Sequenced surfactant oligomers, process for preparing the same and compositions containing the same

Claim 2

A cosmetic composition for application to and for use in the care of the skin, nails or hair comprising a cosmetic carrier and 0.1-80 weight percent based on the total weight of the composition of a sequenced oligomer surfactant of the formula: P--O --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR30## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR31## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O--, wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents a member selected from: ##STR32## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydroxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 SO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊕ HV and R 1 R 2 N--O.sup.⊕ HV.sup.⊖ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1; m represents a whole or decimal number from 2 to 10; and n and n' represent a whole or decimal number from 2 to 25, with one of n and n' capable of being 0.

Claim 3

The cosmetic composition of claim 1 wherein said carrier is water or a water-alcohol solution wherein said alcohol is an alcohol of 1-4 carbon atoms and is present in an amount from 5 to 70 percent by weight of said composition.

Claim 4

The cosmetic composition of claim 1 in the form of a cream, a gel, an emulsion or an aerosol.

Claim 5

The cosmetic composition of claim 1 in the form of a hair shampoo.

Claim 6

The cosmetic composition of claim 4 which also includes another surfactant selected from an anionic, a cationic, an amphoteric or a non-ionic surfactant.

Claim 7

The cosmetic composition of claim 4 which also includes a cosmetic resin.

Claim 8

The cosmetic composition of claim 1 in the form of a hair conditioner.

Claim 9

The cosmetic composition of claim 1 which also includes a hair dye in an amount effective to dye the hair.

Claim 10

The cosmetic composition of claim 1 having a pH ranging from 3-12.

Claim 11

The cosmetic composition of claim 1 having a pH ranging from 4-10.

Claim 12

The cosmetic composition of claim 1 which also includes an effective amount of a cosmetic adjuvant selected from an acidifying agent, an alkalizing agent, an opacifier, a sequesterant, a super fatting agent, an antiseptic, a preservative, a treating product, a polymer, a perfume, a dye, a dye solvent, a solar filter, an oxidizing agent or an anionic, cationic, nonionic or amphoteric surfactant.

Claim 13

A process for treating the hair comprising applying to the hair an effective amount of the cosmetic composition of claim 1.

Claim 14

A process for dyeing the hair comprising applying to the hair an effective amount of the cosmetic composition of claim 8.

Claim 15

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR33## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR34## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents OH; m represents a whole or decimal number from 2 to 10; and n and n' represent a whole or decimal number from 2 to 25; with one of n and n' capable of being 0, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 16

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR33## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR34## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents OH; m represents a whole or decimal number from 2 to 10; and n and n' represent a whole or decimal number from 2 to 25; with one of n and n' capable of being 0, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 17

The cosmetic composition of claim 6, wherein said resin is present in an amount from 1 to 3 weight percent based on the total weight of the composition.

Claim 18

The cosmetic composition of claim 1, which includes 1 to 20 weight percent, based on the total weight of the composition, of a thickening agent.

Claim 19

The cosmetic composition of claim 4, which includes 1 to 20 weight percent, based on the total weight of the composition, of a thickening agent.

Claim 20

The cosmetic composition of claim 1, wherein said application and use is to areas which necessitate a very weak aggressiveness vis-a-vis the skin or the ocular mucous, by said composition.

Claim 21

The cosmetic composition of claim 1, in which B is OH.

Claim 22

The cosmetic composition of claim 1, wherein B is (b)-(g).

Claim 23

The cosmetic composition of claim 1, wherein each of n and n' is 2-25.

Claim 24

The cosmetic composition of claim 1, wherein B is (b)-(g) and wherein each of n and n' is 2-25.

Claim 25

The cosmetic composition of claim 1, wherein n is 0.

Claim 26

The cosmetic composition of claim 23, wherein P is alkyl.

Claim 27

The cosmetic composition of claim 23, wherein B is (b)-(g).

Claim 28

The cosmetic composition of claim 24, wherein B is (b)-(g).

Claim 29

The cosmetic composition of claim 1, wherein n' is 0.

Claim 30

The cosmetic composition of claim 27, wherein P is alkyl.

Claim 31

The cosmetic composition of claim 27, wherein B is (b)-(g).

Claim 32

The cosmetic composition of claim 28, wherein B is (b)-(g).

Claim 33

The cosmetic composition of claim 19 in the form of a hair shampoo.

Claim 34

The cosmetic composition of claim 20 in the form of a hair shampoo.

Claim 35

The cosmetic composition of claim 21 in the form of a hair shampoo.

Claim 36

The cosmetic composition of claim 22 in the form of a hair shampoo.

Claim 37

The cosmetic composition of claim 26 in the form of a hair shampoo.

Claim 38

The cosmetic composition of claim 27 in the form of a hair shampoo.

Claim 39

The cosmetic composition of claim 19, which also includes a hair dye in an amount effective to dye the hair.

Claim 40

The cosmetic composition of claim 20, which also includes a hair dye in an amount effective to dye the hair.

Claim 41

The cosmetic composition of claim 21, which also includes a hair dye in an amount effective to dye the hair.

Claim 42

The cosmetic composition of claim 22, which also includes a hair dye in an amount effective to dye the hair.

Claim 43

The cosmetic composition of claim 26, which also includes a hair dye in an amount effective to dye the hair.

Claim 44

The cosmetic composition of claim 30 which also includes a hair dye in an amount effective to dye the hair.

Claim 45

The cosmetic composition of claim 19, which also includes an effective amount of a cosmetic adjuvant selected from an acidifying agent, an alkalizing agent, an opacifier, a sequesterant, a super fatting agent, an antiseptic, a preservative, a treating product, a polymer, a perfume, a dye, a dye solvent, a solar filter, an oxidizing agent or an anionic, cationic, nonionic or amphoteric surfactant.

Claim 46

The cosmetic composition of claim 20, which also includes an effective amount of a cosmetic adjuvant selected from an acidifying agent, an alkalizing agent, an opacifier, a sequesterant, a super fatting agent, an antiseptic, a preservative, a treating product, a polymer, a perfume, a dye, a dye solvent, a solar filter, an oxidizing agent or an anionic, cationic, nonionic or amphoteric surfactant.

Claim 47

The cosmetic composition of claim 21, which also includes an effective amount of a cosmetic adjuvant selected from an acidifying agent, an alkalizing agent, an opacifier, a sequesterant, a super fatting agent, an antiseptic, a preservative, a treating product, a polymer, a perfume, a dye, a dye solvent, a solar filter, an oxidizing agent or an anionic, cationic, nonionic or amphoteric surfactant.

Claim 48

The cosmetic composition of claim 22, which also includes an effective amount of a cosmetic adjuvant selected from an acidifying agent, an alkalizing agent, an opacifier, a sequesterant, a super fatting agent, an antiseptic, a preservative, a treating product, a polymer, a perfume, a dye, a dye solvent a solar filter, an oxidizing agent or an anionic, cationic, nonionic or amphoteric surfactant.

Claim 49

The cosmetic composition of claim 26, which also includes an effective amount of a cosmetic adjuvant selected from an acidifying agent, an alkalizing agent, an opacifier, a sequesterant, a super fatting agent, an antiseptic, a presevative, a treating product, a polymer, a perfume, a dye, a dye solvent, a solar filter, an oxidizing agent or an anionic, cationic, nonionic or amphoteric surfactant.

Claim 50

The cosmetic composition of claim 30, which also includes an effective amount of a cosmetic adjuvant selected from an acidifying agent, an alkalizing agent, an opacifier, a sequesterant, a super fatting agent, an antiseptic, a preservative, a treating product, a polymer, a perfume, a dye, a dye solvent, a solar filter, an oxidizing agent or an anionic, cationic, nonionic or amphoteric surfactant.

Claim 51

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n, --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR35## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR36## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B repesents a member selected from the group consisting of: ##STR37## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydroxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 CO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1; m represents a whole or decimal number from 2 to 10; and n and n' represent a whole or decimal number from 2 to 25, with one of n and n' capable of being 0, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 52

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n, --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR35## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR36## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B repesents a member selected from the group consisting of: ##STR37## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydroxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 CO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1; m represents a whole or decimal number from 2 to 10; and n and n' represent a whole or decimal number from 2 to 25, with one of n and n' capable of being 0, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 53

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR38## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR39## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents a member selected from: ##STR40## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydroxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 SO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1, m represents a whole or decimal number from 2 to 10; and n and n' represent a whole or decimal number from 2 to 25, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 54

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR38## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR39## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents a member selected from: ##STR40## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydroxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 SO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1, m represents a whole or decimal number from 2 to 10; and n and n' represent a whole or decimal number from 2 to 25, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 55

The composition of claim 50, wherein B is (b)-(g).

Claim 56

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m H wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR41## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR42## represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents a member selected from: ##STR43## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydoxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 SO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1; m represents a whole or decimal number from 2 to 10; and n' represents a whole or decimal number from 2 to 25, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 57

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' --C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m H wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR41## --C 2 H 3 (CH 2 A)O-- represents the two isomers: ##STR42## represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents a member selected from: ##STR43## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydoxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 SO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1; m represents a whole or decimal number from 2 to 10; and n' represents a whole or decimal number from 2 to 25, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 58

The composition of claim 52, wherein B is (b)-(g).

Claim 59

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR44## --C 2 H 3 (CH 2 A)O-- represent the two isomers: ##STR45## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents a member selected from the group consisting of: ##STR46## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydroxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 SO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1; m represents a whole or decimal number from 2 to 10; and n represents a whole or decimal number from 2 to 25, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 60

In a cosmetic or pharmaceutical composition for application to the skin for the care thereof, the improvement comprising as an excipient or carrier for said composition at least one sequenced oligomer of the formula: P--O--C.sub.2 H.sub.3 (CH.sub.2 A)O--.sub.m --C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n Q wherein: --C 2 H 3 (CH 2 B)O-- represents the two isomers: ##STR44## --C 2 H 3 (CH 2 A)O-- represent the two isomers: ##STR45## one of P and Q represents hydrogen and the other represents linear or branched alkyl having from 1-20 carbon atoms; A represents R--CH 2 -- or R'--O-- wherein R represents linear alkyl having from 4-16 carbon atoms and R' represents linear or branched alkyl having from 4-20 carbon atoms; B represents a member selected from the group consisting of: ##STR46## wherein R 1 and R 2 each independently represent alkyl or hydroxyalkyl, having 1-3 carbon atoms or R 1 and R 2 together with the adjacent nitrogen atom form a heterocycle selected from piperidino or morpholino, R 3 represents methyl or ethyl, R 4 represents alkyl, hydroxyalkyl or dihydroxyalkyl, wherein the alkyl has 1-3 carbon atoms, Z.sup.⊖ is an anion selected from HSO 3 .sup.⊖, CH 3 SO 3 .sup.⊖, CH 3 SO 4 .sup.⊖ and CH 3 --C 6 H 4 --SO 3 .sup.⊖, R 1 R 2 N.sup.⊖ HV.sup.⊕ and R 1 R 2 N--O.sup.⊖ HV.sup.⊕ represent a salt of an amine or amine oxide wherein R 1 and R 2 have the meanings given above, and a represents 0 or 1; m represents a whole or decimal number from 2 to 10; and n represents a whole or decimal number from 2 to 25, wherein said oligomer is present in an amount ranging from 0.1 to 80 weight percent of said composition.

Claim 61

The composition of claim 54, wherein B is (b)-(g).