US4183974A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Container coating method
Assignee: WR Grace and Co
•
Filing: 1977-03-24
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Granted: 1980-01-15
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Expires: 1997-03-24
Abstract
Abstract A method for coating a cylindrical container with a thin, resinous coating by spraying powdered resin is disclosed. The technique involves spraying of finely divided resin particles into a beverage container from spray nozzles external to the container. The container may be sprayed by directing a pulse of a predetermined quantum of resin into the container to deposit a substantially uniform coating. Alternatively, a continuous flow of resin at a predetermined rate may be sprayed into a container. The resin particles are caused to adhere to the container by preheating the container. The coating is rendered continuous by preheating the container to temperatures above the softening point of the resin. Postheating of the coated container at temperatures in excess of about 300° F. matures the coating.
Inventors
- 👤 Robert G. Coucher
- 👤 Gene Gerek
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 09:09
CPC Classifications
B; B05; B05D; B05D3/00; B05D3/14; B05D3/141; B05D3/145; B05D3/147; B05B; B05B13/00; B05B13/06; B05B13/0609; B05D1/00; B05D1/002; B05D1/02; B05D1/08; B05D1/10; B05D1/12; B05D3/08; B05D3/142; B05D7/00; B05D7/22; B05D7/227; B05D2202/00; B05D2202/10; B05D2202/20; B05D2202/25; B05D2401/00; B05D2401/30; B05D2401/32; B05D2504/00; B05D3/02; B05D3/0218; B05D3/0254
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
248 words
Method for applying an ultra thin resinous coating less than 1 mil in thickness to the entire interior surfaces of a plurality of thin-walled, cylindrical, metal beverage containers having an open end and a closed end, comprising: heating each container until at least its bottom is above the softening point of a selected resin; moving the thus heated containers in a sequence through an application zone, and while each container is in said application zone, and said bottom is above the softening point of said resin, introducing at least one pulse of said resin in finely divided solid form with maximum individual particle diameters of less than about 20 microns, said resin being suspended in a carrier gas, approximately axially toward the closed end of said container through the open end of said container from a region outside the container at a velocity sufficient to project particles of resin to the bottom of said container, thereby to cover substantially the entire interior surface of said container with a resinous coating; causing said resin particles to adhere to the interior surface of the sidewalls of said container by either heating said sidewalls to above the softening point of said resin, imposing tribo-electric charges on said resin particles or both heating said sidewalls to above the softening point of said resin and imposing tribo-electric charges on said resin particles; and moving the containers in sequence from said application zone and curing said coating into an adherent, solventfree, substantially continuous film.
Claim 2
Dependent Claim
248 words
Method for applying an ultra thin resinous coating less than 1 mil in thickness to the entire interior surfaces of a plurality of thin-walled, cylindrical, metal beverage containers having an open end and a closed end, comprising: heating each container until at least its bottom is above the softening point of a selected resin; moving the thus heated containers in a sequence through an application zone, and while each container is in said application zone, and said bottom is above the softening point of said resin, introducing at least one pulse of said resin in finely divided solid form with maximum individual particle diameters of less than about 20 microns, said resin being suspended in a carrier gas, approximately axially toward the closed end of said container through the open end of said container from a region outside the container at a velocity sufficient to project particles of resin to the bottom of said container, thereby to cover substantially the entire interior surface of said container with a resinous coating; causing said resin particles to adhere to the interior surface of the sidewalls of said container by either heating said sidewalls to above the softening point of said resin, imposing tribo-electric charges on said resin particles or both heating said sidewalls to above the softening point of said resin and imposing tribo-electric charges on said resin particles; and moving the containers in sequence from said application zone and curing said coating into an adherent, solventfree, substantially continuous film.
Claim 3
Dependent Claim
35 words
A method according to claim 1 wherein said pulse is created by directing the discharges from a pair of nozzles so that they intersect at the open end of the container at approximately its center.
Claim 4
Dependent Claim
41 words
A method according to claim 1 wherein each container is moved to the application zone and is indexed therein during the spray interval so that its central axis is fixed with respect to said zone during the interval of said pulse.
Claim 5
Dependent Claim
22 words
A method according to claim 1 wherein the containers are moved continuously through said application zone during the interval of said pulse.
Claim 6
Dependent Claim
39 words
A method according to claim 4 wherein said pulse is introduced through means which travel with each container so that the central axis of said container is fixed with respect to said means during the interval of said pulse.
Claim 7
Dependent Claim
25 words
A method according to claim 1 wherein at least two pulses of resin are so directed in said application zone prior to curing said coating.
Claim 8
Dependent Claim
13 words
A method according to claim 6 wherein the containers are comprised of steel.
Claim 9
Dependent Claim
55 words
A method according to claim 1 wherein the container is heated so that at the time said pulse is introduced, the interior surface at the bottom of the container is above the softening point of the resin and the interior surface of the sidewall of the container is below the softening point of said resin.
Claim 10
Dependent Claim
64 words
A method according to claim 8 wherein said pulse is directed toward the bottom of the container along approximately the center axis of the container so that a portion of the resin particles adhere to the bottom and the remainder of the resin particles are forced out towards the side walls and then along said side walls towards the open top of the container.
Claim 11
Dependent Claim
23 words
A method according to claim 9 wherein a first said pulse is followed by a second said pulse before said coating is cured.
Claim 12
Dependent Claim
40 words
A method according to claim 8 wherein said pulse is created by directing the approximately simultaneous discharges from a pair of nozzles into each other at a region outside the container and at approximately the center axis of said container.
Claim 13
Dependent Claim
38 words
A method according to claim 1 wherein said resin is dispersed in said carrier gas by means of sufficient tribo-electric charges imposed on said resin particles to cause said particles to adhere to the sidewalls of said container.
Claim 14
Dependent Claim
27 words
A method according to claim 1 wherein said container is an aluminum cylinder with one end closed and with side walls less than about 4 mils thick.
Claim 15
Dependent Claim
40 words
A method according to claim 1 wherein means for curing said resin after it is applied to said containers is provided in association with said application zone so that containers are introduced directly from said application through said curing zone.
Claim 16
Dependent Claim
15 words
A method according to claim 14 wherein said means for curing comprises electric oven means.
Claim 17
Dependent Claim
28 words
A method according to claim 14 further including means associated with said application zone for preheating said containers and continuously forwarding said containers directly to said application zone.
Claim 18
Dependent Claim
15 words
A method according to claim 16 wherein said means for preheating comprises electric oven means.
Claim 19
Dependent Claim
26 words
A method according to claim 1 wherein the average particle diameter of said resin particles is within the range of about 5 to about 10 microns.
Claim 20
Dependent Claim
14 words
A method according to claim 1 wherein the resin is a thermosetting epoxy resin.
Claim 21
Dependent Claim
220 words
Method for applying an ultra thin resinous coating less than 1 mil in thickness to the entire interior surfaces of a plurality of thin-walled, cylindrical, metal beverage containers, each having an open end, cylindrical sidewalls and a closed end, comprising: heating each container until at least its bottom is above the softening point of a selected resin; moving the thus heated containers in sequence through an application zone, and while each container is in said application zone, and said bottom is above the softening point of said resin, introducing at least one pulse of said resin in finely divided solid form wherein the maximum diameter of individual particles is less than about 20 microns, said resin being suspended in a carrier gas, approximately axially toward the closed end of said container through the open end of said container from a region outside the container at a velocity sufficient to project particles of resin to the bottom of said container, thereby to cover substantially the entire interior surface of said container with a resinuous coating; moving the containers in sequence from said application zone and curing said coating into an adherent, solventfree, substantially continuous film; wherein sufficient tribo-electric charge is imposed on said resin particles prior to their introduction into said container to promote adherence of said particles on said sidewalls.
Claim 22
Dependent Claim
220 words
Method for applying an ultra thin resinous coating less than 1 mil in thickness to the entire interior surfaces of a plurality of thin-walled, cylindrical, metal beverage containers, each having an open end, cylindrical sidewalls and a closed end, comprising: heating each container until at least its bottom is above the softening point of a selected resin; moving the thus heated containers in sequence through an application zone, and while each container is in said application zone, and said bottom is above the softening point of said resin, introducing at least one pulse of said resin in finely divided solid form wherein the maximum diameter of individual particles is less than about 20 microns, said resin being suspended in a carrier gas, approximately axially toward the closed end of said container through the open end of said container from a region outside the container at a velocity sufficient to project particles of resin to the bottom of said container, thereby to cover substantially the entire interior surface of said container with a resinuous coating; moving the containers in sequence from said application zone and curing said coating into an adherent, solventfree, substantially continuous film; wherein sufficient tribo-electric charge is imposed on said resin particles prior to their introduction into said container to promote adherence of said particles on said sidewalls.
Claim 23
Dependent Claim
35 words
A method according to claim 20 wherein said pulse is created by directing the discharges from a pair of nozzles so that they intersect at the open end of the container at approximately its center.
Claim 24
Dependent Claim
25 words
A method according to claim 20 wherein at least two pulses of resin are so directed in said application zone prior to curing said coating.
Claim 25
Dependent Claim
55 words
A method according to claim 20 wherein the container is heated so that at the time said pulse is introduced, the interior surface at the bottom of the container is above the softening point of the resin and the interior surface of the sidewall of the container is below the softening point of said resin.
Claim 26
Dependent Claim
64 words
A method according to claim 23 wherein said pulse is directed toward the bottom of the container along approximately the center axis of the container so that a portion of the resin particles adhere to the bottom and the remainder of the resin particles are forced out towards the side walls and then along said side walls towards the open top of the container.
Claim 27
Dependent Claim
23 words
A method according to claim 24 wherein a first said pulse is followed by a second said pulse before said coating is cured.
Claim 28
Dependent Claim
40 words
A method according to claim 25 wherein said pulse is created by directing the approximately simultaneous discharges from a pair of nozzles into each other at a region outside the container and at approximately the center axis of said container.
Claim 29
Dependent Claim
223 words
Method for applying a resinous coating less than 1 ml thick to the entire interior surface of a thinwalled, cylindrical, metal beverage container having an open top, cylindrical sidewalls and a bottom, said bottom including an annular moat region adjacent said sidewalls, comprising: preheating said container so that the temperature of its bottom is above the softening point of a selected resin; indexing a source of said resin outside the container with respect to the central axis of said container, and while the container is thus indexed and the bottom of the container is above said temperature, introducing at least one pulse of said resin approximately axially through the open top and toward the bottom of the container under conditions wherein: the resin is in powder form with the individual particles rounded and having maximum diameters less than about 20 microns, the resin is entrained in a carrier gas traveling at a velocity such that the velocity of individual particles of resin is sufficient to reach the bottom of the container, the pulse is less than about 50 milliseconds in duration, and the carrier gas and entrained resin are formed in a cloud-like spray pattern to assure coverage of said moat region; adhering resin to substantially the entire interior surface of said container; and curing said resin into a substantially uniform, solvent-free coating.
Claim 30
Dependent Claim
223 words
Method for applying a resinous coating less than 1 ml thick to the entire interior surface of a thinwalled, cylindrical, metal beverage container having an open top, cylindrical sidewalls and a bottom, said bottom including an annular moat region adjacent said sidewalls, comprising: preheating said container so that the temperature of its bottom is above the softening point of a selected resin; indexing a source of said resin outside the container with respect to the central axis of said container, and while the container is thus indexed and the bottom of the container is above said temperature, introducing at least one pulse of said resin approximately axially through the open top and toward the bottom of the container under conditions wherein: the resin is in powder form with the individual particles rounded and having maximum diameters less than about 20 microns, the resin is entrained in a carrier gas traveling at a velocity such that the velocity of individual particles of resin is sufficient to reach the bottom of the container, the pulse is less than about 50 milliseconds in duration, and the carrier gas and entrained resin are formed in a cloud-like spray pattern to assure coverage of said moat region; adhering resin to substantially the entire interior surface of said container; and curing said resin into a substantially uniform, solvent-free coating.
Claim 31
Dependent Claim
28 words
A method according to claim 27 wherein the sidewalls of the container are between about 80° F. and about 150° F. when said pulse of resin is introduced.
Claim 32
Dependent Claim
24 words
A method according to claim 27 wherein a tribo-electric charge is imposed on said resin particles prior to introduction of said pulse of resin.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-01-14 | 1983-07-16 | 1984-01-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-01-14 | 1987-07-16 | 1988-01-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-01-14 | 1991-07-16 | 1992-01-15 | $7700.00 | Window Closed / Lapsed |