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US4185988A Expired / Lapsed US ⏱️ 0.0 years remaining

Anticaking compositions

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1978-07-28
•
Granted: 1980-01-29
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Expires: 1998-07-28
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Abstract

Abstract An anticaking composition suitable for fertilizers comprising a hydrophobic liquid having dissolved therein from 0.01 to 20% by weight of an alkylaryl sulphonate derived from an alkylaryl sulphonic acid of molecular weight greater than 400. Also covered are fertilizer granules, e.g. NPK fertilizers coated with this anticaking composition.

Inventors

  • 👤 Jean P. Kistler
  • 👤 Michel Guinot

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 07:03
CPC Classifications
B; B01; B01J; B01J2/00; B01J2/30; C; C05; C05G; C05G3/00; C05G3/30; C05G5/00; C05G5/30; C10; C10M; C10M2201/00; C10M2201/06; C10M2201/062; C10M2201/10; C10M2201/105; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/24; C10M2215/26; C10M2219/00; C10M2219/04; C10M2219/044; C10N; C10N2010/00; C10N2010/04; C10N2040/00; C10N2040/30; C10N2040/32; C10N2040/34; C10N2040/36; C10N2040/38; C10N2040/40; C10N2040/42; C10N2040/44; C10N2040/50

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 62 words
Fertilizer granules coated with a hydrophobic layer in an amount ranging from 0.005 to 0.4% by weight based on the weight of said fertilizer, said hydrophobic layer comprising mineral oil having dissolved therein from 0.01 to 20% by weight of an alkylaryl sulfonate of a nitrogen-containing compound, said sulfonate derived from a synthetic alkylaryl sulfonic acid of molecular weight greater than 400.
Claim 2
Dependent Claim 62 words
Fertilizer granules coated with a hydrophobic layer in an amount ranging from 0.005 to 0.4% by weight based on the weight of said fertilizer, said hydrophobic layer comprising mineral oil having dissolved therein from 0.01 to 20% by weight of an alkylaryl sulfonate of a nitrogen-containing compound, said sulfonate derived from a synthetic alkylaryl sulfonic acid of molecular weight greater than 400.
Claim 3
Dependent Claim 33 words
The fertilizer granules according to claim 1 wherein said nitrogen-containing compound is selected from ammonia, ethanolamine, ethoxy amines and fatty acid amines and said hydrophobic layer ranges from 0.2 to 0.4% by weight.
Claim 4
Dependent Claim 22 words
The fertilizer granules according to claim 2 wherein said sulfonic acid has a molecular weight in the range of 480 to 530.
Claim 5
Dependent Claim 24 words
The fertilizer granules according to claim 2 wherein said alkylaryl sulfonate is the diethanolamine salt of a synthetic sulfonic acid of molecular weight 520.
Claim 6
Dependent Claim 99 words
In a method for reducing the tendency of fertilizers to cake wherein fertilizer granules are coated with an anticaking composition to provide a hydrophobic layer thereby curtailing absorption of water by the granule, the improvement of providing said hydrophobic layer in an amount ranging from 0.005-0.4% by weight based on the weight of the fertilizer by coating said fertilizer granules with an anticaking composition comprising mineral oil having dissolved therein from 0.01 to 20% by weight of an alkylaryl sulfonate of a nitrogen-containing compound, said sulfonate derived from a synthetic alkylaryl sulfonic acid of molecular weight greater than 400.
Claim 7
Dependent Claim 99 words
In a method for reducing the tendency of fertilizers to cake wherein fertilizer granules are coated with an anticaking composition to provide a hydrophobic layer thereby curtailing absorption of water by the granule, the improvement of providing said hydrophobic layer in an amount ranging from 0.005-0.4% by weight based on the weight of the fertilizer by coating said fertilizer granules with an anticaking composition comprising mineral oil having dissolved therein from 0.01 to 20% by weight of an alkylaryl sulfonate of a nitrogen-containing compound, said sulfonate derived from a synthetic alkylaryl sulfonic acid of molecular weight greater than 400.
Claim 8
Dependent Claim 33 words
In the method according to claim 5 wherein said nitrogen-containing compound is selected from ammonia, ethanolamine, ethoxy amines and fatty acid amines and said hydrophobic layer ranges from 0.2 to 0.4% by weight.
Claim 9
Dependent Claim 22 words
In a method according to claim 6 wherein said sulfonic acid has a molecular weight in the range of 480 to 530.
Claim 10
Dependent Claim 19 words
In a method according to claim 6 wherein said alkylaryl sulfonate is the diethanolamine salt of said sulfonic acid.
Claim 11
Dependent Claim 78 words
Fertilizer granules coated with a hydrophobic layer in an amount ranging from 0.005-0.4% by weight based on the weight of said fertilizer, said hydrophobic layer consisting essentially of paraffinic mineral oil having dissolved therein the combination from about 0.01-20% by weight of an alkylaryl sulfonate derived from a synthetic alkylaryl sulfonic acid of molecular weight ranging from 480-530 and from 0.1-10% by weight of a fatty amine whereby the absorption of water by said fertilizer granules is curtailed.
Claim 12
Dependent Claim 78 words
Fertilizer granules coated with a hydrophobic layer in an amount ranging from 0.005-0.4% by weight based on the weight of said fertilizer, said hydrophobic layer consisting essentially of paraffinic mineral oil having dissolved therein the combination from about 0.01-20% by weight of an alkylaryl sulfonate derived from a synthetic alkylaryl sulfonic acid of molecular weight ranging from 480-530 and from 0.1-10% by weight of a fatty amine whereby the absorption of water by said fertilizer granules is curtailed.
Claim 13
Dependent Claim 17 words
The fertilizer granules of claim 9 wherein said sulfonate is an alkali or alkaline earth metal sulfonate.
Claim 14
Dependent Claim 26 words
The fertilizer granules of claim 9 wherein said sulfonate is the sulfonate of a nitrogen-containing compound selected from ammonia, ethanolamine, ethoxy amines and fatty acid amines.
Claim 15
Dependent Claim 13 words
The fertilizer granules of claim 9 wherein said fertilizer is calcium ammonium nitrate.
Claim 16
Dependent Claim 105 words
In a method for reducing the tendency of fertilizers to cake wherein fertilizer granules are coated with an anticaking composition to provide a hydrophobic layer thereby curtailing absorption of water by the granule, the improvement of providing said hydrophobic layer in an amount ranging from 0.005-0.4% by weight based on the weight of the fertilizer by coating said fertilizer granules with an anticaking composition consisting essentially of paraffinic mineral oil having dissolved therein the combination from about 0.01-20% by weight of an alkylaryl sulfonate derived from an alkylaryl sulfonic acid of molecular weight ranging from 480-530 and from 0.1-10% by weight of a fatty amine.
Claim 17
Dependent Claim 105 words
In a method for reducing the tendency of fertilizers to cake wherein fertilizer granules are coated with an anticaking composition to provide a hydrophobic layer thereby curtailing absorption of water by the granule, the improvement of providing said hydrophobic layer in an amount ranging from 0.005-0.4% by weight based on the weight of the fertilizer by coating said fertilizer granules with an anticaking composition consisting essentially of paraffinic mineral oil having dissolved therein the combination from about 0.01-20% by weight of an alkylaryl sulfonate derived from an alkylaryl sulfonic acid of molecular weight ranging from 480-530 and from 0.1-10% by weight of a fatty amine.
Claim 18
Dependent Claim 18 words
In a method according to claim 13 wherein said sulfonate is an alkali or alkaline earth metal sulfonate.
Claim 19
Dependent Claim 27 words
In a method according to claim 13 wherein said sulfonate is the sulfonate of a nitrogen-containing compound selected from ammonia, ethanolamine, ethoxy amines and fatty acid amines.
Claim 20
Dependent Claim 21 words
In a method according to claim 13 wherein said fatty amine is predominantly of amines containing 16 and 18 carbon atoms.

References Cited (Backward Citations)

US3234003A Cited
US3690391A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-01-28 1983-07-30 1984-01-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-01-28 1987-07-30 1988-01-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-01-28 1991-07-30 1992-01-29 $7700.00 Window Closed / Lapsed

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