Patent US1699211A successfully refreshed from Google Patents.
US4191684A
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US
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Urea derivatives, their preparation, and their use as light stabilizers
Assignee: Hoechst AG
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Filing: 1978-08-21
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Granted: 1980-03-04
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Expires: 1998-08-21
Abstract
Abstract The invention provides novel 4-carbamoyl derivatives of 1-oxa-3-oxo-4,8-diaza-spiro-[4,5]-decanes and their preparation from 1 oxa-3-oxo-4,8-diaza-spiro-[4,5]-decanes and isocyanates. The products are suitable light stabilizers for thermoplastics.
Inventors
- 👤 Hartmut Wiezer
- 👤 Gerhard Pfahler
- 👤 Norbert Mayer
- 👤 Harald Knorr
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 02:24
CPC Classifications
C; C07; C07D; C07D498/00; C07D498/02; C07D498/10; C07D498/12; C07D498/20; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/35
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
327 words
A compound of the formula (I) ##STR3## in which R 1 and R 2 , being identical or different, each are linear or branched alkyl having from 1 to 12 carbon atoms, or R 1 and R 2 together with the carbon atom to which they are linked form a cyclopentane or cyclohexane ring which may also be methyl-substituted or a 2,2,6,6-tetramethylpiperidine ring the carbon atom 4 of which is identical with the carbon atom 7 of the spirodecane system; R 3 is hydrogen, alkyl or isoalkyl having from 1 to 30 carbon atoms, or phenylalkyl having from 7 to 10 carbon atoms, the aliphatic chain having from 1 to 4 carbon atoms; R 4 is hydrogen, alkyl having from 1 to 30 carbon atoms, phenyl or naphthyl, which may be substituted by a halogen atom, or alkyl radical having from 1 to 4 carbon atoms, or phenylalkyl having from 7 to 10 carbon atoms, the aliphatic chain containing from 1 to 4 of the latter carbon atoms; or R 3 and R 4 together with the carbon atom linking them form a cycloalkane ring having from 4 to 20 carbon atoms; R 5 , when n is 1, is alkyl having from 1 to 20 carbon atoms, alkenyl having from 3 to 18 carbon atoms, cycloalkyl having from 5 to 12 carbon atoms, which may be substituted by C 1 -C 4 -alkyl phenyl or naphthyl which may be substituted by a chlorine atom or alkyl having from 1 to 18 carbon atoms, or phenylalkyl having from 7 to 18 carbon atoms, the aryl ring containing 6 carbon atoms; R 5 , when n is 2, is linear or branched alkylene having from 2 to 20 carbon atoms, phenylene or naphthylene which may be substituted by C 1 -C 4 -alkyl, or phenylalkylene having from 7 to 18 carbon atoms; and R 6 is hydrogen, oxygen, hydroxyl or alkyl having from 1 to 4 carbon atoms.
Claim 2
Dependent Claim
327 words
A compound of the formula (I) ##STR3## in which R 1 and R 2 , being identical or different, each are linear or branched alkyl having from 1 to 12 carbon atoms, or R 1 and R 2 together with the carbon atom to which they are linked form a cyclopentane or cyclohexane ring which may also be methyl-substituted or a 2,2,6,6-tetramethylpiperidine ring the carbon atom 4 of which is identical with the carbon atom 7 of the spirodecane system; R 3 is hydrogen, alkyl or isoalkyl having from 1 to 30 carbon atoms, or phenylalkyl having from 7 to 10 carbon atoms, the aliphatic chain having from 1 to 4 carbon atoms; R 4 is hydrogen, alkyl having from 1 to 30 carbon atoms, phenyl or naphthyl, which may be substituted by a halogen atom, or alkyl radical having from 1 to 4 carbon atoms, or phenylalkyl having from 7 to 10 carbon atoms, the aliphatic chain containing from 1 to 4 of the latter carbon atoms; or R 3 and R 4 together with the carbon atom linking them form a cycloalkane ring having from 4 to 20 carbon atoms; R 5 , when n is 1, is alkyl having from 1 to 20 carbon atoms, alkenyl having from 3 to 18 carbon atoms, cycloalkyl having from 5 to 12 carbon atoms, which may be substituted by C 1 -C 4 -alkyl phenyl or naphthyl which may be substituted by a chlorine atom or alkyl having from 1 to 18 carbon atoms, or phenylalkyl having from 7 to 18 carbon atoms, the aryl ring containing 6 carbon atoms; R 5 , when n is 2, is linear or branched alkylene having from 2 to 20 carbon atoms, phenylene or naphthylene which may be substituted by C 1 -C 4 -alkyl, or phenylalkylene having from 7 to 18 carbon atoms; and R 6 is hydrogen, oxygen, hydroxyl or alkyl having from 1 to 4 carbon atoms.
Claim 3
Dependent Claim
21 words
A compound as claimed in claim 1, in which R 1 and R 2 are methyl and R 6 is hydrogen.
Claim 4
Dependent Claim
70 words
A process for the preparation of a compound as claimed in claim 1 or 2, which comprises reacting a compound of the formula (III) ##STR4## with an isocyanate of the formula (II) R.sup.6 (NCO).sub.n (II), in which formula R 1 to R 6 are as defined in claim 9, in and inert organic solvent at temperatures of from 20° to 180° C. with addition of catalytic amounts of a base.
Claim 5
Dependent Claim
53 words
Process for stablizing halogen-free aliphatic alpha-olefin homo- and copolymers and chlorine-containing vinyl homo- and copolymers against the damaging influence of light, wherein 0.01 to 5 parts by weight, based on the polymer, of a compound of claim 1 or a salt thereof with an inorganic or organic acid, is added to the polymers.
Claim 6
Dependent Claim
36 words
Organic polymers stablized against UV decomposition, containing 0.01 to 5 parts by weight, calculated on the polymers, of a compound as claimed in claim 1 or of a salt thereof with an inorganic or organic acid.
References Cited (Backward Citations)
US4107139A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-03-04 | 1983-09-03 | 1984-03-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-03-04 | 1987-09-03 | 1988-03-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-03-04 | 1991-09-03 | 1992-03-04 | $7700.00 | Window Closed / Lapsed |