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US4197236A Expired / Lapsed US ⏱️ 0.0 years remaining

Piperidine stabilizers

Assignee: Novartis Corp
•
Filing: 1978-08-07
•
Granted: 1980-04-08
•
Expires: 1998-08-07
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Abstract

Abstract Compounds of the general formula I ##STR1## or their acid addition salts in which one of R 1 and R 3 is --OH and the other is hydrogen and R 2 denotes C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, C 6 -C 10 -aryl or C 7 -C 9 -aralkyl and R 4 and R 5 are hydrogen, C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, C 6 -C 10 -aryl or C 7 -C 9 -aralkyl and R 6 denotes hydrogen, C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, phenyl or benzyl and R 7 is hydrogen or C 1 -C 8 -alkyl and R 8 is hydrogen, oxyl, C 1 -C 12 -alkyl, C 3 -C 6 -alkenyl, C 3 -C 4 -alkinyl, C 2 -C 21 -alkoxyalkyl, C 7 -C 8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-4 C atoms or one of the groups --CH 2 COOR 9 , --CH 2 --CH(R 10 )--OR 11 , --COOR 12 or -- CONHR 12 , in which R 9 is C 1 -C 12 -alkyl, C 3 -C 6 -alkenyl, phenyl, C 7 -C 8 -aralkyl or cyclohexyl and R 10 is hydrogen, methyl or phenyl and R 11 denotes hydrogen or an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C 1 -C 4 -alkyl or C 1 -C 8 -alkoxy and/or by hydroxyl, or a group ##STR2## and R 12 denotes C 1 -C 12 -alkyl, cyclohexyl, phenyl or benzyl and X is --O-- or --NR 13 --, in which R 13 denotes hydrogen, C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl or C 7 -C 9 -aralkyl and A is one of the groups --(C n H 2n )--, which can optionally be interrupted by --S-- or ##STR3## in which n denotes 0 to 12 and Y is one of the groups ##STR4## in which R 7 , R 8 and X have the meaning defined above and R 14 denotes C 1 -C 12 -alkyl, phenyl or tolyl as stabilizers for organic material.

Inventors

  • 👤 Siegfried Rosenberger
  • 👤 Samuel Evans

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:15
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/005; C07; C07C; C07C323/00; C07D; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/40; C07D211/44; C07D211/46; C07D211/56; C07D211/58

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 56 words
A compound of the formula I ##STR41## or its acid addition salt, in which R 2 is C 1 -C 4 -alkyl, R 3 is --OH, R 5 is hydrogen or methyl, R 6 is hydrogen or methyl, R 8 is hydrogen, methyl or acetyl, X is --O-- or --NH-- and n is 0 to 2.
Claim 2
Dependent Claim 56 words
A compound of the formula I ##STR41## or its acid addition salt, in which R 2 is C 1 -C 4 -alkyl, R 3 is --OH, R 5 is hydrogen or methyl, R 6 is hydrogen or methyl, R 8 is hydrogen, methyl or acetyl, X is --O-- or --NH-- and n is 0 to 2.
Claim 3
Dependent Claim 9 words
The compound according to claim 1, namely 2,2,6,6-tetramethyl-N-acetyl-piperidin-4-yl di-(3-t-butyl-6-methyl-4-hydroxy-phenyl)-acetate.
Claim 4
Dependent Claim 9 words
The compound according to claim 1, namely 1,2,2,6,6-pentamethyl-piperidin-4-yl 4,4-di-(4-hydroxy-3-t-butyl-phenyl)-valerate.
Claim 5
Dependent Claim 10 words
The compound according to claim 1, namely 4,4-di-(4-hydroxy-3-t-butyl-phenyl)-valeric acid (2,2,6,6-tetramethyl-piperidin-4-yl)-amide.
Claim 6
Dependent Claim 14 words
A composition consisting essentially of a plastic and a compound according to claim 1.

References Cited (Backward Citations)

US3414538A Cited
US3422059A Cited
US3640928A Cited
US3684765A Cited
US3992390A Cited
US4021432A Cited
US3993655A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-08 1983-10-08 1984-04-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-08 1987-10-08 1988-04-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-08 1991-10-08 1992-04-08 $7700.00 Window Closed / Lapsed

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