US4194993A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of manufacturing powdered cleaning composition
Assignee: Milliken Research Corp
•
Filing: 1978-03-13
•
Granted: 1980-03-25
•
Expires: 1998-03-13
Abstract
Abstract A method of forming a powdered cleaning composition is disclosed. The process comprises the steps of: polymerizing urea and formaldehyde in acidic aqueous solution to form particles of a specified size and porosity, centrifuging the polymer particles to lower their moisture content to less than about 43%, blending polyethylene oxide into the polymer, spraying a fine mist of detergent solution directly onto the polymer mass as it is being blended. The acid may be neutralized by adding buffer to the solution after the urea and formaldehyde are polymerized or by spraying a mist of buffer containing solution directly onto the polymer as it is being blended.
Inventors
- 👤 James F. Deal, III
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 08:21
CPC Classifications
C; C11; C11D; C11D17/00; C11D17/06; C11D3/00; C11D3/0005; C11D3/0031; C11D3/16; C11D3/37; C11D3/3703; C11D3/3707
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
143 words
A method of preparing a powdered cleaning composition comprising the steps of: polymerizing urea and formaldehyde in aqueous acidic solution to form a mass of polymer particles having an average particle size between about 10 and 105 microns and an oil value of at least about 90; neutralizing the mass of polymer particles; centrifuging the mass of polymer particles until the moisture content of said mass of polymer particles is less than about 43, but more than 30% based on the dry weight of the polymer; sprinkling at least about 0.2% of polyethylene oxide powder having a molecular weight of at least about 20,000 onto freshly blended surfaces of the polymer mass as it is being blended; and spraying sufficient surfactant into the polymer mass to lower the surface tension of the moisture therein to no more than about 40 dynes per centimeter.
Claim 2
Independent Claim
143 words
A method of preparing a powdered cleaning composition comprising the steps of: polymerizing urea and formaldehyde in aqueous acidic solution to form a mass of polymer particles having an average particle size between about 10 and 105 microns and an oil value of at least about 90; neutralizing the mass of polymer particles; centrifuging the mass of polymer particles until the moisture content of said mass of polymer particles is less than about 43, but more than 30% based on the dry weight of the polymer; sprinkling at least about 0.2% of polyethylene oxide powder having a molecular weight of at least about 20,000 onto freshly blended surfaces of the polymer mass as it is being blended; and spraying sufficient surfactant into the polymer mass to lower the surface tension of the moisture therein to no more than about 40 dynes per centimeter.
Claim 3
Independent Claim
214 words
A method of preparing a powdered cleaning composition comprising the steps of: polymerizing urea and formaldehyde in aqueous acidic solution to form a mass of polymer particles having an average particle size between about 10 and 105 microns and an oil value of at least about 90; centrifuging the mass of polymer particles until the moisture content of said mass of polymer particles is less than about 43 but more than 30% based on the dry weight of the polymer; sprinkling at least about 0.2% of polyethylene oxide powder having a molecular weight of at least about 20,000 onto freshly blended surfaces of the polymer mass as it is being blended; spraying a solution of a buffer in water in the form of a mist directly onto the polymer mass and simultaneously blending the polymer mass to continually expose new surface to the spray, the amount of solution being sufficient to maintain the moisture content of the mass of polymer particles to between about 30% and about 43% and the amount of buffer being sufficient to substantially neutralize the residual acid in the mass of polymer particles; and spraying sufficient surfactant directly onto the polymer mass to lower the surface tension of the moisture therein to no more than about 40 dynes per centimeter.
Claim 4
Independent Claim
214 words
A method of preparing a powdered cleaning composition comprising the steps of: polymerizing urea and formaldehyde in aqueous acidic solution to form a mass of polymer particles having an average particle size between about 10 and 105 microns and an oil value of at least about 90; centrifuging the mass of polymer particles until the moisture content of said mass of polymer particles is less than about 43 but more than 30% based on the dry weight of the polymer; sprinkling at least about 0.2% of polyethylene oxide powder having a molecular weight of at least about 20,000 onto freshly blended surfaces of the polymer mass as it is being blended; spraying a solution of a buffer in water in the form of a mist directly onto the polymer mass and simultaneously blending the polymer mass to continually expose new surface to the spray, the amount of solution being sufficient to maintain the moisture content of the mass of polymer particles to between about 30% and about 43% and the amount of buffer being sufficient to substantially neutralize the residual acid in the mass of polymer particles; and spraying sufficient surfactant directly onto the polymer mass to lower the surface tension of the moisture therein to no more than about 40 dynes per centimeter.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-03-25 | 1983-09-24 | 1984-03-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-03-25 | 1987-09-24 | 1988-03-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-03-25 | 1991-09-24 | 1992-03-25 | $7700.00 | Window Closed / Lapsed |