US4188352A
Expired / Lapsed
US
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Elastomeric composition comprising fluoroelastomer and epicholorohydrin elastomer
Assignee: Daikin Industries Ltd
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Filing: 1978-12-29
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Granted: 1980-02-12
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Expires: 1998-12-29
Abstract
Abstract An elastomeric composition comprising a fluoroelastomer, an epichlorohydrin elastomer, an acid-acceptor, a curing accelerator and a fluorine-containing polyhydroxy compound, which is handled without any difficulty and can afford, on crosslinking, a rubbery material excellent in physical and chemical properties at a wide range of temperatures.
Inventors
- 👤 Takeshi Suzuki
- 👤 Yasuyoshi Furukawa
- 👤 Masayasu Tomoda
- 👤 Yutaka Ueta
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 10:10
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/12; C08L27/16; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K5/00; C08K5/04; C08K5/05; C08K5/16; C08K5/17; C08K5/49; C08K5/50; C08L71/00; C08L71/02; C08L71/03
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
37 words
An elastomeric composition which comprises a fluoroelastomer, an epichlorohydrin elastomer, an acid-acceptor, a curing accelerator and a fluorine-containing polyhydroxy compound wherein the proportion of the fluoroelastomer and the epichlorohydrin elastomer is from 95:5 to 5:95 by weight.
Claim 2
Dependent Claim
37 words
An elastomeric composition which comprises a fluoroelastomer, an epichlorohydrin elastomer, an acid-acceptor, a curing accelerator and a fluorine-containing polyhydroxy compound wherein the proportion of the fluoroelastomer and the epichlorohydrin elastomer is from 95:5 to 5:95 by weight.
Claim 3
Dependent Claim
26 words
The elastomeric composition according to claim 1, wherein the fluoroelastomer is a copolymer of vinylidene fluoride with at least one fluorinated olefin other than vinylidene fluoride.
Claim 4
Dependent Claim
26 words
The elastomeric composition according to claim 2, wherein the fluorinated olefin is hexafluoropropene, pentafluoropropene, trifluoroethylene, trifluorochloroethylene, tetrafluoroethylene, vinyl fluoride, perfluoromethyl vinyl ether or perfluoropropyl vinyl ether.
Claim 5
Dependent Claim
18 words
The elastomeric composition according to claim 2, wherein the fluoroelastomer is vinylidene fluoride-hexafluoropropene copolymer or vinylidene fluoride-tetrafluoroethylene-hexafluoropropene copolymer.
Claim 6
Dependent Claim
28 words
The elastomeric composition according to claim 1, wherein the epichlorohydrin elastomer is homopolymer of epichlorohydrin or copolymer of epichlorohydrin with at least one polymerizable monomer other than epichlorohydrin.
Claim 7
Dependent Claim
14 words
The elastomeric composition according to claim 5, wherein the polymerizable monomer is ethylene oxide.
Claim 8
Dependent Claim
21 words
The elastomeric composition according to claim 1, wherein the acid-acceptor is an oxide or hydroxide of magnesium, lead, calcium or zinc.
Claim 9
Dependent Claim
239 words
The elastomeric composition according to claim 1, wherein the curing accelerator is at least one selected from the group consisting of (a) amines of the formulae: ##STR4## wherein R 1 , R 2 and R 3 are each an alkyl group having 1 to 20 carbon atoms, or one of them may be a cycloalkyl group having 5 or 6 carbon atoms, or two of them may be bonded together to make a nitrogen-containing saturated ring, R 4 , R 5 , R 6 and R 7 are each an alkyl group having 1 to 6 carbon atoms, or R 4 and R 6 and/or R 5 and R 7 may be linked to make each a nitrogen-containing saturated ring, and R 8 is an alkylene group having 1 to 21 carbon atoms, and their salts with organic or inorganic acid, (b) cyclic amines of the formulae: ##STR5## wherein R 9 is a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or an aralkyl group having 7 to 20 carbon atoms and R 10 is an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 12 carbon atoms, and their salts with organic or inorganic acids, and (c) phosphorus compounds of the formula: ##STR6## wherein X, Y and Z are each an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 12 carbon atoms.
Claim 10
Dependent Claim
82 words
The elastomeric composition according to claim 1, wherein the fluorine-containing polyhydroxy compound is 2,2-bis(4-hydroxyphenyl)perfluoropropane, 2,2-bis(4-hydroxyphenyl)tetrafluorodicyclopropane, 2-(4'-hydroxyphenyl)-1,1,1,3,3,3-hexafluoro-2-propanol, HOCH 2 (CF 2 ) 3 CH 2 OH, HOCH 2 CF 2 CFH(CF 2 ) 3 CFHCF 2 CH 2 OH, HOCH 2 CH 2 CH 2 (CF 2 ) 3 CH 2 CH 2 CH 2 OH or HOCH 2 CF 2 CH 2 (CF 2 ) 3 CH 2 CF 2 CH 2 OH, or its alkali metal or alkaline earth metal salt.
Claim 11
Dependent Claim
14 words
The elastomeric composition according to claim 9, wherein the fluorine-containing polyhydroxy compound is 2,2-bis(4-hydroxyphenyl)perfluoropropane.
Claim 12
Dependent Claim
31 words
The elastomeric composition according to claim 1, wherein the acid-acceptor is included in an amount of from 1 to 40 parts by weight to 100 parts by weight of the elastomers.
Claim 13
Dependent Claim
32 words
The elastomeric composition according to claim 1, wherein the curing accelerator is included in an amount of from 0.1 to 10 parts by weight to 100 parts by weight of the elastomers.
Claim 14
Dependent Claim
33 words
The elastomeric composition according to claim 1, wherein the fluorine-containing polyhydroxy compound is included in an amount of from 0.5 to 10 parts by weight to 100 parts by weight of the elastomers.
References Cited (Backward Citations)
US3424818A
Cited
US4141874A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-02-11 | 1983-08-13 | 1984-02-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-02-11 | 1987-08-13 | 1988-02-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-02-11 | 1991-08-13 | 1992-02-12 | $7700.00 | Window Closed / Lapsed |