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US4205399A Expired / Lapsed US ⏱️ 0.0 years remaining

Synthetic absorbable surgical devices of poly(alkylene oxalates)

Assignee: Ethicon Inc
•
Filing: 1978-05-26
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Granted: 1980-06-03
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Expires: 1998-05-26
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Abstract

Abstract Synthetic filaments composed of homopolymers and copolymers of poly(alkylene oxalates) are absorbable in animal tissue with minimal adverse tissue reaction. Polymers prepared by reacting a dialkyl oxalate with an alkylene diol are melt spun and drawn to obtain oriented fibers having good tensile properties and a high level of flexibility and softness. The filaments are particularly useful in the preparation of surgical prosthesis comprising woven or knitted fabrics and meshes. Other absorbable surgical devices including films and molded items may also be prepared from the disclosed polymer.

Inventors

  • 👤 Shalaby W. Shalaby
  • 👤 Dennis D. Jamiolkowski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-22 20:06
CPC Classifications
D; D01; D01F; D01F6/00; D01F6/78; D01F6/84; A; A61; A61L; A61L17/00; A61L17/06; A61L17/10; A61L17/105; A61L27/00; A61L27/14; A61L27/18; C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; D01F6/58; D01F6/62; D01F6/625

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 75 words
A surgical prosthesis comprising a fabric manufactured at least in part from synthetic absorbable fibers comprising a polymer having a major portion of units of the formula ##STR3## wherein R is a C 3 to C 16 alkylene and n is the degree of polymerization resulting in a fiber-forming polymer having an inherent viscosity of at least about 0.4 as determined at 25° C. on a 0.1 percent solution of polymer in chloroform or hexafluoroisopropanol.
Claim 2
Dependent Claim 75 words
A surgical prosthesis comprising a fabric manufactured at least in part from synthetic absorbable fibers comprising a polymer having a major portion of units of the formula ##STR3## wherein R is a C 3 to C 16 alkylene and n is the degree of polymerization resulting in a fiber-forming polymer having an inherent viscosity of at least about 0.4 as determined at 25° C. on a 0.1 percent solution of polymer in chloroform or hexafluoroisopropanol.
Claim 3
Dependent Claim 33 words
A surgical prosthesis of claim 1 wherein said fibers are further characterized by a straight tensile strength of at least about 30,000 psi and a Young's modulus of less than about 600,000 psi.
Claim 4
Dependent Claim 45 words
A surgical prosthesis of claim 2 wherein said polymer is a homopolymer of poly(alkylene oxalate) or a copolymer of C 3 to C 16 alkylene oxalate with up to about 50 percent by weight of at least one other monomer copolymerizable to an absorbable polymer.
Claim 5
Dependent Claim 10 words
A surgical prosthesis of claim 1 comprising a woven fabric.
Claim 6
Dependent Claim 10 words
A surgical prosthesis of claim 1 comprising a knitted fabric.
Claim 7
Dependent Claim 11 words
A surgical prosthesis of claim 1 comprising a nonwoven, felted fabric.
Claim 8
Dependent Claim 12 words
A surgical prosthesis of claim 1 comprising a tubular vascular prosthetic device.
Claim 9
Dependent Claim 69 words
A surgical prosthesis comprising a solid surgical aid, cast or machined from an absorbable polymer having a major portion of units of the formula ##STR4## wherein R is a C 3 to C 16 alkylene and n is the degree of polymerization resulting in a polymer having an inherent viscosity of at least 0.4 determined at 25° C. on a 0.1 percent solution of polymer in chloroform or hexafluoroisopropanol.
Claim 10
Dependent Claim 69 words
A surgical prosthesis comprising a solid surgical aid, cast or machined from an absorbable polymer having a major portion of units of the formula ##STR4## wherein R is a C 3 to C 16 alkylene and n is the degree of polymerization resulting in a polymer having an inherent viscosity of at least 0.4 determined at 25° C. on a 0.1 percent solution of polymer in chloroform or hexafluoroisopropanol.
Claim 11
Dependent Claim 45 words
A surgical prosthesis of claim 8 wherein said polymer is a homopolymer of poly(alkylene oxalate) or a copolymer of C 3 to C 16 alkylene oxalate with up to about 50 percent by weight of at least one other monomer copolymerizable to an absorbable polymer.

References Cited (Backward Citations)

US4032993A Cited
US4105034A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-06-03 1983-12-03 1984-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-06-03 1987-12-03 1988-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-06-03 1991-12-03 1992-06-03 $7700.00 Window Closed / Lapsed

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