US4199371A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for continuous acid hydrolysis and saccharification
Assignee: Battelle Memorial Institute Inc
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Filing: 1978-03-31
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Granted: 1980-04-22
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Expires: 1998-03-31
Abstract
Abstract Continuous hydrolysis to produce sugars is effected by cyclically immersing a solid, divided lignocellulosic material in a bath of concentrated hydrochloric acid and draining the material between successive immersions so as to dissolve the produced sugars, until the sugar concentration of the acid in the bath has attained a desired value. The solid material and the liquid acid are delivered to a tubular horizontal rotary reactor arranged to provide a bath of the acid, to produce a rotating movement for cyclical immersion of the solid material in the bath of acid and longitudinally displace the solid material undergoing hydrolysis together with the acid of the bath and to continuously discharge solid residue and acid containing dissolved sugars due to overflow by gravity at an outlet end of the reactor.
Inventors
- 👤 Alain Regnault
- 👤 Jean-Pierre Sachetto
- 👤 Herve Tournier
- 👤 Thomas Hamm
- 👤 Jean-Michel Armanet
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 14:27
CPC Classifications
C; C13; C13K; C13K1/00; C13K1/02
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
117 words
A process for continuously producing sugars by hydrolyzing lignocellulosic material with concentrated aqueous hydrochloric acid in a horizontal rotating tubular reactor which comprises the steps of: (a) feeding concentrated aqueous hydrochloric acid to the reactor and forming a liquid bath in the bottom thereof, (b) feeding lignocellulosic material to one end of the reactor, (c) cyclically immersing said material in said acid bath while removing and draining a part of said material between consecutive immersions thereof by rotating the reactor, (d) continuously and simultaneously with said immersing step conveying said material along the length of the reactor; and (e) continuously discharging solid residue and liquid acid containing sugars by gravity from the opposite end of the reactor.
Claim 2
Dependent Claim
117 words
A process for continuously producing sugars by hydrolyzing lignocellulosic material with concentrated aqueous hydrochloric acid in a horizontal rotating tubular reactor which comprises the steps of: (a) feeding concentrated aqueous hydrochloric acid to the reactor and forming a liquid bath in the bottom thereof, (b) feeding lignocellulosic material to one end of the reactor, (c) cyclically immersing said material in said acid bath while removing and draining a part of said material between consecutive immersions thereof by rotating the reactor, (d) continuously and simultaneously with said immersing step conveying said material along the length of the reactor; and (e) continuously discharging solid residue and liquid acid containing sugars by gravity from the opposite end of the reactor.
Claim 3
Dependent Claim
31 words
The process of claim 1, which comprises recycling at least a part of the acid having served for hydrolysis and discharged from the reactor for further use in the hydrolysis process.
Claim 4
Dependent Claim
21 words
The process of claim 1, wherein the material to acid ratio in the reactor is between 1:5 and 1:10 by weight.
Claim 5
Dependent Claim
55 words
The process of claim 1, wherein the hydrochloric acid has a concentration less than 37% by weight, whereby selective hydrolysis of the hemicellulose fraction of the material is effected and whereby a lignocellulose fraction that has retained substantially the same physical form as the lignocellulosic material fed to the reactor is discharged from the reactor.
Claim 6
Dependent Claim
35 words
The process of claim 1 including dividing said lignocellulosic material into fragments during passage through the reactor, the greatest dimension of which is no greater than 1/8 of the internal diameter of the tubular reactor.
Claim 7
Dependent Claim
38 words
The process of claim 1 wherein the hydrolysis is carried out in two successive rotating tubular reactors and includes the step of feeding the solid residue discharged from the first reactor to a second reactor for further hydrolysis.
Claim 8
Dependent Claim
123 words
The process of claim 6, wherein the hydrochloric acid in the first reactor has a concentration of from about 30% to 37% by weight and a heterogeneous mixture comprising a solid nonhydrolyzed lignocellulose fraction mixed with concentrated acid containing sugars formed in the first reactor is discharged therefrom, including separating the lignocellulose fraction from said mixture, washing the fraction with hydrochloric acid at a concentration of about 33-37% by weight and feeding the washed fraction to the second reactor containing hydrochloric acid with a concentration of from 39% to 41% by weight, whereby substantially complete hydrolysis of the lignocellulose fraction is effected thus forming in the second reactor a lignin suspension in concentrated acid containing the dissolved sugars formed during said complete hydrolysis.
Claim 9
Dependent Claim
66 words
The process of claim 1, wherein the hydrochloric acid has a concentration of from about 39 to 41% by weight and a suspension of lignin in the hydrochloric acid containing dissolved sugars is discharged from the reactor including drying the resulting suspension by direct contact with a hot gas flow in an evaporator to provide a powder mixture comprising lignin and the sugars formed by hydrolysis.
Claim 10
Dependent Claim
20 words
The process of claim 8, including separating the sugars from said powder mixture by taking up this mixture with water.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-04-22 | 1983-10-22 | 1984-04-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-04-22 | 1987-10-22 | 1988-04-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-04-22 | 1991-10-22 | 1992-04-22 | $7700.00 | Window Closed / Lapsed |