a substantially random copolymer of the first and second materials as a transition section between the first and second sections.

Inventors

  • 👤 William G. Deichert
  • 👤 Joseph J. Falcetta
  • 👤 Kai C. Su

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:48
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043; B; B29; B29D; B29D11/00; B29D11/00009; B29D11/00038; B29D11/00048; G02C; G02C7/00; G02C7/02; G02C7/04; G02C7/049

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 189 words
A method of manufacturing a shaped body for eventual use as a contact lens comprising at least two polymerized materials, comprising: providing a first polymerizable material in a mold, said mold having a convex surface therein, said material being capable of forming a relatively swellable polymerized material a portion of said material forming a surface free of contact with the mold said polymerizable material not completely covering said convex surface in said mold; providing a swelling agent in the mold with the first polymerizable material; polymerizing a portion of the first material while inhibiting polymerization of the surface portion of the first material to obtain polymerized and unpolymerized portions of the first material; adding a second polymerizable material to the mold said second material contacting the surface of the first material, the second material being relatively hard when polymerized; and polymerizing the unpolymerized portion of the first material and the second material to obtain a shaped body having a polymerized edge section of the first material, a polymerized section of a substantially random copolymer of the first and second materials and a polymerized center section of the second material.
Claim 2
Independent Claim 189 words
A method of manufacturing a shaped body for eventual use as a contact lens comprising at least two polymerized materials, comprising: providing a first polymerizable material in a mold, said mold having a convex surface therein, said material being capable of forming a relatively swellable polymerized material a portion of said material forming a surface free of contact with the mold said polymerizable material not completely covering said convex surface in said mold; providing a swelling agent in the mold with the first polymerizable material; polymerizing a portion of the first material while inhibiting polymerization of the surface portion of the first material to obtain polymerized and unpolymerized portions of the first material; adding a second polymerizable material to the mold said second material contacting the surface of the first material, the second material being relatively hard when polymerized; and polymerizing the unpolymerized portion of the first material and the second material to obtain a shaped body having a polymerized edge section of the first material, a polymerized section of a substantially random copolymer of the first and second materials and a polymerized center section of the second material.
Claim 3
Dependent Claim 24 words
The method of claim 1, wherein the amount of swelling agent used is limited to that amount necessary to suitably swell the first material.
Claim 4
Dependent Claim 46 words
The method of claim 2, wherein the first material is a sparingly cross-linked poly (2-hydroxyethyl methacrylate), the swelling agent is water and the amount of water used is between 35 and 40 percent of the total weight of a mixture of the first material and water.
Claim 5
Dependent Claim 60 words
The method of claim 1, wherein the polymerized material used in the edge section is selected to be relatively soft when combined with a swelling agent, the polymerized material used in the center section is selected to be relatively hard and transparent and the configuration of the mold is selected to substantially form the shaped body into a contact lens.
Claim 6
Dependent Claim 57 words
The method of claim 1, wherein the polymerized material used in the edge section is selected to be relatively soft when combined with a swelling agent, the polymerized material used in the center section is selected to be relatively hard and transparent and the materials are machined to substantially form the shaped body into a contact lens.
Claim 7
Dependent Claim 52 words
The invention according to claim 1 in which said mold has a top half having a concave surface therein, said concave surface being juxtaposed to said convex surface of said mold so as to provide a curved exterior surface on the portion of said shaped body comprised of said second polymerizable material.
Claim 8
Dependent Claim 21 words
The invention according to claim 1 in which the first polymerizable material is hydrophilic and the second polymerizable material is hydrophobic.
Claim 9
Independent Claim 186 words
A method of manufacturing a shaped body for eventual use in a contact lens comprising at least two polymerized materials, comprising: providing a first polymerizable material in a mold, said material being capable of forming a relatively soft swellable polymerized material, a portion of said material forming a surface portion that is free of contact with the mold; providing a swelling agent in the mold with the first polymerizable material; polymerizing a portion of the first material while inhibiting polymerization of the surface portion of the first material to obtain polymerized and unpolymerized portions of the first material; removing the means of inhibiting polymerization of the surface portion of the first material; adding a second polymerizable material to the mold, said second material contacting the surface of the first material, said second material being relatively hard when polymerized; and polymerizing the unpolymerized portion of the first material and the second material to obtain a shaped body having a section of the first polymerized material, a transition section of a substantially random copolymer of the first and second materials, and a section of the second polymerized material.
Claim 10
Independent Claim 186 words
A method of manufacturing a shaped body for eventual use in a contact lens comprising at least two polymerized materials, comprising: providing a first polymerizable material in a mold, said material being capable of forming a relatively soft swellable polymerized material, a portion of said material forming a surface portion that is free of contact with the mold; providing a swelling agent in the mold with the first polymerizable material; polymerizing a portion of the first material while inhibiting polymerization of the surface portion of the first material to obtain polymerized and unpolymerized portions of the first material; removing the means of inhibiting polymerization of the surface portion of the first material; adding a second polymerizable material to the mold, said second material contacting the surface of the first material, said second material being relatively hard when polymerized; and polymerizing the unpolymerized portion of the first material and the second material to obtain a shaped body having a section of the first polymerized material, a transition section of a substantially random copolymer of the first and second materials, and a section of the second polymerized material.
Claim 11
Dependent Claim 21 words
The invention according to claim 8 in which said first polymerizable material is hydrophilic and said second polymerizable material is hydrophobic.
Claim 12
Dependent Claim 57 words
The invention according to claim 8 involving the additional step of: machining at least one of the polymerized materials to obtain a contact lens having an edge section of the first polymerized material, a polymerized section of a substantially random copolymer of the first and second polymerized materials and a center section of the second polymerized material.

References Cited (Backward Citations)

GB1045065A Cited
US3489491A Cited
US3925178A Cited
US3804366A Cited
GB1412439A Cited
US3961379A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-06-17 1983-12-17 1984-06-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-06-17 1987-12-17 1988-06-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-06-17 1991-12-17 1992-06-17 $7700.00 Window Closed / Lapsed

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