US4182828A
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Production of solutions or dispersions of polyisocyanate polyaddition products containing urethane and/or urea groups and containing both anionic and cationic groups
Assignee: Bayer AG
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Filing: 1978-04-27
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Granted: 1980-01-08
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Expires: 1998-04-27
Abstract
Abstract This invention relates to a process for the production of new, non-foamed urethane and/or urea group-containing polyisocyanate polyaddition products which contain both cationic and also anionic groups chemically bound into the same molecule of said polyisocyanate polyaddition products, to the polyaddition products obtainable by this process and to the use thereof for coating flexible and non-flexible sheet-form materials.
Inventors
- 👤 Artur Reischl
- 👤 Wolfgang Wenzel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 12:32
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0804; C08G18/0833; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31558; Y10T428/31598; Y10T428/31601; Y10T442/00; Y10T442/20
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
291 words
A process for the production of solutions or dispersions of non-foamed urethane and/or urea group-containing polyisocyanate polyaddition products in which chemically fixed anionic groups and chemically fixed cationic groups are simultaneously present in a medium selected from the group consisting of water, organic solvents and dispersants which comprises reacting: (a) isocyanates selected from the group consisting of organic polyisocyanates and organic monoisocyanates; with (b) organic compounds selected from the group consisting of organic compounds containing at least two isocyanate-reactive groups and organic compounds containing one isocyanate-reactive group, compounds containing ionic groups and/or groups which may be converted into ionic groups being used as component (a) and/or component (b), characterized in that the compounds containing ionic groups or groups convertible into ionic groups which are used in accordance with the present invention are both: (i) compounds containing anionic groups and/or groups convertible into anionic groups; and (ii) compounds containing cationic groups and/or groups convertible into cationic groups; any groups convertible into ionic groups which are present in the polyaddition product on completion of its synthesis being at least partly converted into ionic groups, in known manner by neutralization or quaternization, and the synthesis components used and the degree of neutralization and quaternization being selected in such a way that an equivalent ratio between cationic and anionic groups of from about 5:1 to 1:10 prevails in the end product ultimately obtained for a total content of ionic groups of from about 2 to 300 milliequivalents per 100 g of solids and in that at least one urethane or urea group is present between every cationic and anionic group which is chemically fixed in the end product, and (c) dissolving or dispersing the polyisocyanate polyaddition products during or after their production in said medium.
Claim 2
Dependent Claim
291 words
A process for the production of solutions or dispersions of non-foamed urethane and/or urea group-containing polyisocyanate polyaddition products in which chemically fixed anionic groups and chemically fixed cationic groups are simultaneously present in a medium selected from the group consisting of water, organic solvents and dispersants which comprises reacting: (a) isocyanates selected from the group consisting of organic polyisocyanates and organic monoisocyanates; with (b) organic compounds selected from the group consisting of organic compounds containing at least two isocyanate-reactive groups and organic compounds containing one isocyanate-reactive group, compounds containing ionic groups and/or groups which may be converted into ionic groups being used as component (a) and/or component (b), characterized in that the compounds containing ionic groups or groups convertible into ionic groups which are used in accordance with the present invention are both: (i) compounds containing anionic groups and/or groups convertible into anionic groups; and (ii) compounds containing cationic groups and/or groups convertible into cationic groups; any groups convertible into ionic groups which are present in the polyaddition product on completion of its synthesis being at least partly converted into ionic groups, in known manner by neutralization or quaternization, and the synthesis components used and the degree of neutralization and quaternization being selected in such a way that an equivalent ratio between cationic and anionic groups of from about 5:1 to 1:10 prevails in the end product ultimately obtained for a total content of ionic groups of from about 2 to 300 milliequivalents per 100 g of solids and in that at least one urethane or urea group is present between every cationic and anionic group which is chemically fixed in the end product, and (c) dissolving or dispersing the polyisocyanate polyaddition products during or after their production in said medium.
Claim 3
Dependent Claim
89 words
Solutions or dispersions of non-foamed polyisocyanate polyaddition products containing urethane and/or urea groups in a medium selected from the group consisting of water, organic solvents and dispersants, characterized by a content of from about 2 to 300 milliequivalents of ionic groups per 100 g of solids chemically bound into the polyisocyanate polyaddition products which are made up of cationic and anionic groups in an equivalent ratio of from about 5:1 to 1:10, the cationic groups being separated from the anionic groups by at least one urethane and/or urea group.
Claim 4
Dependent Claim
89 words
Solutions or dispersions of non-foamed polyisocyanate polyaddition products containing urethane and/or urea groups in a medium selected from the group consisting of water, organic solvents and dispersants, characterized by a content of from about 2 to 300 milliequivalents of ionic groups per 100 g of solids chemically bound into the polyisocyanate polyaddition products which are made up of cationic and anionic groups in an equivalent ratio of from about 5:1 to 1:10, the cationic groups being separated from the anionic groups by at least one urethane and/or urea group.
Claim 5
Dependent Claim
30 words
Flexible or non-flexiblle sheet-form materials coated with the polyisocyanate polyaddition products of claim 2 dissolved or dispersed in mediums selected from the group consisting of water, organic solvents and dispersants.
Claim 6
Dependent Claim
177 words
A process for the production of a solution or dispersion of a non-foamed urethane group- and/or urea grop-containing polyisocyanate polyaddition product in which chemically bound anionic and cationic groups are simultaneously present comprising reacting (a) organic polyisocyanates with (b) organic compounds containing at least two isocyanate-reactive groups, wherein at least some of at least one of components (a) or (b) contain dispersing centers selected from the group consisting of anionic groups, potential anionic groups, cationic groups and potential cationic groups, and (c) dissolving or dispersing said polyisocyanate polyaddition product during or after its production in a medium selected from the group consisting of water, organic solvents and dispersants, said process resulting in a polyisocyanate polyaddition product (i) containing cationic and anionic groups in an equivalent ratio of from about 5:1 to 1:10, (ii) having a total content of ionic groups of from about 2 to 300 milliequivalents per 100 g of solids, and (iii) having at least one urethane or urea group between each cationic and anionic group which is chemically bound into the polyisocyanate polyaddition product.
Claim 7
Dependent Claim
177 words
A process for the production of a solution or dispersion of a non-foamed urethane group- and/or urea grop-containing polyisocyanate polyaddition product in which chemically bound anionic and cationic groups are simultaneously present comprising reacting (a) organic polyisocyanates with (b) organic compounds containing at least two isocyanate-reactive groups, wherein at least some of at least one of components (a) or (b) contain dispersing centers selected from the group consisting of anionic groups, potential anionic groups, cationic groups and potential cationic groups, and (c) dissolving or dispersing said polyisocyanate polyaddition product during or after its production in a medium selected from the group consisting of water, organic solvents and dispersants, said process resulting in a polyisocyanate polyaddition product (i) containing cationic and anionic groups in an equivalent ratio of from about 5:1 to 1:10, (ii) having a total content of ionic groups of from about 2 to 300 milliequivalents per 100 g of solids, and (iii) having at least one urethane or urea group between each cationic and anionic group which is chemically bound into the polyisocyanate polyaddition product.
Claim 8
Dependent Claim
34 words
The process of claim 4 wherein any potential anionic or cationic groups contained in the polyisocyanate polyaddition product after its synthesis are at least partly converted into ionic groups by neutralization or quaternization processes.
Claim 9
Dependent Claim
40 words
The process of claim 4 wherein the cationic groups contained in the polyisocyanate polyaddition product are in the form of potential cationic groups during the synthesis of the polyaddition product and then subsequently converted to cationic groups by quaternization processes.
Claim 10
Dependent Claim
63 words
The process of claim 4 wherein component (a) contains organic polyisocyanates of the formula Q(NCO).sub.2 wherein Q represents an aliphatic hydrocarbon radical containing from 4 to 12 carbon atoms, a cycloaliphatic hydrocarbon radical containing from 6 to 15 carbon atoms, an aromatic hydrocarbon radical containing from 6 to 15 carbon atoms, or an araliphatic hydrocarbon radical containing from 7 to 15 carbon atoms.
Claim 11
Dependent Claim
48 words
The process of claim 4 wherein component (b) contains organic compounds containing at least two isocyanate-reactive groups having a molecular weight of from about 62 to 10,000 and selected from the group consisting of hydroxy polyesters, hydroxy polyethers, hydroxy polythioethers, hydroxy polyacetals, hydroxy polycarbonates and hydroxy polyester amides.
Claim 12
Dependent Claim
24 words
The process of claim 4 wherein compounds selected from the group consisting of organic monoisocyanates and organic compounds containing one isocyanate-reactive group are present.
Claim 13
Dependent Claim
28 words
The process of claim 4 wherein the resulting polyisocyanate polyaddition product has a total ionic content of from about 5 to 100 milliequivalents per 100 g of solids.
Claim 14
Dependent Claim
20 words
The process of claim 4 wherein the ratio of isocyanate groups to isocyanate-reactive groups is from about 0.8:1 to 1.2:1.
Claim 15
Dependent Claim
26 words
The polyisocyanate polyaddition products of claim 2 wherein the ionic groups are selected from the group consisting of ##STR4## --CO 2 .sup.⊖ and --SO 3 .sup.⊖.
Claim 16
Dependent Claim
25 words
The process of claims 1 or 4 wherein the medium is selected from the group consisting of water with water-miscible solvents and organic polyhydroxyl compounds.
Claim 17
Dependent Claim
12 words
The process of claims 1 or 4 wherein the medium is water.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-01-07 | 1983-07-09 | 1984-01-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-01-07 | 1987-07-09 | 1988-01-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-01-07 | 1991-07-09 | 1992-01-08 | $7700.00 | Window Closed / Lapsed |