US4187672A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Apparatus for converting carbonaceous material into fuel gases and the recovery of energy therefrom
Assignee: Rasor Associates Inc
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Filing: 1977-11-17
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Granted: 1980-02-12
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Expires: 1997-11-17
Abstract
Abstract The invention is concerned with novel apparatus and process for converting crude carbon such as coal, carbonaceous wastes and the like into valuable chemical products and/or energy. A mass of solid crude carbonaceous fuel is fed into a high temperature liquid which acts as a solvent for carbon at a temperature sufficient to carbonize the mass and by which the carbon is separated from impurities. Volatile fractions are removed from the mass which acts as a distillation column. Air, or another oxygen source, is introduced into the reactor wherein it reacts with the carbon dissolved in the liquid therein, which may preferably be iron to form a hot fuel gas. The hot fuel gas is then used to produce useful energy, generally via a stepwise procedure.
Inventors
- 👤 Ned S. Rasor
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 19:55
CPC Classifications
C; C10; C10B; C10B49/00; C10B49/14; C10G; C10G1/00; C10J; C10J3/00; C10J3/57; F; F02; F02B; F02B43/00; F02B43/08; C10J2200/00; C10J2200/15; C10J2200/158; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/30
Claims Analysis
Total Claims: 33
Claim 1
Independent Claim
289 words
Apparatus for converting a feed which includes a sulfur component and which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow flow of liquid between said carbonization chamber and said oxidation chamber means, said partition means further defining a leaching chamber within said reactor separated above said liquid level from said carbonization chamber and said oxidation chamber means but allowing flow of liquid thereinto and thereoutof; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber; means for introducing oxidizing means having an oxygen content into said oxidation chamber means to produce oxygen bound in said liquid solvent; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; means for introducing a metal oxide, said metal forming a sulfide which is insoluble in said liquid and of a different density therefrom whereby said metal sulfide when formed separates into a sulfide layer, into said leaching chamber; means for conducting off gas formed by reaction of said metal oxide with sulfur and carbon dissolved in said liquid in said leaching chamber away therefrom; means for removing said sulfide layer from said leaching chamber; and means for conducting away from said oxidation chamber means a first hot gas formed therein.
Claim 2
Dependent Claim
289 words
Apparatus for converting a feed which includes a sulfur component and which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow flow of liquid between said carbonization chamber and said oxidation chamber means, said partition means further defining a leaching chamber within said reactor separated above said liquid level from said carbonization chamber and said oxidation chamber means but allowing flow of liquid thereinto and thereoutof; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber; means for introducing oxidizing means having an oxygen content into said oxidation chamber means to produce oxygen bound in said liquid solvent; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; means for introducing a metal oxide, said metal forming a sulfide which is insoluble in said liquid and of a different density therefrom whereby said metal sulfide when formed separates into a sulfide layer, into said leaching chamber; means for conducting off gas formed by reaction of said metal oxide with sulfur and carbon dissolved in said liquid in said leaching chamber away therefrom; means for removing said sulfide layer from said leaching chamber; and means for conducting away from said oxidation chamber means a first hot gas formed therein.
Claim 3
Dependent Claim
26 words
Apparatus as in claim 1, wherein said liquid solvent comprises molten iron at a temperature within a range from about 1100° C. to about 1700° C.
Claim 4
Dependent Claim
24 words
Apparatus as in claim 2, further comprising: means for reacting said removed sulfide with carbon dioxide to produce elemental sulfur and recyclable metal oxide.
Claim 5
Dependent Claim
19 words
Apparatus as in claim 3, including: means for transferring said recyclable metal oxide to said metal oxide introducing means.
Claim 6
Dependent Claim
259 words
Apparatus for converting a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow flow of liquid between said carbonization chamber and said oxidation chamber means; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber, said feed introducing means comprising means for contacting a first end of a mass of said feed extending generally linearly into said carbonization chamber with said liquid; and means for progressively adding said feed to a second end of said mass to maintain the extension thereof into said carbonization chamber substantially constant and create a temperature gradient therealong; a plurality of volatile fraction takeoff means in flow communication with said mass along the length thereof for selectively removing fractions of differing volatilities therefrom; means for introducing oxidizing means having an oxygen content into said oxidation chamber means to produce oxygen bound in said liquid solvent; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; and means for conducting away from said oxidation chamber means a first hot gas formed therein.
Claim 7
Dependent Claim
259 words
Apparatus for converting a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow flow of liquid between said carbonization chamber and said oxidation chamber means; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber, said feed introducing means comprising means for contacting a first end of a mass of said feed extending generally linearly into said carbonization chamber with said liquid; and means for progressively adding said feed to a second end of said mass to maintain the extension thereof into said carbonization chamber substantially constant and create a temperature gradient therealong; a plurality of volatile fraction takeoff means in flow communication with said mass along the length thereof for selectively removing fractions of differing volatilities therefrom; means for introducing oxidizing means having an oxygen content into said oxidation chamber means to produce oxygen bound in said liquid solvent; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; and means for conducting away from said oxidation chamber means a first hot gas formed therein.
Claim 8
Dependent Claim
75 words
Apparatus as in claim 5, wherein said first end feed contacting means comprises a generally vertical digester through which said feed progresses downwardly under the influence of gravity and said first end of said feed comprises a bottom end thereof, said feed adding means comprises means for adding feed to a top portion of said digester and said fraction takeoff means comprises a plurality of vertically separated openings through an external wall of said digester.
Claim 9
Dependent Claim
28 words
Apparatus as in claim 6, wherein said liquid solvent comprises molten iron at a temperature which falls within a range from about 1100° C. to about 1700° C.
Claim 10
Dependent Claim
17 words
Apparatus as in claim 7, including: means for removing a slag layer formed in said carbonization chamber.
Claim 11
Dependent Claim
123 words
Apparatus as in claim 8, wherein said feed includes a sulfur component, said partition means further defines a leaching chamber within said reactor separated above said liquid level from said carbonization chamber and said oxidation chamber means but allowing flow of liquid thereinto and thereoutof and further comprising: means for introducing a metal oxide, said metal forming a sulfide which is insoluble in said liquid and of a different density therefrom whereby said metal sulfide when formed separates into a sulfide layer, into said leaching chamber; means for conducting off gas formed by reaction of said metal oxide with sulfide and carbon dissolved in said liquid in said leaching chamber away therefrom; and means for removing said sulfide layer from said leaching chamber.
Claim 12
Dependent Claim
26 words
Apparatus as in claim 9, further comprising: means for reacting said removed sulfide with carbon dioxide to produce elemental sulfur and recyclable metal oxide or hydroxide.
Claim 13
Dependent Claim
23 words
Apparatus as in claim 10, including: means for transferring said recyclable metal oxide or hydroxide to said metal oxide or hydroxide introducing means.
Claim 14
Dependent Claim
122 words
Apparatus as in claim 11, wherein said oxidation chamber means comprises a decarbonization chamber and a first oxidizing chamber within said reactor defined by said partition means, said decarbonization chamber is separated above said liquid level from said carbonization and said first oxidation chambers but said partition means allows flow of liquid into said decarbonization chamber with carbon dissolved therein from said carbonization chamber and of liquid with oxygen bound therein from said first oxidation chamber and flow of liquid from said decarbonization chamber substantially free of oxygen bound therein to said decarbonization chamber and of liquid therefrom having oxygen bound therein to said first oxidation chamber and further comprising: means for conducting a second hot gas away from said decarbonization chamber.
Claim 15
Dependent Claim
101 words
Apparatus as in claim 12, wherein said oxidation chamber means further comprises a second oxidation chamber separated above said liquid level from said decarbonization and first oxidation chambers but in liquid flow communication therewith, said oxidizing means comprises a first oxidizing gas comprising air introduced into said first oxidation chamber and a second oxidizing gas comprising steam introduced into said second oxidization chamber, said first hot gas comprises a first separate portion comprising nitrogen produced in said first oxidation chamber and a second separate portion comprising hydrogen produced in said second oxidation chamber, and said second hot gas comprises carbon monoxide.
Claim 16
Dependent Claim
84 words
Apparatus as in claim 5, wherein said first end feed contacting means comprises means for feeding said mass generally horizontally into said carbonization chamber generally onto a surface of said liquid and said first end of said mass progresses generally horizontally along said surface, said feed adding means comprises means for force feeding said feed against said second end of said mass and said fraction takeoff means comprise a plurality of openings above said mass and spaced from one another along the length thereof.
Claim 17
Dependent Claim
17 words
Apparatus as in claim 14, including: means for removing a slag layer formed in said carbonization chamber.
Claim 18
Dependent Claim
123 words
Apparatus as in claim 15, wherein said feed includes a sulfur component, said partition means further defines a leaching chamber within said reactor separated above said liquid level from said carbonization chamber and said oxidation chamber means but allowing flow of liquid thereinto and thereoutof and further comprising: means for introducing a metal oxide, said metal forming a sulfide which is insoluble in said liquid and of a different density therefrom whereby said metal sulfide when formed separates into a sulfide layer, into said leaching chamber; means for conducting off gas formed by reaction of said metal oxide with sulfur and carbon dissolved in said liquid in said leaching chamber away therefrom; and means for removing said sulfide layer from said leaching chamber.
Claim 19
Dependent Claim
24 words
Apparatus as in claim 16, further comprising: means for reacting said removed sulfide with carbon dioxide to produce elemental sulfur and recyclable metal oxide.
Claim 20
Dependent Claim
19 words
Apparatus as in claim 17, including: means for transferring said recyclable metal oxide to said metal oxide introducing means.
Claim 21
Dependent Claim
110 words
Apparatus as in claim 18, wherein said oxidation chamber means comprises a decarbonization chamber and a first oxidizing chamber within said reactor defined by said partition means, said decarbonization chamber is separated above said liquid level from said carbonization chamber and said first oxidation chambers but said partition means allows flow of liquid into said decarbonization chamber with carbon dissolved therein from said carbonization chamber and of liquid with oxygen bound therein from said first oxidation chamber and flow of liquid from said decarbonization chamber substantially free of oxygen bound therein to said carbonization chamber and further comprising: means for conducting a second hot gas away from said decarbonization chamber.
Claim 22
Dependent Claim
256 words
Apparatus for converting a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow a flow of liquid between said carbonization chamber and said oxidation chamber means; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber; means for introducing oxidizing means having an oxygen content into said oxidation chamber means to produce oxygen bound in said liquid solvent; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; means for conducting away from said oxidation chamber means a first hot gas formed therein; and back pressure creating means in said hot gas conducting means to prevent flow of said hot gas therethrough unless the pressure thereof reaches a required value; and wherein said liquid level comprises a first liquid level in said carbonization chamber and a second liquid level in said oxidation chamber means and the difference in height between said first and second liquid levels comprises a hydraulic pressure head of said liquid generally equal to said required hot gas pressure value.
Claim 23
Dependent Claim
256 words
Apparatus for converting a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow a flow of liquid between said carbonization chamber and said oxidation chamber means; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber; means for introducing oxidizing means having an oxygen content into said oxidation chamber means to produce oxygen bound in said liquid solvent; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; means for conducting away from said oxidation chamber means a first hot gas formed therein; and back pressure creating means in said hot gas conducting means to prevent flow of said hot gas therethrough unless the pressure thereof reaches a required value; and wherein said liquid level comprises a first liquid level in said carbonization chamber and a second liquid level in said oxidation chamber means and the difference in height between said first and second liquid levels comprises a hydraulic pressure head of said liquid generally equal to said required hot gas pressure value.
Claim 24
Dependent Claim
27 words
Apparatus as in claim 20, including means for abstracting energy in usable form from said hot gas after it has been compressed to said predetermined pressure value.
Claim 25
Dependent Claim
28 words
Apparatus as in claim 21, wherein said liquid solvent comprises molten iron at a temperature which falls within a range from about 1100° C. to about 1700° C.
Claim 26
Dependent Claim
14 words
Apparatus as in claim 22, wherein said energy abstracting means comprises gas turbine means.
Claim 27
Dependent Claim
245 words
Apparatus for converting a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow flow of liquid between said carbonization chamber and said oxidation chamber means; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber, said feed introducing means comprising means for contacting a generally circular mass of said feed extending into said carbonization chamber with said liquid; and means for progressively adding said feed to a central portion of said mass to maintain the extention thereof into said carbonization chamber substantially constant and create a temperature gradient from said central portion to a peripheral portion of said mass; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; a plurality of volatile fraction takeoff means in flow communication with said carbonization chamber extending radially along said mass for selectively removing fractions of differing volatilities therefrom; and means for conducting away from said oxidation chamber means a first hot gas formed therein.
Claim 28
Dependent Claim
245 words
Apparatus for converting a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into a hot gas, comprising: a reactor; a liquid solvent for carbon which fills said reactor up to a liquid level therein below a top thereof; partition means, separating said reactor above said liquid level into a carbonization chamber and oxidation chamber means, said partition means terminating below said liquid level and above a bottom of said reactor to allow flow of liquid between said carbonization chamber and said oxidation chamber means; means for introducing a feed which yields carbon on being heated above a carbonization temperature thereof and which is solid at ambient temperature into said carbonization chamber, said feed introducing means comprising means for contacting a generally circular mass of said feed extending into said carbonization chamber with said liquid; and means for progressively adding said feed to a central portion of said mass to maintain the extention thereof into said carbonization chamber substantially constant and create a temperature gradient from said central portion to a peripheral portion of said mass; means for causing flow of said liquid between said carbonization chamber and said oxidation chamber means; a plurality of volatile fraction takeoff means in flow communication with said carbonization chamber extending radially along said mass for selectively removing fractions of differing volatilities therefrom; and means for conducting away from said oxidation chamber means a first hot gas formed therein.
Claim 29
Dependent Claim
34 words
Apparatus as in claim 24, including: stirrer means engaged in said central portion of said mass for rotating said mass and thereby improving dissolution of said mass and creating fluid flow within said liquid.
Claim 30
Dependent Claim
17 words
Apparatus as in claim 25, including means for abstracting energy in useable form from said hot gas.
Claim 31
Dependent Claim
28 words
Apparatus as in claim 26, wherein said liquid solvent comprises molten iron at a temperature which falls within a range from about 1100° C. to about 1700° C.
Claim 32
Dependent Claim
14 words
Apparatus as in claim 27, wherein said energy abstracting means comprises gas turbine means.
Claim 33
Dependent Claim
46 words
Apparatus as in claim 28, wherein said gas turbine means includes a plurality of combustion stages which sequentially combust portions of said second gas to maintain the temperature of said second gas within a temperature range corresponding generally to maximum efficiency of said gas turbine means.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-02-11 | 1983-08-13 | 1984-02-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-02-11 | 1987-08-13 | 1988-02-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-02-11 | 1991-08-13 | 1992-02-12 | $7700.00 | Window Closed / Lapsed |