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US4188352A Expired / Lapsed US ⏱️ 0.0 years remaining

Elastomeric composition comprising fluoroelastomer and epicholorohydrin elastomer

Assignee: Daikin Industries Ltd
•
Filing: 1978-12-29
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Granted: 1980-02-12
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Expires: 1998-12-29
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Abstract

Abstract An elastomeric composition comprising a fluoroelastomer, an epichlorohydrin elastomer, an acid-acceptor, a curing accelerator and a fluorine-containing polyhydroxy compound, which is handled without any difficulty and can afford, on crosslinking, a rubbery material excellent in physical and chemical properties at a wide range of temperatures.

Inventors

  • 👤 Takeshi Suzuki
  • 👤 Yasuyoshi Furukawa
  • 👤 Masayasu Tomoda
  • 👤 Yutaka Ueta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 10:10
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/12; C08L27/16; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K5/00; C08K5/04; C08K5/05; C08K5/16; C08K5/17; C08K5/49; C08K5/50; C08L71/00; C08L71/02; C08L71/03

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 37 words
An elastomeric composition which comprises a fluoroelastomer, an epichlorohydrin elastomer, an acid-acceptor, a curing accelerator and a fluorine-containing polyhydroxy compound wherein the proportion of the fluoroelastomer and the epichlorohydrin elastomer is from 95:5 to 5:95 by weight.
Claim 2
Dependent Claim 37 words
An elastomeric composition which comprises a fluoroelastomer, an epichlorohydrin elastomer, an acid-acceptor, a curing accelerator and a fluorine-containing polyhydroxy compound wherein the proportion of the fluoroelastomer and the epichlorohydrin elastomer is from 95:5 to 5:95 by weight.
Claim 3
Dependent Claim 26 words
The elastomeric composition according to claim 1, wherein the fluoroelastomer is a copolymer of vinylidene fluoride with at least one fluorinated olefin other than vinylidene fluoride.
Claim 4
Dependent Claim 26 words
The elastomeric composition according to claim 2, wherein the fluorinated olefin is hexafluoropropene, pentafluoropropene, trifluoroethylene, trifluorochloroethylene, tetrafluoroethylene, vinyl fluoride, perfluoromethyl vinyl ether or perfluoropropyl vinyl ether.
Claim 5
Dependent Claim 18 words
The elastomeric composition according to claim 2, wherein the fluoroelastomer is vinylidene fluoride-hexafluoropropene copolymer or vinylidene fluoride-tetrafluoroethylene-hexafluoropropene copolymer.
Claim 6
Dependent Claim 28 words
The elastomeric composition according to claim 1, wherein the epichlorohydrin elastomer is homopolymer of epichlorohydrin or copolymer of epichlorohydrin with at least one polymerizable monomer other than epichlorohydrin.
Claim 7
Dependent Claim 14 words
The elastomeric composition according to claim 5, wherein the polymerizable monomer is ethylene oxide.
Claim 8
Dependent Claim 21 words
The elastomeric composition according to claim 1, wherein the acid-acceptor is an oxide or hydroxide of magnesium, lead, calcium or zinc.
Claim 9
Dependent Claim 239 words
The elastomeric composition according to claim 1, wherein the curing accelerator is at least one selected from the group consisting of (a) amines of the formulae: ##STR4## wherein R 1 , R 2 and R 3 are each an alkyl group having 1 to 20 carbon atoms, or one of them may be a cycloalkyl group having 5 or 6 carbon atoms, or two of them may be bonded together to make a nitrogen-containing saturated ring, R 4 , R 5 , R 6 and R 7 are each an alkyl group having 1 to 6 carbon atoms, or R 4 and R 6 and/or R 5 and R 7 may be linked to make each a nitrogen-containing saturated ring, and R 8 is an alkylene group having 1 to 21 carbon atoms, and their salts with organic or inorganic acid, (b) cyclic amines of the formulae: ##STR5## wherein R 9 is a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or an aralkyl group having 7 to 20 carbon atoms and R 10 is an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 12 carbon atoms, and their salts with organic or inorganic acids, and (c) phosphorus compounds of the formula: ##STR6## wherein X, Y and Z are each an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 12 carbon atoms.
Claim 10
Dependent Claim 82 words
The elastomeric composition according to claim 1, wherein the fluorine-containing polyhydroxy compound is 2,2-bis(4-hydroxyphenyl)perfluoropropane, 2,2-bis(4-hydroxyphenyl)tetrafluorodicyclopropane, 2-(4'-hydroxyphenyl)-1,1,1,3,3,3-hexafluoro-2-propanol, HOCH 2 (CF 2 ) 3 CH 2 OH, HOCH 2 CF 2 CFH(CF 2 ) 3 CFHCF 2 CH 2 OH, HOCH 2 CH 2 CH 2 (CF 2 ) 3 CH 2 CH 2 CH 2 OH or HOCH 2 CF 2 CH 2 (CF 2 ) 3 CH 2 CF 2 CH 2 OH, or its alkali metal or alkaline earth metal salt.
Claim 11
Dependent Claim 14 words
The elastomeric composition according to claim 9, wherein the fluorine-containing polyhydroxy compound is 2,2-bis(4-hydroxyphenyl)perfluoropropane.
Claim 12
Dependent Claim 31 words
The elastomeric composition according to claim 1, wherein the acid-acceptor is included in an amount of from 1 to 40 parts by weight to 100 parts by weight of the elastomers.
Claim 13
Dependent Claim 32 words
The elastomeric composition according to claim 1, wherein the curing accelerator is included in an amount of from 0.1 to 10 parts by weight to 100 parts by weight of the elastomers.
Claim 14
Dependent Claim 33 words
The elastomeric composition according to claim 1, wherein the fluorine-containing polyhydroxy compound is included in an amount of from 0.5 to 10 parts by weight to 100 parts by weight of the elastomers.

References Cited (Backward Citations)

US3424818A Cited
US4141874A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-02-11 1983-08-13 1984-02-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-02-11 1987-08-13 1988-02-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-02-11 1991-08-13 1992-02-12 $7700.00 Window Closed / Lapsed

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