Liquid crystal mixtures

Claim 2

A nematic liquid crystal mixture having positive anisotropy of the dielectric constants comprising a nematogenic material having a clearing point above 60° C. and one or more compounds of the formula ##STR18## wherein R 1 and R 2 are hydrogen or straight-chain alkyl, provided that at least one of R 1 and R 2 is other than hydrogen and that the sum of the number of carbon atoms present in R 1 and R 2 is at most 9.

Claim 3

A nematic liquid crystal mixture in accordance with claim 1, further comprising as an additional doping agent a compound of the formula ##STR19## wherein R 3 and R 4 are straight-chain alkyl containing a total of at most 14 carbon atoms or R 3 is straight-chain alkyl and R 4 is straight-chain alkoxy containing together a total of at most 8 carbon atoms, and/or a compound of the formula ##STR20## wherein R 5 and R 6 are straight-chain alkyl containing together a total of at most 6 carbon atoms, and/or a compound of the formula ##STR21## wherein R 7 and R 8 are the same as R 5 and R 6 described above, and/or any other organic solvent or solvent mixture having a specific resistance of at least 10 7 ohm cm.

Claim 4

A nematic liquid crystal mixture in accordance with claim 2, wherein the compound of formula I is present in an amount in the range of from about 1 wt.% to about 20 wt.%.

Claim 5

A nematic liquid crystal mixture in accordance with claim 3, wherein the compound of formula I is present in an amount in the range of from about 5 wt.% to about 15 wt.%.

Claim 6

A nematic liquid crystal mixture in accordance with claim 4, wherein the number of carbon atoms present in each of R 1 and R 2 in the compound of formula I is 2-6.

Claim 7

A nematic liquid crystal mixture in accordance with claim 5, wherein the compound of formula I is 1-n-hexyl-4-cyclohexyl-benzene, 1-n-butyl-4-cyclohexyl-benzene, 1-methyl-4-(4-n-butyl-cyclohexyl)-benzene, 1-ethyl-4-(4-n-butyl-cyclohexyl)-benzene, 1-n-propyl-(4-n-propyl-cyclohexyl)-benzene, 1-ethyl-4-(4-n-propyl-cyclohexyl)-benzene or (4-n-butyl-cyclohexyl)-benzene.

Claim 8

A nematic liquid crystal mixture in accordance with any one of claims 1, 2, 3, 4, 5 or 6, wherein the nematogenic material comprises one or more compounds of the formula ##STR22## wherein R 9 is straight-chain alkyl of 2 to 8 carbon atoms, straight-chain alkoxy of 4 to 7 carbon atoms, straight-chain alkanoyloxy of 2 to 8 carbon atoms or straight-chain alkylcarbonate of 2 to 11 carbon atoms, and/or one or more compounds of the formula ##STR23## wherein R 10 is straight-chain alkyl of 4 to 7 carbon atoms or straight-chain alkylcarbonate of 2 to 11 carbon atoms, and/or one or more compounds of the formula ##STR24## wherein R 11 is straight-chain alkyl of 4 to 8 carbon atoms, straight-chain alkoxy of 5 to 8 carbon atoms, straight-chain alkanoyloxy of 2 to 8 carbon atoms or straight-chain alkylcarbonate of 3 to 11 carbon atoms, and/or one or more compounds of the formula ##STR25## wherein R 12 is straight-chain alkyl of 4 to 8 carbon atoms, straight-chain alkoxy of 4 to 8 carbon atoms, straight-chain alkanoyloxy of 4 to 9 carbon atoms or straight-chain alkylcarbonate of 4 to 11 carbon atoms, and/or one or more trans-cinnamic acid esters of the formula ##STR26## wherein R 13 is straight-chain alkyl of 1 to 8 carbon atoms, and/or one or more compounds of the formula ##STR27## wherein one of R 14 and R 15 are cyano and the other is straight-chain alkyl of 3 to 9 carbon atoms, straight-chain alkoxy of 2 to 9 carbon atoms or straight-chain alkanoyloxy of 2 to 9 carbon atoms, and/or one or more compounds of the formula ##STR28## wherein one of R 16 and R 17 is hydrogen, straight-chain alkyl of 1 to 7 carbon atoms, straight-chain alkoxy of 1 to 7 carbon atoms or straight-chain alkanoyloxy of 2 to 7 carbon atoms and the other is cyano and one of X, Y and Z is nitrogen and the two others are a CH group, and/or one or more compounds of the formula ##STR29## wherein R 18 and R 19 are straight-chain alkyl of 1 to 10 carbon atoms, straight-chain alkoxy of 1 to 10 carbon atoms, straight-chain alkanoyloxy of 2 to 11 carbon atoms or straight-chain alkylcarbonate of 2 to 11 carbon atoms and R 20 is chlorine, bromine or methyl, and/or one or more compounds of the formula ##STR30## wherein R 21 is straight-chain alkyl of 3 to 8 carbon atoms.

Claim 9

A nematic liquid crystal mixture in accordance with claim 1 which contains p-n-butylbenzoic acid p'-cyanophenyl ester, p-n-pentylbenzoic acid p'-cyanophenyl ester, p-n-hexylbenzoic acid p'-cyanophenyl ester, p-n-heptylbenzoic acid p'-cyanophenyl ester, 5-n-pentyl-2-(4-cyanophenyl)-pyrimidine, 5-n-heptyl-2-(4-cyanophenyl)-pyrimidine, 2-(4-cyanophenyl)-5-(4-n-butylphenyl)-pyrimidine, 1-n-hexyl-4-cyclohexyl-benzene and 4-methyl-4'-n-pentyl-biphenyl.

Claim 10

A nematic liquid crystal mixture in accordance with claim 8 which contains 8.7 wt.% p-n-butylbenzoic acid p'-cyanophenyl ester, 9.84 wt.% p-n-pentylbenzoic acid p'-cyanophenyl ester, 13.35 wt.% p-n-hexylbenzoic acid p'-cyanophenyl ester, 15.02 wt.% p-n-heptylbenzoic acid p'-cyanophenyl ester, 8.35 wt.% 5-n-pentyl-2-(4-cyanophenyl)-pyrimidine, 17.91 wt.% 5-n-heptyl-2-(4-cyanophenyl)-pyrimidine, 15.8 wt.% 2-(4-cyanophenyl)-5-(4-n-butylphenyl)-pyrimidine, 5 wt.% 1-n-hexyl-4-cyclohexyl-benzene and 7 wt.% 4-methyl-4'-n-pentyl-biphenyl.

Claim 11

A nematic liquid crystal mixture in accordance with claim 1 which contains 4'-n-pentyl-4-cyanobiphenyl, 4'-n-pentyloxy-4-cyanobiphenyl, 5-n-pentyl-2-(4-cyanophenyl)-pyrimidine, 5-n-heptyl-2-(4-cyanophenyl)-pyrimidine, 2-(4-cyanophenyl)-5-(4-n-butylphenyl)-pyrimidine, 4-cyano-4"-n-pentyl-p-terphenyl and 1-n-hexyl-4-cyclohexyl-benzene.

Claim 12

A nematic liquid crystal mixture in accordance with claim 10 which contains 37.44 wt.% 4'-n-pentyl-4-cyanobiphenyl, 22.65 wt.% 4'-n-pentyloxy-4-cyanobiphenyl, 5.16 wt.% 5-n-pentyl-2-(4-cyanophenyl)-pyrimidine, 10.49 wt.% 5-n-heptyl-2-(4-cyanophenyl)-pyrimidine, 11.31 wt.% 2-(4-cyanophenyl)-5-(4-n-butylphenyl)-pyrimidine, 7.95 wt.% 4-cyano-4"-n-pentyl-p-terphenyl and 5 wt.% 1-n-hexyl-4-cyclohexyl-benzene.

Claim 13

A nematic liquid crystal mixture in accordance with claim 8 which contains 8.7 wt.% p-n-butylbenzoic acid p'-cyanophenyl ester, 9.84 wt.% p-n-pentylbenzoic acid p'-cyanophenyl ester, 13.35 wt.% p-n-hexylbenzoic acid p'-cyanophenyl ester, 15.02 wt.% p-n-heptylbenzoic acid p'-cyanophenyl ester, 8.35 wt.% 5-n-pentyl-2-(4-cyanophenyl)-pyrimidine, 17.91 wt.% 5-n-heptyl-2-(4-cyanophenyl)-pyrimidine, 15.8 wt.% 2-(4-cyanophenyl)-5-(4-n-butylphenyl)-pyrimidine, 8 wt.% 1-n-hexyl-4-cyclohexyl-benzene and 6 wt.% 4-methyl-4'-n-pentyl-biphenyl.

Claim 14

A nematic liquid crystal mixture in accordance with claim 8 which contains 8.7 wt.% p-n-butylbenzoic acid p'-cyanophenyl ester, 9.84 wt.% p-n-pentylbenzoic acid p'-cyanophenyl ester, 13.35 wt.% p-n-hexylbenzoic acid p'-cyanophenyl ester, 15.02 wt.% p-n-heptylbenzoic acid p'-cyanophenyl ester, 8.35 wt.% 5-n-pentyl-2-(4-cyanophenyl)-pyrimidine, 17.91 wt.% 5-n-heptyl-2-(4-cyanophenyl)-pyrimidine, 15.8 wt.% 2-(4-cyanophenyl)-5-(4-n-butylphenyl)-pyrimidine, 9 wt.% 1-n-hexyl-4-cyclohexyl-benzene and 4 wt.% 4-methyl-4'-n-pentyl-biphenyl.

Claim 15

An electro-optical apparatus comprising a nematic liquid crystal mixture having positive anisotropy of the dielectric constants comprising a nematogenic material having a clearing point above 60° C. and one or more compounds of the formula ##STR31## wherein R 1 and R 2 are hydrogen or straight-chain alkyl, provided that at least one of R 1 and R 2 is other than hydrogen and that the sum of the number of carbon atoms present in R 1 and R 2 is at most 9, disposed between two plate means at least one of which plate means is transparent; means for controlling the optical activity of the cell; and said liquid crystal means having a helical structure in the direction perpendicular to the plate means and the surfaces of the plate means being wall oriented.

Claim 16

An electro-optical apparatus comprising a nematic liquid crystal mixture having positive anisotropy of the dielectric constants comprising a nematogenic material having a clearing point above 60° C. and one or more compounds of the formula ##STR31## wherein R 1 and R 2 are hydrogen or straight-chain alkyl, provided that at least one of R 1 and R 2 is other than hydrogen and that the sum of the number of carbon atoms present in R 1 and R 2 is at most 9, disposed between two plate means at least one of which plate means is transparent; means for controlling the optical activity of the cell; and said liquid crystal means having a helical structure in the direction perpendicular to the plate means and the surfaces of the plate means being wall oriented.

Claim 17

A rotation cell comprising a nematic liquid crystal mixture having positive anisotropy of the dielectric constants comprising a nematogenic material having a clearing point above 60° C. and one or more compounds of the formula ##STR32## wherein R 1 and R 2 are hydrogen or straight-chain alkyl, provided that at least one of R 1 and R 2 is other than hydrogen and that the sum of the number of carbon atoms present in R 1 and R 2 is at most 9, disposed between two plate means at least one of which plate means is transparent; means for controlling the optical activity of the cell; and said liquid crystal means having a helical structure in the direction perpendicular to the plate means and the surfaces of the plate means being wall oriented.

Claim 18

A rotation cell comprising a nematic liquid crystal mixture having positive anisotropy of the dielectric constants comprising a nematogenic material having a clearing point above 60° C. and one or more compounds of the formula ##STR32## wherein R 1 and R 2 are hydrogen or straight-chain alkyl, provided that at least one of R 1 and R 2 is other than hydrogen and that the sum of the number of carbon atoms present in R 1 and R 2 is at most 9, disposed between two plate means at least one of which plate means is transparent; means for controlling the optical activity of the cell; and said liquid crystal means having a helical structure in the direction perpendicular to the plate means and the surfaces of the plate means being wall oriented.