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US4179435A Expired / Lapsed US ⏱️ 0.0 years remaining

Azo dyestuffs having a carboxyl group and a substituted sulfonylimino group in the coupling component

Assignee: BASF Corp
•
Filing: 1978-06-22
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Granted: 1979-12-18
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Expires: 1998-06-22
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Abstract

Abstract Dyestuffs of the formula ##STR1## wherein D is a heterocyclic diazo component, R 1 is an alkyl radical which may be substituted, R 2 is phenylene or alkylene d is hydrogen, chloro, lower alkyl, lower alkoxy, aryl, aryloxy or arylmercapto, and R is an optionally substituted alkyl, aryl or amino group, dye polyester fibers in red and blue shades with good fasteners, and are suitable for use in the thermosol process.

Inventors

  • 👤 Visvanathan Ramanathan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:48
CPC Classifications
C; C09; C09B; C09B29/00; C09B29/06; C09B29/08; C09B29/0801; C09B29/0802; C09B29/0025

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 307 words
A dyestuff of the formula ##STR44## in which D is a diazo component radical selected from the group consisting of thiazolyl which is unsubstituted or substituted by chloro, bromo, nitro, cyano, thiocyano, lower alkyl, lower aralkyl, phenyl, lower cyanoalkyl, lower alkoxy, lower alkoxycarbonyl, trifluoromethyl, lower alkylcarbonyl or lower alkylsulfonyl; benzthiazole which is unsubstituted or substituted by chloro, bromo, cyano, thiocyano, lower alkyl, lower alkoxy, lower aralkoxy, phenyl, lower alkylmercapto, lower alkylsulfonyl, trifluoromethyl, nitro, cyanoethylsulfonyl, aminosulfonyl, monoalkylated aminosulfonyl, dialkylated aminosulfonyl, or lower alkoxycarbonyl; pyrazole which is unsubstituted or substituted by cyano, lower alkyl, lower alkoxy, lower alkoxycarbonyl or phenyl; thiadiazolyl which is unsubstituted or substituted by chloro, bromo, lower alkoxy, alkylmercapto, lower alkyl, lower alkylsulfonyl, phenyl, methylthiophenyl, nitrophenyl, tolyl, chlorophenyl or bromophenyl; imidazolyl which is unsubstituted or substituted by nitro or lower alkyl; thienyl which is unsubstituted or substituted by nitro, lower alkoxycarbonyl, lower alkyl, lower alkylsulfonyl, acetyl, aminosulfonyl or alkylated aminosulfonyl; isothiazolyl which is unsubstituted or substituted by alkyl, phenyl or cyano; benzisothiazolyl which is unsubstituted or substituted by lower alkyl, nitro, bromo or chloro; and pyridyl which is substituted by lower alkyl, cyano, bromo or chloro; d is hydrogen, chloro, lower alkyl, lower alkoxy, lower alkylmercapto, aryl, aryloxy or arylmercapto; R 1 is C 1 -C 5 alkyl which is unsubstituted or substituted by chloro, bromo, hydroxy, phenoxy, phenyl, cyano, C 1 -C 4 -alkoxy, formylamino, C 1 -C 4 -alkylcarboxyloxy, C 1 -C 4 -alkylcarbamoyloxy, phenylcarbamoyloxy, C 1 -C 3 -alkoxycarbamoyloxy, benzoyloxy, phenoxycarbonyloxy or benzoyloxy; R 2 is straight or branched chain alkylene of 1 to 4 carbon atoms; and R is C 1 -C 5 alkyl or a group of the formula ##STR45## where R 3 and R 4 are C 1 -C 5 alkyl, or R 3 and R 4 together with the nitrogen to which they are attached, represent morpholino or piperidino.
Claim 2
Dependent Claim 307 words
A dyestuff of the formula ##STR44## in which D is a diazo component radical selected from the group consisting of thiazolyl which is unsubstituted or substituted by chloro, bromo, nitro, cyano, thiocyano, lower alkyl, lower aralkyl, phenyl, lower cyanoalkyl, lower alkoxy, lower alkoxycarbonyl, trifluoromethyl, lower alkylcarbonyl or lower alkylsulfonyl; benzthiazole which is unsubstituted or substituted by chloro, bromo, cyano, thiocyano, lower alkyl, lower alkoxy, lower aralkoxy, phenyl, lower alkylmercapto, lower alkylsulfonyl, trifluoromethyl, nitro, cyanoethylsulfonyl, aminosulfonyl, monoalkylated aminosulfonyl, dialkylated aminosulfonyl, or lower alkoxycarbonyl; pyrazole which is unsubstituted or substituted by cyano, lower alkyl, lower alkoxy, lower alkoxycarbonyl or phenyl; thiadiazolyl which is unsubstituted or substituted by chloro, bromo, lower alkoxy, alkylmercapto, lower alkyl, lower alkylsulfonyl, phenyl, methylthiophenyl, nitrophenyl, tolyl, chlorophenyl or bromophenyl; imidazolyl which is unsubstituted or substituted by nitro or lower alkyl; thienyl which is unsubstituted or substituted by nitro, lower alkoxycarbonyl, lower alkyl, lower alkylsulfonyl, acetyl, aminosulfonyl or alkylated aminosulfonyl; isothiazolyl which is unsubstituted or substituted by alkyl, phenyl or cyano; benzisothiazolyl which is unsubstituted or substituted by lower alkyl, nitro, bromo or chloro; and pyridyl which is substituted by lower alkyl, cyano, bromo or chloro; d is hydrogen, chloro, lower alkyl, lower alkoxy, lower alkylmercapto, aryl, aryloxy or arylmercapto; R 1 is C 1 -C 5 alkyl which is unsubstituted or substituted by chloro, bromo, hydroxy, phenoxy, phenyl, cyano, C 1 -C 4 -alkoxy, formylamino, C 1 -C 4 -alkylcarboxyloxy, C 1 -C 4 -alkylcarbamoyloxy, phenylcarbamoyloxy, C 1 -C 3 -alkoxycarbamoyloxy, benzoyloxy, phenoxycarbonyloxy or benzoyloxy; R 2 is straight or branched chain alkylene of 1 to 4 carbon atoms; and R is C 1 -C 5 alkyl or a group of the formula ##STR45## where R 3 and R 4 are C 1 -C 5 alkyl, or R 3 and R 4 together with the nitrogen to which they are attached, represent morpholino or piperidino.
Claim 3
Dependent Claim 19 words
A azo dyestuff according to claim 1, which has the formula ##STR46## wherein n is at the most 3.
Claim 4
Dependent Claim 11 words
An azo dyestuff according to claim 2, which has formula ##STR47##
Claim 5
Dependent Claim 15 words
An azo dyestuff according to claim 1, wherein R is C 1 -C 5 -alkyl.
Claim 6
Dependent Claim 36 words
An azo dyestuff according to claim 1, wherein R is of the formula ##STR48## in which R 3 and R 4 are C 1 -C 5 alkyl or together with the nitrogen form morpholino or piperidino.
Claim 7
Dependent Claim 12 words
An azo dyestuff as claimed in claim 1, of the formula ##STR49##

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-17 1983-06-18 1983-12-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-17 1987-06-18 1987-12-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-17 1991-06-18 1991-12-18 $7700.00 Window Closed / Lapsed

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