Photographic products and processes employing nondiffusible 6-arylazo-2-amino-3-pyridinol dye-releasing compounds and precursors thereof

Claim 2

A photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer, said emulsion layer having associated therewith a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through a sulfonamido linking group or through the oxygen of a ##STR24## which said ballasted carrier moiety contains, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions.

Claim 3

The photographic element of claim 1 wherein said compound has the formula: ##STR25## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p --where each R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 14 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) each R 2 represents a hydrogen atom, an alkyl or substituted alkyl group having 1 to about 6 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms; (g) CAR represents said ballasted carrier moiety; (h) t is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR26## and is attached to the phenyl group through the oxygen of said ##STR27## and (i) G represents hydroxy or a precursor thereof.

Claim 4

The photographic element of claim 1 wherein said compound has the formula: ##STR28## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p -- where each R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 14 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) CAR represents said ballasted carrier moiety; (g) t is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR29## and is attached to the phenyl group through the oxygen of said ##STR30## and (h) G represents hydroxy or a precursor thereof.

Claim 5

The photographic element of claim 2 wherein CAR is a group having the formula: (Ballast-Carrier)- wherein: (a) Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; and (b) Carrier is an oxidizable acyclic, carbocyclic or heterocyclic moiety.

Claim 6

The photographic element of claim 4 wherein the Carrier moiety contains atoms according to the following configuration: a(--C═C).sub.b -- wherein: b is a positive integer of 1 to 2; and a represents the radicals OH, SH, NH--, or hydrolyzable precursors thereof.

Claim 7

The photographic element of claim 2 wherein CAR is a group having the formula: ##STR31## wherein: (a) Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; (b) D is OR 4 or NHR 5 wherein R 4 is hydrogen or a hydrolyzable moiety and R 5 is hydrogen or a substituted or unsubstituted alkyl group of 1 to 22 carbon atoms; (c) Y represents the atoms necessary to complete a benzene nucleus, a naphthalene nucleus, or a 5 to 7 membered heterocyclic ring; and (d) j is a positive integer of 1 to 2 and is 2 when D is OR 4 or when R 5 is hydrogen or an alkyl group of less than 8 carbon atoms.

Claim 8

The photographic element of claim 6 wherein D is OH, j is 2, Y is a naphthalene nucleus, R is H, each R 2 is H, X is a phenylene radical, and the phenyl group is substituted with a nitro group para to the azo linkage.

Claim 9

The photographic element of claim 1 wherein said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof is released as an inverse function of said development of said silver halide emulsion layer under alkaline conditions.

Claim 10

The photographic element of claim 8 wherein said ballasted carrier moiety is a group having the formula: ##STR32## wherein: Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; W 1 represents at least the atoms necessary to complete a quinone nucleus; r is a positive integer of 1 or 2; R 6 is an alkyl radical having 1 to about 40 carbon atoms or an aryl radical having 6 to about 40 carbon atoms; and k is a positive integer of 1 to 2 and is 2 when R 6 is a radical of less than 8 carbon atoms.

Claim 11

The photographic element of claim 8 wherein said ballasted carrier moiety is a group having the formula: ##STR33## wherein: Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; W 2 represents at least the atoms necessary to complete a benzene nucleus; and R 7 is an alkyl radical having 1 to about 4 carbon atoms.

Claim 12

The photographic element of claim 8 wherein said ballasted carrier moiety is a group having the formula: ##STR34## wherein: Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; W 2 represents at least the atoms necessary to complete a benzene nucleus; and R 7 is an alkyl radical having 1 to about 4 carbon atoms.

Claim 13

The photographic element of claim 8 wherein said ballasted carrier moiety is a group having the formula: ##STR35## wherein: Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; W 2 represents at least the atoms necessary to complete a benzene nucleus; r is a positive integer of 1 or 2; R 6 is an alkyl radical having 1 to about 40 carbon atoms or an aryl radical having 6 to about 40 carbon atoms; k is a positive integer of 1 to 2 and is 2 when R 6 is a radical of less than 8 carbon atoms; and K is OH or a hydrolyzable precursor thereof.

Claim 14

The photographic element of claim 1 wherein said dye-releasing compound is: ##STR36##

Claim 15

The photographic element of claim 1 wherein said dye-releasing compound is: ##STR37##

Claim 16

In a photographic assemblage comprising: (a) a support having thereon at least one photosensitive silver halide emulsion layer having associated therewith a dye image-providing material; (b) a dye image-receiving layer; and (c) an alkaline processing composition and means for discharging same within said assemblage; said assemblage containing a silver halide developing agent, the improvement wherein said dye image-providing material is a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through a sulfonamido linking group or through the oxygen of a ##STR38## which said ballasted carrier moiety contains, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions.

Claim 17

In a photographic assemblage comprising: (a) a support having thereon at least one photosensitive silver halide emulsion layer having associated therewith a dye image-providing material; (b) a dye image-receiving layer; and (c) an alkaline processing composition and means for discharging same within said assemblage; said assemblage containing a silver halide developing agent, the improvement wherein said dye image-providing material is a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through a sulfonamido linking group or through the oxygen of a ##STR38## which said ballasted carrier moiety contains, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions.

Claim 18

The photographic assemblage of claim 15 wherein said compound has the formula: ##STR39## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p -- where each R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 14 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) each R 2 represents a hydrogen atom, an alkyl or substituted alkyl group having 1 to about 6 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms; (g) CAR represents said ballasted carrier moiety; (h) t is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR40## and is attached to the phenyl group through the oxygen of said ##STR41## and (i) G represents hydroxy or a precursor thereof.

Claim 19

The photographic assemblage of claim 15 wherein said compound has the formula: ##STR42## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p -- where each R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 14 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) CAR represents said ballasted carrier moiety; (g) t is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR43## and is attached to the phenyl group through the oxygen of said ##STR44## and (h) G represents hydroxy or a precursor thereof.

Claim 20

The photographic assemblage of claim 16 wherein CAR is a group having the formula: (Ballast-Carrier)- wherein: (a) Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; and (b) Carrier is an oxidizable acyclic, carbocyclic or heterocyclic moiety.

Claim 21

The photographic assemblage of claim 18 wherein the Carrier moiety contains atoms according to the following configuration: a(--C═C).sub.b -- wherein: b is a positive integer of 1 to 2; and a represents the radicals OH, SH, NH--, or hydrolyzable precursors thereof.

Claim 22

The photographic assemblage of claim 15 wherein said dye image-receiving layer or a layer adjacent thereto contains metal ions.

Claim 23

The photographic assemblage of claim 20 wherein: (a) said dye image-receiving layer is located between said support and said silver halide emulsion layer; and (b) said assemblage also includes a transparent cover sheet over the layer outermost from said support.

Claim 24

The photographic assemblage of claim 21 wherein said cover sheet has thereon, in sequence, a neutralizing layer and a timing layer.

Claim 25

The photographic assemblage of claim 22 wherein said discharging means is a rupturable container containing said alkaline processing composition and an opacifying agent, said container being so positioned during processing of said assemblage that a compressive force applied to said container will effect a discharge of the container's contents between said transparent sheet and the layer outermost from said support.

Claim 26

The photographic assemblage of claim 20 wherein said support having thereon said photosensitive silver halide emulsion layer is opaque and said dye image-receiving layer is located on a separate transparent support superposed over the layer outermost from said opaque support.

Claim 27

The photographic assemblage of claim 24 wherein said transparent support has thereon, in sequence, a neutralizing layer, a timing layer, and said dye image-receiving layer.

Claim 28

In an integral photographic assemblage comprising: (a) a photosensitive element comprising a transparent support having thereon the following layers in sequence: a dye image-receiving layer, an alkaline solution-permeable, light-reflective layer, an alkaline solution-permeable, opaque layer, a red-sensitive silver halide emulsion layer having a ballasted cyan dye releaser associated therewith, a green-sensitive silver halide emulsion layer having a ballasted magenta dye releaser associated therewith, and a blue-sensitive silver halide emulsion layer having a ballasted yellow dye releaser associated therewith; (b) a transparent sheet superposed over said blue-sensitive silver halide emulsion layer and comprising a transparent support having thereon, in sequence, a neutralizing layer and a timing layer; and (c) a rupturable container containing an alkaline processing composition and an opacifying agent which is so positioned during processing of said assemblage that a compressive force applied to said container will effect a discharge of the container's contents between said transparent sheet and said blue-sensitive silver halide emulsion layer; said assemblage containing a silver halide developing agent; the improvement wherein at least one of said ballasted dye releasers is a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through a sulfonamido linking group or through the oxygen of a ##STR45## which said ballasted carrier moiety contains, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions.

Claim 29

In an integral photographic assemblage comprising: (a) a photosensitive element comprising a transparent support having thereon the following layers in sequence: a dye image-receiving layer, an alkaline solution-permeable, light-reflective layer, an alkaline solution-permeable, opaque layer, a red-sensitive silver halide emulsion layer having a ballasted cyan dye releaser associated therewith, a green-sensitive silver halide emulsion layer having a ballasted magenta dye releaser associated therewith, and a blue-sensitive silver halide emulsion layer having a ballasted yellow dye releaser associated therewith; (b) a transparent sheet superposed over said blue-sensitive silver halide emulsion layer and comprising a transparent support having thereon, in sequence, a neutralizing layer and a timing layer; and (c) a rupturable container containing an alkaline processing composition and an opacifying agent which is so positioned during processing of said assemblage that a compressive force applied to said container will effect a discharge of the container's contents between said transparent sheet and said blue-sensitive silver halide emulsion layer; said assemblage containing a silver halide developing agent; the improvement wherein at least one of said ballasted dye releasers is a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through a sulfonamido linking group or through the oxygen of a ##STR45## which said ballasted carrier moiety contains, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions.

Claim 30

The photographic assemblage of claim 26 wherein said compound has the formula: ##STR46## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p -- where R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 4 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) each R 2 represents a hydrogen atom, an alkyl or substituted alkyl group having 1 to about 6 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms; (g) CAR represents said ballasted carrier moiety; (h) t is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR47## and is attached to the phenyl group through the oxygen of said ##STR48## and (i) G represents hydroxy or a precursor thereof.

Claim 31

The photographic assemblage of claim 26 wherein said compound has the formula: ##STR49## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p -- where each R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 14 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) CAR represents said ballasted carrier moiety; (g) t is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR50## and is attached to the phenyl group through the oxygen of said ##STR51## and (h) G represents hydroxy or a precursor thereof.

Claim 32

The photographic assemblage of claim 26 wherein said dye image-receiving layer or a layer adjacent thereto contains metal ions.

Claim 33

A process for producing a photographic transfer image in color in an imagewise-exposed photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer, said emulsion layer having associated therewith a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through the sulfonamido linking group or through the oxygen of a ##STR52## which said ballasted carrier moiety contains, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions, said process comprising: (a) treating said photographic element with an alkaline processing composition in the presence of a silver halide developing agent to effect development of each of the exposed silver halide emulsion layers; (b) said dye-releasing compound then releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof imagewise as a function of said development of each of said silver halide emulsion layers; (c) at least a portion of said imagewise distribution of said 6-arylazo-2-amino-3-pyridinol dye or precursor thereof diffusing to a dye image-receiving layer; and (d) contacting said imagewise distribution of said 6-arylazo-2-amino-3-pyridinol dye or precursor thereof with metal ions, thereby forming a metal-complexed, 6-arylazo-2-amino-3-pyridinol dye transfer image.

Claim 34

A process for producing a photographic transfer image in color in an imagewise-exposed photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer, said emulsion layer having associated therewith a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through the sulfonamido linking group or through the oxygen of a ##STR52## which said ballasted carrier moiety contains, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions, said process comprising: (a) treating said photographic element with an alkaline processing composition in the presence of a silver halide developing agent to effect development of each of the exposed silver halide emulsion layers; (b) said dye-releasing compound then releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof imagewise as a function of said development of each of said silver halide emulsion layers; (c) at least a portion of said imagewise distribution of said 6-arylazo-2-amino-3-pyridinol dye or precursor thereof diffusing to a dye image-receiving layer; and (d) contacting said imagewise distribution of said 6-arylazo-2-amino-3-pyridinol dye or precursor thereof with metal ions, thereby forming a metal-complexed, 6-arylazo-2-amino-3-pyridinol dye transfer image.

Claim 35

The process of claim 30 wherein said compound has the formula: ##STR53## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p -- where each R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 14 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) each R 2 represents a hydrogen atom, an alkyl or substituted alkyl group having 1 to about 6 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms; (g) CAR represents said ballasted carrier moiety; (h) t is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR54## and is attached to the phenyl group through the oxygen of said ##STR55## and (i) G represents hydroxy or a precursor thereof.

Claim 36

The process of claim 30 wherein said compound has the formula: ##STR56## wherein: (a) X represents a bivalent linking group of the formula --R 1 --L n --R 1 p -- where each R 1 can be the same or different and each represents an alkylene radical having 1 to about 8 carbon atoms; a phenylene radical; or a substituted phenylene radical having 6 to about 9 carbon atoms; (b) L represents a bivalent radical selected from oxy, imino, carbonyl, carboxamido, carbamoyl, sulfonamido, ureylene, sulfamoyl, sulfinyl or sulfonyl; (c) n is an integer of 0 or 1; (d) p is 1 when n equals 1 and p is 1 or 0 when n equals 0, provided that when p is 1 the carbon content of the sum of both R 1 radicals does not exceed 14 carbon atoms; (e) R represents a hydrogen atom, a hydrolyzable acyl group having the formula --COR 3 or --COOR 3 , wherein R 3 is an alkyl or substituted alkyl group having 1 to about 4 carbon atoms or an aryl or substituted aryl group having 6 to about 8 carbon atoms, or a hydrolyzable alkanesulfonyl group having 1 to about 4 carbon atoms; (f) CAR represents said ballasted carrier moiety; (g) ti is an integer of 0 or 1, with the proviso that when t is 0 then CAR contains a ##STR57## and is attached to the phenyl group through the oxygen of said ##STR58## and (h) G represents hydroxy or a precursor thereof.

Claim 37

A process for producing a photographic transfer image in color in an imagewise-exposed photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer, said emulsion layer having associated therewith a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto through a sulfonamido linking group, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions, said ballasted carrier moiety being a group having the formula: ##STR59## wherein: (a) Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; (b) D is OR 4 or NHR 5 wherein R 4 is hydrogen or a hydrolyzable moiety and R 5 is hydrogen or a substituted or unsubstituted alkyl group of 1 to 22 carbon atoms; (c) Y represents the atoms necessary to complete a benzene nucleus, a naphthalene nucleus, or a 5 to 7 membered heterocyclic ring; and (d) j is a positive integer of 1 to 2 and is 2 when D is OR 4 or when R 5 is hydrogen or an alkyl group of less than 8 carbon atoms, said process comprising: (1) treating said photographic element with an alkaline processing composition in the presence of a silver halide developing agent to effect development of each of the exposed silver halide emulsion layers, thereby oxidizing the said developing agent; (2) said oxidized developing agent thereby cross-oxidizing said dye-releasing compound; (3) said cross-oxidized dye-releasing compound then cleaving as a result of alkaline hydrolysis to release said nondiffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof imagewise as a function of said imagewise exposure of each of said silver halide emulsion layers; (4) at least a portion of said imagewise distribution of said 6-arylazo-2-amino -3-pyridinol dye or precursor thereof diffusing to a dye image-receiving layer; and (5) contacting said imagewise distribution of said 6-arylazo-2-amino-3-pyridinol dye or precursor thereof with metal ions, thereby forming a metal-complexed, 6-arylazo-2-amino-3-pyridinol dye transfer image.

Claim 38

A process for producing a photographic transfer image in color in an imagewise-exposed photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer, said emulsion layer having associated therewith a nondiffusible compound having a releasable, diffusible, 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof where the hydroxy group of said pyridinol is a hydroxy precursor, said compound containing in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto through a sulfonamido linking group, said ballasted carrier moiety being capable of releasing said diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof as a function of development of said silver halide emulsion layer under alkaline conditions, said ballasted carrier moiety being a group having the formula: ##STR59## wherein: (a) Ballast is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition; (b) D is OR 4 or NHR 5 wherein R 4 is hydrogen or a hydrolyzable moiety and R 5 is hydrogen or a substituted or unsubstituted alkyl group of 1 to 22 carbon atoms; (c) Y represents the atoms necessary to complete a benzene nucleus, a naphthalene nucleus, or a 5 to 7 membered heterocyclic ring; and (d) j is a positive integer of 1 to 2 and is 2 when D is OR 4 or when R 5 is hydrogen or an alkyl group of less than 8 carbon atoms, said process comprising: (1) treating said photographic element with an alkaline processing composition in the presence of a silver halide developing agent to effect development of each of the exposed silver halide emulsion layers, thereby oxidizing the said developing agent; (2) said oxidized developing agent thereby cross-oxidizing said dye-releasing compound; (3) said cross-oxidized dye-releasing compound then cleaving as a result of alkaline hydrolysis to release said nondiffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof imagewise as a function of said imagewise exposure of each of said silver halide emulsion layers; (4) at least a portion of said imagewise distribution of said 6-arylazo-2-amino -3-pyridinol dye or precursor thereof diffusing to a dye image-receiving layer; and (5) contacting said imagewise distribution of said 6-arylazo-2-amino-3-pyridinol dye or precursor thereof with metal ions, thereby forming a metal-complexed, 6-arylazo-2-amino-3-pyridinol dye transfer image.

Claim 39

The process of claim 33 wherein D is OH, j is 2, Y is a naphthalene nucleus, R is H, each R 2 is H, X is a phenylene radical, and the phenyl group is substituted with a nitro group para to the azo linkage.