US4185047A
Expired / Lapsed
US
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Thermoplastic molding compositions
Assignee: General Electric Co
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Filing: 1977-12-30
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Granted: 1980-01-22
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Expires: 1997-12-30
Abstract
Abstract A thermoplastic molding composition having improved mold release properties is provided, the composition comprising a thermoplastic resin selected from the group consisting of a high molecular weight linear polyester and a high molecular weight block copolyester, from about 0.1 to 4.5% by weight, based on the total composition, of a polyolefin or olefin-based copolymer, and, optionally, from about 0.02 to 0.5% by weight, based on the total composition, of talc.
Inventors
- 👤 Stuart C. Cohen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 18:44
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08K; C08K3/00; C08K3/34; C08L23/00; C08L31/00; C08L33/00
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
218 words
An improved molding composition, having improved mold releasability, said composition comprising: (a) a block copolymer derived from blocks of (i) a terminally reactive poly(1,4-butylene terephthalate) and (ii) a terminally reactive aromatic/aliphatic copolyester of a dicarboxylic acid selected from the group consisting of terephthalic acid, isophthalic acid, naphthalene dicarboxylic acids, phenyl indane dicarboxylic acid and compounds of the formula ##STR3## in which X may be alkylene or alkylidene of from 1 to 4 carbon atoms, carbonyl, sulfonyl, oxygen or a bond between the benzene rings, and an aliphatic dicarboxylic acid having from 6 to 12 carbon atoms in the chain and one or more straight or branched chain dihydric aliphatic glycols having from 4 to 10 carbon atoms in the chain, said copolyester having at least 10% of aliphatic units being derived from a dicarboxylic acid; or (iii) a terminally-reactive aliphatic polyester of a straight chain aliphatic dicarboxylic acid having from 4 to 12 carbon atoms in the chain and a straight or branched chain aliphatic glycol, said blocks being connected by interterminal linkages consisting essentially of ester linkages; (b) from about 0.25 to 4.5 percent by weight, based on the total composition, of a composition, of a polyolefin or olefin-based copolymer; and (c) from about 0.02 to about 0.5% by weight, based on the total composition, of talc.
Claim 2
Dependent Claim
218 words
An improved molding composition, having improved mold releasability, said composition comprising: (a) a block copolymer derived from blocks of (i) a terminally reactive poly(1,4-butylene terephthalate) and (ii) a terminally reactive aromatic/aliphatic copolyester of a dicarboxylic acid selected from the group consisting of terephthalic acid, isophthalic acid, naphthalene dicarboxylic acids, phenyl indane dicarboxylic acid and compounds of the formula ##STR3## in which X may be alkylene or alkylidene of from 1 to 4 carbon atoms, carbonyl, sulfonyl, oxygen or a bond between the benzene rings, and an aliphatic dicarboxylic acid having from 6 to 12 carbon atoms in the chain and one or more straight or branched chain dihydric aliphatic glycols having from 4 to 10 carbon atoms in the chain, said copolyester having at least 10% of aliphatic units being derived from a dicarboxylic acid; or (iii) a terminally-reactive aliphatic polyester of a straight chain aliphatic dicarboxylic acid having from 4 to 12 carbon atoms in the chain and a straight or branched chain aliphatic glycol, said blocks being connected by interterminal linkages consisting essentially of ester linkages; (b) from about 0.25 to 4.5 percent by weight, based on the total composition, of a composition, of a polyolefin or olefin-based copolymer; and (c) from about 0.02 to about 0.5% by weight, based on the total composition, of talc.
Claim 3
Dependent Claim
28 words
A composition as defined in claim 1 wherein said polyolefin or olefin-based copolymer is selected from the group consisting of polyethylene, ethylene-acrylic acid copolymer and ethylene-vinyl acetate copolymer.
Claim 4
Dependent Claim
12 words
A composition as defined in claim 1 wherein said polyolefin is polyethylene.
Claim 5
Dependent Claim
69 words
A composition as defined in claim 1 wherein said thermoplastic resin is a block copolyester derived from blocks of (i) a terminally-reactive poly(1,4-butylene terephthalate) and (ii) a copolyester of isophthalic acid and a straight chain aliphatic dicarboxylic acid having from 6 to 12 carbon atoms in the chain with one or more straight or branched chain dihydric aliphatic glycols having from 4 to 10 carbon atoms in the chain.
Claim 6
Dependent Claim
46 words
A composition as defined in claim 4, wherein said block copolyester is derived from blocks of (i) a terminally-reactive poly(1,4-butylene terephthalate) and (ii) a polyester of a straight chain aliphatic dicarboxylic acid having from 6 to 12 carbon atoms and a branched chain dihydric aliphatic glycol.
Claim 7
Dependent Claim
24 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly (1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-azelate-co-isophthalate).
Claim 8
Dependent Claim
24 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-(0.7)-azelate-co-(0.3) isophthalate.
Claim 9
Dependent Claim
23 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-adipate-co-isophthalate).
Claim 10
Dependent Claim
24 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-(0.5)-adipate-co-(0.5) isophthalate).
Claim 11
Dependent Claim
23 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-(0.7)-adipate-co-(0.3)-isophthalate).
Claim 12
Dependent Claim
23 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-co-neopentyl-adipate-co-isophthalate).
Claim 13
Dependent Claim
23 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(neopentyl-adipate).
Claim 14
Dependent Claim
23 words
A composition as defined in claim 4 wherein said block copolymer is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,4-butylene-adipate).
Claim 15
Dependent Claim
23 words
A composition as defined in claim 4 wherein said block copolyester is derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(ethylene-co-1,4-butylene-adipate).
Claim 16
Dependent Claim
45 words
An improved flame-retardant thermoplastic molding composition, said composition comprising: (a) a block copolyester derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-azelate-co-isophthalate); and (b) from about 0.1 to 4.5 percent by weight, based on the total composition, of a polyolefin or olefin-based copolymer.
Claim 17
Dependent Claim
45 words
An improved flame-retardant thermoplastic molding composition, said composition comprising: (a) a block copolyester derived from blocks of (i) terminally-reactive poly(1,4-butylene terephthalate) and (ii) poly(1,6-hexylene-azelate-co-isophthalate); and (b) from about 0.1 to 4.5 percent by weight, based on the total composition, of a polyolefin or olefin-based copolymer.
Claim 18
Dependent Claim
28 words
A composition as defined in claim 15 wherein said polyolefin or olefin-based copolymer is selected from the group consisting of polyethylene, ethylene-acrylic acid copolymer, and ethylene-vinyl acetate copolymer.
Claim 19
Dependent Claim
12 words
A composition as defined in claim 15 wherein said polyolefin is polyethylene.
Claim 20
Dependent Claim
20 words
A composition as defined in claim 15 wherein said polyolefin is low density polyethylene and said poly(1,6-hexylene-azelate-co-isophthalate is poly(1,6-hexylene-(0.7)-azelate-co-(0.3) isophthalate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-01-21 | 1983-07-23 | 1984-01-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-01-21 | 1987-07-23 | 1988-01-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-01-21 | 1991-07-23 | 1992-01-22 | $7700.00 | Window Closed / Lapsed |