Polyester coating composition

Claim 2

In a coating composition comprising a resinous binder and optionally pigment and diluent in an amount sufficient to provide the coating composition with a sufficient viscosity for coating, the improvement comprising: using as the resinous binder an ungelled polyester having a hydroxyl value of 10-160 and a weight average molecular weight of about 50,000 to 300,000 as determined by gel permeation chromatography using a polystyrene standard, formed from reacting: (A) 10 to 70 percent by weight of a difunctional active hydrogen component having two active hydrogens per molecule selected from the class consisting of hydroxyl, primary amine and secondary amine, said active hydrogen component comprising: (1) 10 to 60 percent by weight of an acrylic diol having a carbon to oxygen ratio of at least 2, (2) up to 60 percent by weight of a cyclic diol, (3) up to 20 percent by weight of a compound selected from the class consisting of diamines and hydroxyl-containing amines; (B) 25 to 85 percent by weight of a dicarboxylic acid component comprising: (1) 5 to 85 percent by weight of an acyclic dicarboxylic acid containing from 2 to 36 carbon atoms, (2) up to 80 percent by weight of a cyclic dicarboxylic acid; (C) up to 30 percent by weight of an active hydrogen component having at least three active hydrogens per molecule, the active hydrogens being selected from the class consisting of hydroxyl, primary amine, secondary amine and carboxylic acid; (D) up to 20 percent by weight of a monoamino monocarboxylic acid; the percentages by weight being based on total weight of (A), (B), (C) and (D), the percentages of the reactants being adjusted such that the weight percentages of cyclic moieties in said polyester plus the weight percentages of amide moieties formed in said polyester multiplied by 4 is up to 35 and the weight percentages of the reactants being further adjusted such that these reactants contain about 0.01 to 1.0 gram-mole of reactants having a functionality of 3 or more per 500 grams of reactants.

Claim 3

The polyester of claim 1 in which the acyclic diol is selected from the class consisting of hexanediol and neopentyl glycol and mixtures thereof.

Claim 4

The polyester of claim 1 in which (C) is selected from the class consisting of trimethylolpropane, pentaerythritol, glycerine, dimethylol propionic acid and mixtures thereof.

Claim 5

The polyester of claim 1 in which the cyclic dicarboxylic acid is selected from the class consisting of phthalic acid, terephthalic acid and isophthalic acid, hydrogenated derivatives thereof and mixtures thereof.

Claim 6

The polyester of claim 1 in which the acyclic dicarboxylic acid is adipic acid.

Claim 7

The polyester of claim 1 which has a hydroxyl value of 40-100.

Claim 8

The polyester of claim 1 which has a weight average molecular weight of 80,000 to 150,000.

Claim 9

The polyester of claim 1 which contains from 0.20 to 0.70 gram-mole of reactants having a functionality of 3 or more per 500 grams of reactants.

Claim 10

The composition of claim 1 in combination with a curing agent.

Claim 11

The composition of claim 9 in which the curing agent is selected from the class consisting of aminoplast and polyisocyanates.

Claim 12

The composition of claim 10 in which the polyester comprises from 20 to 95 percent by weight of the composition and the curing agent from 80 to 5 percent by weight of the composition, the percentage by weight being based on total weight of polyester and curing agent.

Claim 13

A coated article comprising: (A) a substrate and as a coating thereon (B) the cured resinous composition of claim 10.

Claim 14

The coated article of claim 12 in which the coating has a thickness of 0.1 to 5 mils.

Claim 15

The coated article of claim 12 in which the substrate is elastomeric.

Claim 16

The coated article of claim 12 in which the coating is pigmented.

Claim 17

The coated article of claim 15 in which a portion of the pigments are metallic pigments.

Claim 18

A paint composition comprising: (A) the composition of claim 10, (B) pigment, (C) liquid diluent present in an amount sufficient to reduce the paint composition viscosity for coating applications.

Claim 19

The paint of claim 17 in which the pigment-to-resin weight ratio is within the range of 0.05 to 1.5:1.

Claim 20

In a coating composition comprising a resinous binder and optionally pigment and diluent in an amount sufficient to provide the coating composition with a sufficient viscosity for coating, the improvement comprising: using as the resinous binder an ungelled polyester having a hydroxyl value of 10-160 and a weight average molecular weight of about 50,000 to 300,000 as determined by gel permeation chromatography using a polystyrene standard, formed from reacting: (A) 10 to 70 percent by weight of a difunctional active hydrogen component having two active hydrogens per molecule selected from the class consisting of hydroxyl, primary amine and secondary amine, said active hydrogen component comprising: (1) 10 to 60 percent by weight of an acyclic diol having a carbon to oxygen ratio of at least 2, (2) up to 60 percent by weight of a cyclic diol, (3) up to 20 percent by weight of a compound selected from the class consisting of diamines and hydroxyl-containing amines; (B) 25 to 85 percent by weight of a dicarboxylic acid component comprising: (1) 5 to 85 percent by weight of an acyclic dicarboxylic acid containing from 2 to 36 carbon atoms, (2) up to 80 percent by weight of a cyclic dicarboxylic acid; (C) up to 30 percent by weight of an active hydrogen component having at least three active hydrogens per molecule, the active hydrogens being selected from the class consisting of hydroxyl, primary amine, secondary amine and carboxylic acid; (D) up to 20 percent by weight of a monoamino monocarboxylic acid; the percentages by weight being based on total weight of (A), (B), (C) and (D), the percentages of the reactants being adjusted such that the weight percentages of cyclic moieties in said polyester plus the weight percentages of amide moieties formed in said polyester multiplied by 4 is up to 35 and the weight percentages of the reactants being further adjusted such that these reactants contain about 0.1-1.0 gram-mole of reactants having a functionality of 3 or more per 500 grams of reactants; said polyester being used in combination with a curing agent capable of reacting with the hydroxyl groups to form a crosslinked product.

Claim 21

In a coating composition comprising a resinous binder and optionally pigment and diluent in an amount sufficient to provide the coating composition with a sufficient viscosity for coating, the improvement comprising: using as the resinous binder an ungelled polyester having a hydroxyl value of 10-160 and a weight average molecular weight of about 50,000 to 300,000 as determined by gel permeation chromatography using a polystyrene standard, formed from reacting: (A) 10 to 70 percent by weight of a difunctional active hydrogen component having two active hydrogens per molecule selected from the class consisting of hydroxyl, primary amine and secondary amine, said active hydrogen component comprising: (1) 10 to 60 percent by weight of an acyclic diol having a carbon to oxygen ratio of at least 2, (2) up to 60 percent by weight of a cyclic diol, (3) up to 20 percent by weight of a compound selected from the class consisting of diamines and hydroxyl-containing amines; (B) 25 to 85 percent by weight of a dicarboxylic acid component comprising: (1) 5 to 85 percent by weight of an acyclic dicarboxylic acid containing from 2 to 36 carbon atoms, (2) up to 80 percent by weight of a cyclic dicarboxylic acid; (C) up to 30 percent by weight of an active hydrogen component having at least three active hydrogens per molecule, the active hydrogens being selected from the class consisting of hydroxyl, primary amine, secondary amine and carboxylic acid; (D) up to 20 percent by weight of a monoamino monocarboxylic acid; the percentages by weight being based on total weight of (A), (B), (C) and (D), the percentages of the reactants being adjusted such that the weight percentages of cyclic moieties in said polyester plus the weight percentages of amide moieties formed in said polyester multiplied by 4 is up to 35 and the weight percentages of the reactants being further adjusted such that these reactants contain about 0.1-1.0 gram-mole of reactants having a functionality of 3 or more per 500 grams of reactants; said polyester being used in combination with a curing agent capable of reacting with the hydroxyl groups to form a crosslinked product.

Claim 22

The polyester of claim 19 which has a weight average molecular weight of 80,000 to 150,000.

Claim 23

The polyester of claim 19 which has a hydroxyl value of 40 to 100.

Claim 24

The composition of claim 19 in which the curing agent is selected from the class consisting of aminoplasts and polyisocyanates.

Claim 25

The composition of claim 22 in which the polyester comprises from 20 to 95 percent by weight of the composition and the curing agent from 80 to 5 percent by weight of the composition, the percentage by weight being based on total weight of polyester and curing agent.

Claim 26

A coated article comprising: (A) a substrate and as a coating thereon (B) the cured resinous composition of claim 22.

Claim 27

A paint composition comprising: (A) the composition of claim 22, (B) pigment, (C) liquid diluent present in an amount sufficient to reduce the paint composition viscosity for coating applications.