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US4200722A Expired / Lapsed US ⏱️ 0.0 years remaining

Rubber-like copolymers of ethylene, at least one other α-alkene and one or more polyenes possessing increased building tack

Assignee: Stamicarbon BV
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Filing: 1976-11-19
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Granted: 1980-04-29
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Expires: 1996-11-19
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Abstract

Abstract Novel, rubbery copolymers of ethylene with at least one other alpha -alkene such as propylene, and a polyene such as 5-ethylidene norbornene-2, characterized by a differential scanning calorimetry thermogram maximum peak at a temperature between -7 DEG and +11 DEG C., are disclosed. These specific rubbery copolymers when one or more tackifiers are included therein, exhibit an unprecedentedly high tack and consequently provide for the first time EPDM-type compositions that have sufficient building tack for the manufacture of multi-ply articles such as tires.

Inventors

  • 👤 Albertus J. Pennings
  • 👤 Arnold Vossebeld

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 08:52
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; C08F210/18; C08K; C08K3/00; C08K3/02; C08K3/04; C08K3/06; C08K3/18; C08K3/20; C08K3/22; C08K5/00; C08K5/04; C08K5/09; C08L; C08L23/00; C08L23/02; C08L23/16; C08L91/00; C08L2312/00; C08L2666/00; C08L2666/02

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 106 words
A rubbery copolymer of 20 to 75 percent by weight of ethylene, about 24 to about 79 percent by weight of at least one other α-alkene having from 3 to 8 carbon atoms, and from about 0.1 to 10 percent by weight of one or more dienes, the total of said monomers amounting to 100 percent by weight, said rubbery copolymer having a thermogram recorded by differential scanning calorimetry (d.s.c.) at a cooling rate of 8° C. per minute and showing the heat of crystallization as a function of temperature having a peak which passes through a maximum at a temperature between -7° and +11° C.
Claim 2
Dependent Claim 106 words
A rubbery copolymer of 20 to 75 percent by weight of ethylene, about 24 to about 79 percent by weight of at least one other α-alkene having from 3 to 8 carbon atoms, and from about 0.1 to 10 percent by weight of one or more dienes, the total of said monomers amounting to 100 percent by weight, said rubbery copolymer having a thermogram recorded by differential scanning calorimetry (d.s.c.) at a cooling rate of 8° C. per minute and showing the heat of crystallization as a function of temperature having a peak which passes through a maximum at a temperature between -7° and +11° C.
Claim 3
Dependent Claim 22 words
The rubbery copolymer of claim 1 having a peak which passes through a maximum at a temperature between -3° and +8° C.
Claim 4
Dependent Claim 22 words
The rubbery copolymer of claim 1 having a peak which passes through a maximum at a temperature between 0° and 6° C.
Claim 5
Dependent Claim 15 words
The rubbery copolymer of claim 1 wherein said α-alkene is propylene, butylene-1 or mixtures thereof.
Claim 6
Dependent Claim 13 words
The rubbery copolymer of claim 1 wherein said diene present consists of 5-ethylidenenorbornene-2.
Claim 7
Dependent Claim 92 words
A rubbery copolymer of 20 to 75 percent by weight of ethylene, about 24 to about 79 percent by weight of propylene, and from about 0.1 to 10 percent by weight of 5-ethylidenenorbornene-2, the total of said monomers amounting to 100 percent by weight, said rubbery copolymer having a thermogram recorded by differential scanning calorimetry (d.s.c.) at a cooling rate of 8° C. per minute and showing the heat of crystallization as a function of temperature having a peak which passes through a maximum at a temperature between -7° and +11° C.
Claim 8
Dependent Claim 92 words
A rubbery copolymer of 20 to 75 percent by weight of ethylene, about 24 to about 79 percent by weight of propylene, and from about 0.1 to 10 percent by weight of 5-ethylidenenorbornene-2, the total of said monomers amounting to 100 percent by weight, said rubbery copolymer having a thermogram recorded by differential scanning calorimetry (d.s.c.) at a cooling rate of 8° C. per minute and showing the heat of crystallization as a function of temperature having a peak which passes through a maximum at a temperature between -7° and +11° C.
Claim 9
Dependent Claim 22 words
The rubbery copolymer of claim 6 having a peak which passes through a maximum at a temperature between -3° and +8° C.
Claim 10
Dependent Claim 22 words
The rubbery copolymer of claim 6 having a peak which passes through a maximum at a temperature between 0° and 6° C.
Claim 11
Dependent Claim 113 words
A rubbery copolymer of 20 to 75 percent by weight of ethylene, about 24 to about 79 percent by weight of propylene, and from about 0.1 to 10 percent by weight of 5-ethylidenenorbornene-2, the total of said monomers amounting to 100 percent by weight, said rubbery copolymer having a thermogram recorded by differential scanning calorimetry (d.s.c.) at a cooling rate of 8° C. per minute and showing the heat of crystallization as a function of temperature having a peak which passes through a maximum at a temperature between -7° and +11° C., and characterized by ethylene sequences of from about 7 to about 9 carbon atoms in the backbone of said rubbery copolymer.
Claim 12
Dependent Claim 113 words
A rubbery copolymer of 20 to 75 percent by weight of ethylene, about 24 to about 79 percent by weight of propylene, and from about 0.1 to 10 percent by weight of 5-ethylidenenorbornene-2, the total of said monomers amounting to 100 percent by weight, said rubbery copolymer having a thermogram recorded by differential scanning calorimetry (d.s.c.) at a cooling rate of 8° C. per minute and showing the heat of crystallization as a function of temperature having a peak which passes through a maximum at a temperature between -7° and +11° C., and characterized by ethylene sequences of from about 7 to about 9 carbon atoms in the backbone of said rubbery copolymer.
Claim 13
Dependent Claim 22 words
The rubbery copolymer of claim 9 having a peak which passes through a maximum at a temperature between -3° and +8° C.
Claim 14
Dependent Claim 22 words
The rubbery copolymer of claim 9 having a peak which passes through a maximum at a temperature between 0° and 6° C.

References Cited (Backward Citations)

US3063973A Cited
US3379701A Cited
US3684782A Cited
US3658770A Cited
US3671506A Cited
US3705138A Cited
US3681309A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-29 1983-10-29 1984-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-29 1987-10-29 1988-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-29 1991-10-29 1992-04-29 $7700.00 Window Closed / Lapsed

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