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US4190564A Expired / Lapsed US ⏱️ 0.0 years remaining

Cationic electrophoretic coating compositions

Assignee: Kansai Paint Co Ltd
•
Filing: 1978-09-14
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Granted: 1980-02-26
•
Expires: 1998-09-14
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Abstract

Abstract A cationic electrophoretic coating composition comprising: (A) a water-soluble or water-dispersible resin prepared by neutralizing with an acid addition products of partially blocked polyisocyanate and the reaction products, said reaction products being prepared by reacting at least one of fatty acid and polyamide with adducts prepared by being allowed an epoxy resin to react with a basic amino compound, and (B) at least one of addition polymers of at least one of ethylene oxide and propylene oxide and derivatives of the addition polymers, the polymers and the derivatives thereof having a number average molecular weight of 500 to 10,000 and having a solubility of up to 60 parts by weight in 100 parts by weight of water at 25° C.

Inventors

  • 👤 Akira Tominaga
  • 👤 Yasuyuki Hirata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 09:33
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0804; C08G18/0809; C08G18/0814; C08G18/70; C08G18/72; C08G18/80; C08G18/8061; C09; C09D; C09D5/00; C09D5/44; C09D5/4419; Y; Y10; Y10S; Y10S524/00; Y10S524/901

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 272 words
A cationic electrophoretic coating composition comprising an aqueous medium and a resinous binder dispersed therein, said resinous binder comprises: (A) A water-soluble or water-dispersible resin prepared by contacting a reaction product with a partially blocked polyisocyanate having in the molecule not more than one free isocyanate group and at least one blocked isocyanate group on the average at a temperature of 40° to 130° C., and subsequently by neutralizing the resulting product with an acid, said reaction product being prepared by reacting a compound selected from the group consisting of fatty acid, polyamide or mixtures thereof with an adduct, said adduct being prepared by reacting an epoxy resin with a basic amino compound, the amount of said fatty acid and/or polyamide used being 1 to 100 parts by weight per 100 parts by weight epoxy resin and the basic amino compound being used in an amount not exceeding one mole per mole of epoxy group and (B) at least one polymer selected from the group consisting of an ethylene oxide addition polymer, a propylene oxide addition polymer and derivatives of the ethylene oxide addition polymer and/or propylene oxide addition polymer, said polymers and derivatives having a number average molecular weight of 500 to 10,000 and having a solubility of up to 60 parts by weight in 100 parts by weight of water at 25° C., the partially blocked polyisocyanate being used in an amount of 1 to 100 parts by weight per 100 parts by weight of the epoxy resin and the component (B) being used in an amount of 0.5 to 30% by weight based on the component (A) as solid.
Claim 2
Dependent Claim 272 words
A cationic electrophoretic coating composition comprising an aqueous medium and a resinous binder dispersed therein, said resinous binder comprises: (A) A water-soluble or water-dispersible resin prepared by contacting a reaction product with a partially blocked polyisocyanate having in the molecule not more than one free isocyanate group and at least one blocked isocyanate group on the average at a temperature of 40° to 130° C., and subsequently by neutralizing the resulting product with an acid, said reaction product being prepared by reacting a compound selected from the group consisting of fatty acid, polyamide or mixtures thereof with an adduct, said adduct being prepared by reacting an epoxy resin with a basic amino compound, the amount of said fatty acid and/or polyamide used being 1 to 100 parts by weight per 100 parts by weight epoxy resin and the basic amino compound being used in an amount not exceeding one mole per mole of epoxy group and (B) at least one polymer selected from the group consisting of an ethylene oxide addition polymer, a propylene oxide addition polymer and derivatives of the ethylene oxide addition polymer and/or propylene oxide addition polymer, said polymers and derivatives having a number average molecular weight of 500 to 10,000 and having a solubility of up to 60 parts by weight in 100 parts by weight of water at 25° C., the partially blocked polyisocyanate being used in an amount of 1 to 100 parts by weight per 100 parts by weight of the epoxy resin and the component (B) being used in an amount of 0.5 to 30% by weight based on the component (A) as solid.
Claim 3
Dependent Claim 23 words
The cationic electrophoretic coating composition as defined in claim 1 wherein the epoxy resin is a resin prepared from bisphenol A and epichlorohydrin.
Claim 4
Dependent Claim 21 words
The cationic electrophoretic coating composition as defined in claim 1 wherein the basic amino compound is a water-soluble aliphatic amino compound.
Claim 5
Dependent Claim 81 words
The cationic electrophoretic coating composition as defined in claim 1 wherein the reaction products are compounds prepared by reacting an epoxy resin, a basic amino compound and a fatty acid and/or polyamide, the fatty acid being selected from the group consisting of safflower oil fatty acid, linseed oil fatty acid, soybean oil fatty acid, tall oil fatty acid, cotton seed oil fatty acid, coconut oil fatty acid, tung oil fatty acid, oicitica oil fatty acid and dehydrated castor oil fatty acid.
Claim 6
Dependent Claim 42 words
The cationic electrophoretic coating composition as defined in claim 4 wherein the polyamide is a reaction product selected from the group consisting of phthalic acid, adipic acid and sebasic acid, and at least one of ethylenediamine, hexamethylenediamine, diethylenetriamine, triethylenetetramine, propylenediamine and butylenediamine.
Claim 7
Dependent Claim 118 words
The cationic electrophoretic coating composition as defined in claim 1 wherein the water-soluble or water dispersible resin is a reaction product of: (i) a compound prepared by reacting an epoxy resin, a basic amino compound and a fatty acid and/or polyamide, the fatty acid being selected from the group consisting of safflower oil fatty acid, linseed oil fatty acid, soybean oil fatty acid, tall oil fatty acid, cotton seed oil fatty acid, coconunt oil fatty acid, tung oil fatty acid, oicitica oil fatty acid and dehydrated castor oil fatty acid, and (ii) a partially blocked polyisocyanate compound having in the molecule not more than one free isocyanate group and at least one blocked isocyanate group on the average.
Claim 8
Dependent Claim 27 words
The cationic electrophoretic coating composition as defined in claim 1 wherein the polymer or the derivatives thereof have a number average molecular weight of 700 to 5,000.
Claim 9
Dependent Claim 37 words
The cationic electrophoretic coating composition as defined in claim 1 wherein the polymer or the derivatives thereof have a solubility of 20 to 60 parts by weight in 100 parts by weight of water at 25° C.
Claim 10
Dependent Claim 51 words
The cationic electrophoretic coating composition as defined in claim 1 wherein the derivative is a compound prepared by modifying the addition polymers with a monoalcohol, diol, alcohol having at least three hydroxyl groups in the molecule, alkylphenol with an alkyl having at least eight carbon atoms, isocyanate compound or carboxylic acid.
Claim 11
Dependent Claim 26 words
The cationic electrophoretic coating composition as defined in claim 1 which contains 0.5 to 30% by weight of the component (B) based on the component (A).
Claim 12
Dependent Claim 39 words
The cationic electrophoretic coating composition as defined in claim 1 further comprising a cationic or nonionic water-soluble or water-dispersible resin in an amount of up to 20% by weight calculated as solids and based on the overall resin solids.

References Cited (Backward Citations)

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US3449281A Cited
US4031050A Cited
US3945964A Cited
US3804786A Cited
US3947338A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-02-25 1983-08-27 1984-02-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-02-25 1987-08-27 1988-02-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-02-25 1991-08-27 1992-02-26 $7700.00 Window Closed / Lapsed

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