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US4182842A Expired / Lapsed US ⏱️ 0.0 years remaining

Poly(ester-amides)prepared from an aromatic dicarboxylic acid, ethylene glycol and a p-acylaminobenzoic acid

Assignee: Eastman Chemical Co
•
Filing: 1978-11-03
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Granted: 1980-01-08
•
Expires: 1998-11-03
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Abstract

Abstract Disclosed are poly(ester-amides) prepared from an aromatic dicarboxylic acid, ethylene glycol and a p-acylaminobenzoic acid. These poly(ester-amides) contain the following divalent radicals: ##STR1##

Inventors

  • 👤 Winston J. Jackson
  • 👤 Herbert F. Kuhfuss

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:52
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/44

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 149 words
A process comprising (1) preparing a fragmented poly(ester-amide) by contacting within a temperature range of about 250° to about 300° C. (A) a starting polyester having an inherent viscosity of at least about 0.2 comprised of divalent radicals corresponding to the formula ##STR19## wherein ##STR20## wherein X is Cl--, Br--, or a monovalent alkyl radical having one to three carbon atoms and n is 0, 1 or 2, and (B) from about 10 to about 35 mole percent, based on the total moles of p-acylaminobenzoic acid and ##STR21## combined, a p-acylaminobenzoic acid corresponding to the formula ##STR22## wherein R 2 is phenyl or a monovalent alkyl radical of 1 to 8 carbon atoms, and (2) preparing a final poly(ester-amide) having an inherent viscosity of at least 0.4 by increasing the inherent viscosity of the fragmented polyester by exposing the fragmented polyester to a suitable pressure and a suitable temperature.
Claim 2
Dependent Claim 149 words
A process comprising (1) preparing a fragmented poly(ester-amide) by contacting within a temperature range of about 250° to about 300° C. (A) a starting polyester having an inherent viscosity of at least about 0.2 comprised of divalent radicals corresponding to the formula ##STR19## wherein ##STR20## wherein X is Cl--, Br--, or a monovalent alkyl radical having one to three carbon atoms and n is 0, 1 or 2, and (B) from about 10 to about 35 mole percent, based on the total moles of p-acylaminobenzoic acid and ##STR21## combined, a p-acylaminobenzoic acid corresponding to the formula ##STR22## wherein R 2 is phenyl or a monovalent alkyl radical of 1 to 8 carbon atoms, and (2) preparing a final poly(ester-amide) having an inherent viscosity of at least 0.4 by increasing the inherent viscosity of the fragmented polyester by exposing the fragmented polyester to a suitable pressure and a suitable temperature.
Claim 3
Dependent Claim 32 words
The process of claim 1 wherein ##STR23## the range of p-acylaminobenzoic acid is 25 to 30 mole percent, and R 2 is a monovalent alkyl radical having 1 to 4 carbon atoms.
Claim 4
Dependent Claim 20 words
The process of claim 2 wherein step (1) is conducted within a temperature range of 270° C. to 280° C.
Claim 5
Dependent Claim 7 words
The process of claim 3 wherein ##STR24##
Claim 6
Dependent Claim 7 words
Product of the process of claim 1.
Claim 7
Dependent Claim 7 words
Product of the process of claim 2.
Claim 8
Dependent Claim 7 words
Product of the process of claim 3.
Claim 9
Dependent Claim 7 words
Product of the process of claim 4.

References Cited (Backward Citations)

US3671542A Cited
US3778410A Cited
US3804805A Cited
US3926923A Cited
US4043981A Cited
US4035356A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-01-07 1983-07-09 1984-01-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-01-07 1987-07-09 1988-01-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-01-07 1991-07-09 1992-01-08 $7700.00 Window Closed / Lapsed

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