US4179331A
Expired / Lapsed
US
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Glass fiber dispersions for making uniform glass fiber mats by the wet-laid process
Assignee: Building Materials Corp of America
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Filing: 1977-11-15
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Granted: 1979-12-18
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Expires: 1997-11-15
Abstract
Abstract In accordance with the present invention, there is provided herein improved glass fiber dispersions for making uniform glass fiber mats by the wet-laid process. The well dispersed glass fiber compositions of this invention usually are prepared by mixing chopped glass fiber bundles in water with a small amount of an amine oxide surfactant to disperse the bundles into individual fibers. As a feature of the invention, the dispersions may be formed at relatively high glass fiber consistencies. The resultant dispersions then are used to make very high quality glass fiber mats at high rates of production.
Inventors
- 👤 Paritosh M. Chakrabarti
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 12:43
CPC Classifications
D; D21; D21H; D21H13/00; D21H13/36; D21H13/38; D21H13/40; C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/25
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
152 words
In the manufacture of uniform glass mats at a high rate of production by the wet-laid process, the improved method which comprises forming an aqueous dispersion of glass fibers by mixing bundles of said fibers of about 1/4 to 3 inches in length in an aqueous medium at a fiber consistency of about 0.001 to 3.0% with about 5-500 ppm of an amine oxide surfactant having the formula: ##STR15## where R 1 , R 2 , and R 3 are selected from the group consisting of aliphatic and aromatic hydrocarbon radicals, substituted or unsubstituted, containing between 1 and 30 carbon atoms, being the same or different, the sum of R 1 , R 2 and R 3 being between about 14 to 40, thereby to substantially disperse said bundles into individual fibers within the aqueous medium, and, passing said dispersion through a mat-forming screen to form the desired uniform glass fiber mat.
Claim 2
Dependent Claim
152 words
In the manufacture of uniform glass mats at a high rate of production by the wet-laid process, the improved method which comprises forming an aqueous dispersion of glass fibers by mixing bundles of said fibers of about 1/4 to 3 inches in length in an aqueous medium at a fiber consistency of about 0.001 to 3.0% with about 5-500 ppm of an amine oxide surfactant having the formula: ##STR15## where R 1 , R 2 , and R 3 are selected from the group consisting of aliphatic and aromatic hydrocarbon radicals, substituted or unsubstituted, containing between 1 and 30 carbon atoms, being the same or different, the sum of R 1 , R 2 and R 3 being between about 14 to 40, thereby to substantially disperse said bundles into individual fibers within the aqueous medium, and, passing said dispersion through a mat-forming screen to form the desired uniform glass fiber mat.
Claim 3
Dependent Claim
20 words
A method according to claim 1 wherein the R 1 , R 2 and R 3 radicals are aliphatic radicals.
Claim 4
Dependent Claim
18 words
A method according to claim 2 wherein said radicals are selected from alkyl, hydroxyalkyl and substituted radicals thereof.
Claim 5
Dependent Claim
14 words
A method according to claim 1 wherein said sum is about 18 to 24.
Claim 6
Dependent Claim
36 words
A method according to claim 1 wherein at least one of said radicals is lower alkyl or hydroxy lower alkyl, and at least one of said radicals is a long chain alkyl or alkyl substituted group.
Claim 7
Dependent Claim
23 words
A method according to claim 1 wherein said amine oxide is present in an amount of about 5-100 ppm of said aqueous dispersion.
Claim 8
Dependent Claim
16 words
A method according to claim 1 wherein said amount of amine oxide is about 10-25 ppm.
Claim 9
Dependent Claim
28 words
A method according to claim 1 wherein said glass fibers are diluted from a more concentrated consistency to a lower consistency before being passed through said mat-forming screen.
Claim 10
Dependent Claim
14 words
A method according to claim 1 wherein consistency is about 0.05 to about 1%.
Claim 11
Dependent Claim
16 words
A method according to claim 1 wherein said amine oxide is dimethyl hydrogenated tallow amine oxide.
Claim 12
Dependent Claim
13 words
A method according to claim 1 wherein said amine oxide is dimethylstearylamine oxide.
Claim 13
Dependent Claim
13 words
A method according to claim 1 wherein said amine oxide is dimethylhexadecylamine oxide.
Claim 14
Dependent Claim
15 words
A method according to claim 1 wherein said amine oxide is bis(2-hydroxyethyl) tallow amine oxide.
Claim 15
Dependent Claim
17 words
A method according to claim 1 wherein said fibers are about 1/2 to 2 inches in length.
Claim 16
Dependent Claim
18 words
A method according to claim 1 wherein said fibers are about 3 to about 20 microns in diameter.
Claim 17
Dependent Claim
21 words
A method according to claim 1 further characterized in that the dispersion is prepared at or near a neutral pH condition.
Claim 18
Dependent Claim
28 words
A method according to claim 1 further including the steps of drying and curing said mat with a binder to form a finished mat product of high quality.
Claim 19
Dependent Claim
15 words
A method according to claim 1, wherein said fibers are about 1 inch in length.
Claim 20
Dependent Claim
15 words
A method according to claim 1, wherein said fibers are about 15 microns in diameter.
Claim 21
Dependent Claim
39 words
A method according to claim 1 which further comprises: (a) precoating said glass fibers with said amine oxide, having the formula of claim 1, and; (b) adding said thus-coated fibers to an aqueous medium to form said desired dispersion.
Claim 22
Dependent Claim
21 words
A method according to claim 20 wherein said coated fibers contain about 0.01 to 1% by weight of the amine oxide.
Claim 23
Dependent Claim
20 words
A method according to claim 21 wherein the fibers are coated with between 0.025 to 0.25% of the amine oxide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-12-17 | 1983-06-18 | 1983-12-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-12-17 | 1987-06-18 | 1987-12-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-12-17 | 1991-06-18 | 1991-12-18 | $7700.00 | Window Closed / Lapsed |