US4208295A
Expired / Lapsed
US
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Bleaching detergent composition
Assignee: Hochtemperatur Reaktorbau GmbH
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Filing: 1979-01-22
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Granted: 1980-06-17
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Expires: 1999-01-22
Abstract
Abstract A bleaching detergent composition comprises (i) a water-insoluble aluminosilicate having a degree of crystallization of 0 to 75% or a water-insoluble aluminosilicate having exchangeable cations partially substituted by calcium and/or magnesium ions, (ii) a surface active agent and (iii) sodium percarbonate. It is very much improved in respect to the storage stability of the sodium percarbonate.
Inventors
- 👤 Fumio Sai
- 👤 Takashi Fujino
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 21:54
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3942; C11D3/02; C11D3/12; C11D3/124; C11D3/1246; C11D3/128
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
145 words
A bleaching detergent composition consisting essentially of: (i) from 3 to 50% by weight of water-insoluble aluminosilicate having a degree of crystallization of 0 to 75% and having the formula: X(M.sub.2 O)·(Al.sub.2 O.sub.3)·Y(SiO.sub.2)·W(H.sub.2 O) wherein M is sodium and/or potassium, and X, Y and W are mole numbers having the following values: 0.7≦X≦1.2 1.8≦Y≦2.2 and W is zero or a positive number, (ii) from 5 to 50% by weight of water-soluble, synthetic, organic, surface active agent effective for washing clothes and selected from the group consisting of anionic surface active agents, nonionic surface active agents, amphoteric surface active agents and mixtures thereof, (iii) from 3 to 50% by weight of sodium percarbonate, and the balance is one or a mixture of water-soluble alkali metal salt ion sequestering agent for detergents, water-soluble alkali metal salt inorganic electrolyte for detergents and water-soluble recontamination preventing agent for detergents.
Claim 2
Dependent Claim
145 words
A bleaching detergent composition consisting essentially of: (i) from 3 to 50% by weight of water-insoluble aluminosilicate having a degree of crystallization of 0 to 75% and having the formula: X(M.sub.2 O)·(Al.sub.2 O.sub.3)·Y(SiO.sub.2)·W(H.sub.2 O) wherein M is sodium and/or potassium, and X, Y and W are mole numbers having the following values: 0.7≦X≦1.2 1.8≦Y≦2.2 and W is zero or a positive number, (ii) from 5 to 50% by weight of water-soluble, synthetic, organic, surface active agent effective for washing clothes and selected from the group consisting of anionic surface active agents, nonionic surface active agents, amphoteric surface active agents and mixtures thereof, (iii) from 3 to 50% by weight of sodium percarbonate, and the balance is one or a mixture of water-soluble alkali metal salt ion sequestering agent for detergents, water-soluble alkali metal salt inorganic electrolyte for detergents and water-soluble recontamination preventing agent for detergents.
Claim 3
Dependent Claim
23 words
A bleaching detergent composition as claimed in claim 1, in which an amount of the aluminosilicate is from 5 to 50% by weight.
Claim 4
Dependent Claim
25 words
A bleaching detergent composition as claimed in claim 1, in which an amount of the surface active agent is from 10 to 30% by weight.
Claim 5
Dependent Claim
22 words
A bleaching detergent composition as claimed in claim 1, wherein the degree of crystallization of the water-insoluble aluminosilicate is 0 to 50%.
Claim 6
Dependent Claim
132 words
A bleaching detergent as claimed in claim 1, wherein the surface active agent is selected from the group consisting of: (a) straight chain or branched alkylbenzene sulfonates having 10 to 16 carbon atoms in the alkyl group on the average, (b) alkyl or alkenylethoxy sulfates having a straight chain or branched alkyl or alkenyl group having 8 to 20 carbon atoms on the average and containing 0.5 to 8 moles on the average of added ethylene oxide units in the molecule, (c) alkyl or alkenyl sulfates having an alkyl or alkenyl group having 10 to 20 carbon atoms on the average, (d) alkane sulfonates having 10 to 20 carbon atoms on the average in the molecule, and (e) olefin sulfonates having 10 to 20 carbon atoms on the average in the molecule.
Claim 7
Dependent Claim
23 words
A bleaching detergent composition as claimed in claim 1, in which the aluminosilicate has a particle size of not greater than 100 microns.
Claim 8
Dependent Claim
37 words
A bleaching detergent composition as claimed in claim 1, in which the aluminosilicate has a calcium ion exchanging property of at least 150 mg, calculated as calcium carbonate, per gram of said aluminosilicate, calculated as the anhydride.
Claim 9
Dependent Claim
170 words
A bleaching detergent composition consisting essentially of: (i) from 3 to 50% by weight of water-insoluble aluminosilicate having exchangeable cations partially substituted by calcium and/or magnesium ions, having the formula: A(M.sup.+.sub.2 O)·B(M.sup.2+ O)·(Al.sub.2 O.sub.3)·C(SiO.sub.2)·D(H.sub.2 O) wherein M + is alkali metal, M 2+ is calcium and/or magnesium, and A, B, C and D are the mole numbers of the respective components, in which A and B are positive numbers satisfying the relations: 0.7≦A+B≦1.2 and B/A+B=0.001 to 0.1, C is a number in the range of 1.6≦C≦2.2, and D is a positive number, (ii) from 3 to 50% by weight of water-soluble, synthetic, organic surface active agent selected from the group consisting of anionic surface active agents, nonionic surface active agents, amphoteric surface active agents and mixtures thereof, (iii) from 3 to 50% by weight of sodium percarbonate, and the balance is one or a mixture of water-soluble alkali metal salt ion sequestering agent for detergents, water-soluble alkali metal salt inorganic electrolyte for detergents and water-soluble recontamination preventing agent for detergents.
Claim 10
Dependent Claim
170 words
A bleaching detergent composition consisting essentially of: (i) from 3 to 50% by weight of water-insoluble aluminosilicate having exchangeable cations partially substituted by calcium and/or magnesium ions, having the formula: A(M.sup.+.sub.2 O)·B(M.sup.2+ O)·(Al.sub.2 O.sub.3)·C(SiO.sub.2)·D(H.sub.2 O) wherein M + is alkali metal, M 2+ is calcium and/or magnesium, and A, B, C and D are the mole numbers of the respective components, in which A and B are positive numbers satisfying the relations: 0.7≦A+B≦1.2 and B/A+B=0.001 to 0.1, C is a number in the range of 1.6≦C≦2.2, and D is a positive number, (ii) from 3 to 50% by weight of water-soluble, synthetic, organic surface active agent selected from the group consisting of anionic surface active agents, nonionic surface active agents, amphoteric surface active agents and mixtures thereof, (iii) from 3 to 50% by weight of sodium percarbonate, and the balance is one or a mixture of water-soluble alkali metal salt ion sequestering agent for detergents, water-soluble alkali metal salt inorganic electrolyte for detergents and water-soluble recontamination preventing agent for detergents.
Claim 11
Dependent Claim
26 words
A bleaching detergent composition as claimed in claim 8 wherein the aluminosilicate has the same crystal structure as that of an aluminosilicate of the A type.
Claim 12
Dependent Claim
22 words
A bleaching detergent composition as claimed in claim 8 wherein the aluminosilicate is a water-insoluble aluminosilicate which is partially substituted by calcium.
Claim 13
Dependent Claim
24 words
A bleaching detergent composition as claimed in claim 8 wherein the aluminosilicate is a water-insoluble aluminosilicate which is partially substituted by calcium and magnesium.
Claim 14
Dependent Claim
19 words
A bleaching detergent composition as claimed in claim 8 wherein M + is sodium, potassium or a mixture thereof.
Claim 15
Dependent Claim
14 words
A bleaching detergent composition as claimed in claim 12 wherein M + is sodium.
References Cited (Backward Citations)
US3413229A
Cited
US4083795A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-06-17 | 1983-12-17 | 1984-06-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-06-17 | 1987-12-17 | 1988-06-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-06-17 | 1991-12-17 | 1992-06-17 | $7700.00 | Window Closed / Lapsed |