US4185001A
Expired / Lapsed
US
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Process for preparing plastic compositions containing a silicate dispersed therein
Assignee: Rhone Poulenc Industries SA
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Filing: 1977-11-28
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Granted: 1980-01-22
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Expires: 1997-11-28
Abstract
Abstract Silica plastic compositions containing a silicate filler finely dispersed therein are produced by simultaneously adding a mixture of an aqueous solution of an alkali silicate and a coagulable latex emulsion of a plastic polymeric material and a solution of at least one salt of hydrochloric or sulfuric acids and a metal selected from the group consisting of zinc, magnesium, calcium, and maintaining the pH of the reaction medium at a level appropriate for the precipitation of the neutral silicate of the metal, yet at which precipitation of either hydroxy salts of the metal or of alkaline silicates is substantially precluded.
Inventors
- 👤 Jean Machurat
- 👤 Georges Vrisakis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 07:18
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/20; C08J3/205; C08J3/21; C08J3/215; C08K; C08K3/00; C08K3/34; C08K3/36; C08J2321/00; Y; Y10; Y10S; Y10S528/00; Y10S528/931; Y10S528/934
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
212 words
A process for preparing a polymeric composition comprising a polymeric material containing finely dispersed therein a water insoluble inorganic silicate comprising the steps of (a) feeding a stream of an aqueous mixture containing a coagulable latex dispersion of a polymeric material and an aqueous solution of a water soluble alkali silicate into a reactor simultaneously with a separate stream of an aqueous solution containing at least one water soluble bivalent metal salt selected from the group consisting of chlorides and sulfates of a bivalent metal cation selected from the group of zinc, magnesium and calcium cation, to form a reaction slurry the pH of which is constantly maintained at such a value as is appropriate for precipitating a substantially neutral silicate of said bivalent metal by reaction of stoichiometrically equivalent amounts of the alkali silicate and the bivalent metal salt yet at which the precipitation of any hydroxy salt of the bivalent metal cation and of any alkali silicate is substantially prevented thereby maintaining a sufficiently elevated reaction temperature to effect the precipitation of the neutral bivalent metal silicate and the coagulation of the polymeric material to form a suspension of particles of said organic polymeric material having said bivalent metal silicate associated therewith, and (b) recovering said particles from said suspension.
Claim 2
Dependent Claim
212 words
A process for preparing a polymeric composition comprising a polymeric material containing finely dispersed therein a water insoluble inorganic silicate comprising the steps of (a) feeding a stream of an aqueous mixture containing a coagulable latex dispersion of a polymeric material and an aqueous solution of a water soluble alkali silicate into a reactor simultaneously with a separate stream of an aqueous solution containing at least one water soluble bivalent metal salt selected from the group consisting of chlorides and sulfates of a bivalent metal cation selected from the group of zinc, magnesium and calcium cation, to form a reaction slurry the pH of which is constantly maintained at such a value as is appropriate for precipitating a substantially neutral silicate of said bivalent metal by reaction of stoichiometrically equivalent amounts of the alkali silicate and the bivalent metal salt yet at which the precipitation of any hydroxy salt of the bivalent metal cation and of any alkali silicate is substantially prevented thereby maintaining a sufficiently elevated reaction temperature to effect the precipitation of the neutral bivalent metal silicate and the coagulation of the polymeric material to form a suspension of particles of said organic polymeric material having said bivalent metal silicate associated therewith, and (b) recovering said particles from said suspension.
Claim 3
Dependent Claim
22 words
The process as defined in claim 1 wherein the reaction temperature is in the range from about 40° to about 90° C.
Claim 4
Dependent Claim
31 words
The process as defined in claim 1 wherein the bivalent metal salt is a zinc salt and the pH value of the reaction slurry is from about 6.0 to about 6.5.
Claim 5
Dependent Claim
31 words
The process as defined in claim 1 wherein the bivalent metal salt is a magnesium salt and the pH value of the reaction slurry is from about 8.0 to about 9.5.
Claim 6
Dependent Claim
31 words
The process as defined in claim 1 wherein the bivalent metal salt is a calcium salt and the pH value of the reaction slurry is from about 8.5 to about 10.0.
Claim 7
Dependent Claim
53 words
The process as defined in claim 1 wherein the amounts of alkali silicate in the mixture and of bivalent metal salt in the solution and feeding rate of the two separate streams are adjusted such that substantially stoichiometrically equivalent amounts of alkali silicate and bivalent metal salt are simultaneously introduced into the reactor.
Claim 8
Dependent Claim
19 words
The process as defined in claim 1, wherein said streams are simultaneously introduced into water contained in said reactor.
Claim 9
Dependent Claim
18 words
The process as defined in claim 1, wherein said streams are simultaneously introduced into an aqueous electrolyte solution.
Claim 10
Dependent Claim
24 words
The process as defined in claim 8, wherein the electrolyte comprises a salt the anion of which is that of the bivalent metal salt.
Claim 11
Dependent Claim
28 words
The process as defined in claim 1 which further comprises adding to the reaction mixture an acid the anion of which is that of the bivalent metal salt.
Claim 12
Dependent Claim
14 words
The process as defined in claim 1 wherein the polymeric material comprises a styrene-butadiene-rubber.
Claim 13
Dependent Claim
31 words
The process as defined in claim 1 wherein the alkali silicate comprises a sodium silicate wherein the molar ratio SiO 2 /Na 2 O is from about 2 to about 3.5.
Claim 14
Dependent Claim
35 words
The process as defined in claim 1 wherein the amount of alkali silicate in the alkali silicate solution is equivalent to a content of from about 25 to about 75 g/l of SiO 2 .
Claim 15
Dependent Claim
24 words
The process as defined in claim 1 wherein the amount of polymer in the latex dispersion is from about 75 to about 250 g/l.
Claim 16
Dependent Claim
60 words
A plastic composition comprising a polymeric organic compound containing finely dispersed therein at least bivalent metal silicate the bivalent metal being selected from the group consisting of zinc, calcium, and magnesium, the plastic composition being substantially free of any hydroxy salt of the bivalent metal and of any alkali silicate, obtained according to the process as defined in claim 1.
Claim 17
Dependent Claim
18 words
A vulcanizable polymeric composition comprising a master batch composition as defined in claim 15 and a vulcanizing agent.
Claim 18
Dependent Claim
13 words
The vulcanizable polymeric composition as defined in claim 16 further comprising a mercaptosilane.
Claim 19
Dependent Claim
12 words
An elastomer obtained by vulcanizing the composition as defined in claim 16.
Claim 20
Dependent Claim
60 words
A plastic composition comprising a polymeric organic compound containing finely dispersed therein at least bivalent metal silicate the bivalent metal being selected from the group consisting of zinc, calcium and magnesium, the plastic composition being substantially free of any hydroxy salt of the bivalent metal and of any alkali silicate, obtained according to the process as defined in claim 6.
Claim 21
Dependent Claim
18 words
A vulcanizable polymeric composition comprising a master batch composition as defined in claim 19 and a vulcanizing agent.
Claim 22
Dependent Claim
13 words
The vulcanizable polymeric composition as defined in claim 20 further comprising a mercaptosilane.
Claim 23
Dependent Claim
12 words
An elastomer obtained by vulcanizing the composition as defined in claim 20.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-01-21 | 1983-07-23 | 1984-01-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-01-21 | 1987-07-23 | 1988-01-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-01-21 | 1991-07-23 | 1992-01-22 | $7700.00 | Window Closed / Lapsed |