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US4200567A Expired / Lapsed US ⏱️ 0.0 years remaining

Synergistic impact modifier system for poly (alkylene terephthalates)

Assignee: Rohm and Haas Co
•
Filing: 1977-08-22
•
Granted: 1980-04-29
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Expires: 1997-08-22
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Abstract

Abstract Poly(C 2 to C 8 alkylene terephthalates) are improved by a novel synergistic impact modifier system comprised of one or more soft thermoplastic segmented copolyester elastomers and one or more multiphase composite interpolymers.

Inventors

  • 👤 Theodore D. Goldman
  • 👤 Sutton B. Farham

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 22:30
CPC Classifications
C; C08; C08F; C08F285/00; C08L; C08L67/00; C08L67/02

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 191 words
A synergistic impact modifier system for poly(C 2 to C 8 alkylene terephthalate) comprising A. one or more thermoplastic segmented copolyester elastomers, and B. one or more multiphase composite interpolymers comprising a final rigid thermoplastic phase polymerized in the presence of a first elastomeric phase polymerized from a monomer system selected from the group consisting of i. a monomer system comprising about 75 to 99.8% by weight C 1 to C 8 alkyl acrylate, 0.1 to 5% by weight crosslinking monomer, 0.1 to 5% by weight graftlinking monomer, said crosslinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups all of which polymerize at substantially the same rate of reaction, and said graftlinking monomer being polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups, at least one of which polymerizes at a substantially different rate of polymerization from at least one other of said reactive groups; and ii. a monomer system comprising at least 50 percent by weight butadiene and 0 to 50 percent by weight of a different ethylenically unsaturated monomer, the weight ratio of B to A being about 1:2 to 4:1.
Claim 2
Dependent Claim 191 words
A synergistic impact modifier system for poly(C 2 to C 8 alkylene terephthalate) comprising A. one or more thermoplastic segmented copolyester elastomers, and B. one or more multiphase composite interpolymers comprising a final rigid thermoplastic phase polymerized in the presence of a first elastomeric phase polymerized from a monomer system selected from the group consisting of i. a monomer system comprising about 75 to 99.8% by weight C 1 to C 8 alkyl acrylate, 0.1 to 5% by weight crosslinking monomer, 0.1 to 5% by weight graftlinking monomer, said crosslinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups all of which polymerize at substantially the same rate of reaction, and said graftlinking monomer being polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups, at least one of which polymerizes at a substantially different rate of polymerization from at least one other of said reactive groups; and ii. a monomer system comprising at least 50 percent by weight butadiene and 0 to 50 percent by weight of a different ethylenically unsaturated monomer, the weight ratio of B to A being about 1:2 to 4:1.
Claim 3
Dependent Claim 18 words
The synergistic impact modifier system of claim 1 wherein said graftlinking monomer is allyl methacrylate or diallyl maleate.
Claim 4
Dependent Claim 15 words
The synergistic impact modifier system of claim 1 wherein the crosslinking monomer is butylene diacrylate.
Claim 5
Dependent Claim 36 words
The synergistic impact modifier system of claim 1 wherein the final rigid thermoplastic phase is polymerized from a monomer system comprising about 50 to 100 weight percent of a C 1 to C 4 alkyl methacrylate.
Claim 6
Dependent Claim 30 words
The synergistic impact modifier system of claim 1 wherein the multiphase composite interpolymer includes an intermediate phase polymerized from a monomer system comprising about 75 to 100% by weight styrene.
Claim 7
Dependent Claim 22 words
The synergistic impact modifier system of claim 1 wherein the thermoplastic segmented copolyester has an intrinsic viscosity of at least about 1.0.
Claim 8
Dependent Claim 41 words
The synergistic impact modifier system of claim 1 wherein the segmented thermoplastic copolyester elastomer is the condensation product of one or more long chain glycols, one or more short chain glycols, and one or more saturated dicarboxylic acids or esters thereof.
Claim 9
Dependent Claim 36 words
The synergistic impact modifier system of claim 7 wherein the long chain glycol is selected from the group consisting of poly(C 1 to C 6 alkylene ether glycols) of molecular weight of about 400 to 6000.
Claim 10
Dependent Claim 27 words
The synergistic impact modifier system of claim 7 wherein the short chain glycol is selected from the group consisting of C 2 to C 4 alkylene glycol.
Claim 11
Dependent Claim 18 words
The synergistic impact modifier system of claim 7 wherein the dicarboxylic acid or ester derivative thereof is aromatic.
Claim 12
Dependent Claim 24 words
The synergistic impact modifier system of claim 7 wherein the dicarboxylic acid or ester derivative thereof is a mixture dimethyl terephthalate and dimethyl isophthalate.
Claim 13
Dependent Claim 31 words
An injection moldable composition comprising one or more poly(C 2 to C 8 alkylene terephthalates) and about 1 to 40% by weight of the synergistic impact modifier system of claim 1.
Claim 14
Dependent Claim 25 words
The injection moldable composition of claim 12 wherein the poly(C 2 to C 8 alkylene terephthalate) has an intrinsic viscosity of about 0.5 to 2.
Claim 15
Dependent Claim 25 words
The injection moldable composition of claim 12 further including about 10 to 50 weight percent inorganic particulate filler, based on total weight of the blend.
Claim 16
Dependent Claim 24 words
The injection moldable composition of claim 12 further including about 10 to 50 weight percent fibrous reinforcement based on total weight of the blend.
Claim 17
Dependent Claim 13 words
The injection moldable composition of claim 15 wherein the fibrous reinforcement is glass.
Claim 18
Dependent Claim 19 words
The injection moldable composition of claim 12 wherein the poly(C 2 to C 8 alkylene terephthalate) is polybutylene terephthalate.
Claim 19
Dependent Claim 28 words
A process for improving the impact strength of poly(C 2 to C 8 alkylene terephthalate) injection molding composition comprising blending therewith the synergistic impact modifier of claim 1.

References Cited (Backward Citations)

US3864428A Cited
US3954689A Cited
US4096202A Cited
US4096202B1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-29 1983-10-29 1984-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-29 1987-10-29 1988-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-29 1991-10-29 1992-04-29 $7700.00 Window Closed / Lapsed

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