US4190641A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for producing hydrogen
Assignee: RTX Corp
•
Filing: 1978-12-06
•
Granted: 1980-02-26
•
Expires: 1998-12-06
Abstract
Abstract In a method for producing high quality hydrogen, the carbon monoxide level of a hydrogen stream which also contains hydrogen sulfide is shifted in a bed of iron oxide shift catalyst to a desired low level of carbon monoxide using less catalyst than the minimum amount of catalyst which would otherwise be required if there were no hydrogen sulfide in the gas stream. Under normal operating conditions the presence of even relatively small amounts of hydrogen sulfide can double the activity of the catalyst such that much less catalyst may be used to do the same job.
Inventors
- 👤 John L. Preston, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 19:51
CPC Classifications
C; C01; C01B; C01B3/00; C01B3/02; C01B3/06; C01B3/12; C01B3/16
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
157 words
A method for producing hydrogen including the step of shift converting a hydrogen containing gas stream under a given set of conditions of length of time, flow rate, temperature, pressure, moles steam to moles carbon ratio, and inlet CO concentration using a chromia stabilized iron oxide shift catalyst, wherein the hydrogen sulfide content of the gas stream is maintained between 20 ppm and 520 ppm on a dry gas volume basis, but in no event more than that which would result in the conversion of the iron oxide to iron sulfide under said given conditions, and wherein the step of shift converting comprises reducing the carbon monoxide concentration of said gas stream to less than p% by volume using an amount "A" of said shift catalyst which is no greater than about two-thirds the minimum amount "B" which would be required under said given set of conditions if there were no hydrogen sulfide in said gas stream.
Claim 2
Independent Claim
157 words
A method for producing hydrogen including the step of shift converting a hydrogen containing gas stream under a given set of conditions of length of time, flow rate, temperature, pressure, moles steam to moles carbon ratio, and inlet CO concentration using a chromia stabilized iron oxide shift catalyst, wherein the hydrogen sulfide content of the gas stream is maintained between 20 ppm and 520 ppm on a dry gas volume basis, but in no event more than that which would result in the conversion of the iron oxide to iron sulfide under said given conditions, and wherein the step of shift converting comprises reducing the carbon monoxide concentration of said gas stream to less than p% by volume using an amount "A" of said shift catalyst which is no greater than about two-thirds the minimum amount "B" which would be required under said given set of conditions if there were no hydrogen sulfide in said gas stream.
Claim 3
Dependent Claim
27 words
The method for producing hydrogen according to claim 1 wherein said gas stream temperature at the inlet of said shift converter is between 600° and 900° F.
Claim 4
Dependent Claim
21 words
The method for producing hydrogen according to claim 2 wherein said inlet CO concentration is between 10 and 15%, by volume.
Claim 5
Independent Claim
71 words
The method for producing hydrogen according to claims 2 or 3 including the step of steam reforming a sulfur containing hydrocarbon feedstock in a reactor using a nickel catalyst wherein the mole ratio of steam to carbon at the inlet of the reactor is between 3 and 8 and the reactor inlet temperature is at least 1500° F., and wherein the effluent from said reactor is said hydrogen containing gas stream.
Claim 6
Dependent Claim
28 words
The method for producing hydrogen according to claim 4 wherein said mole ratio of steam to carbon at the inlet of the reactor is between 3.5 and 4.5.
Claim 7
Dependent Claim
13 words
The method for producing hydrogen according to claim 4 wherein p% is 5%.
Claim 8
Dependent Claim
18 words
The method for producing hydrogen according to claim 6 wherein "A" is no greater than about one-half "B".
Claim 9
Dependent Claim
20 words
The method for producing hydrogen according to claim 7 wherein said gas stream includes at least 250 ppm hydrogen sulfide.
References Cited (Backward Citations)
US2655442A
Cited
US2815331A
Cited
US2892685A
Cited
US3545926A
Cited
US3361534A
Cited
US3684689A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-02-25 | 1983-08-27 | 1984-02-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-02-25 | 1987-08-27 | 1988-02-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-02-25 | 1991-08-27 | 1992-02-26 | $7700.00 | Window Closed / Lapsed |