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US4178438A Expired / Lapsed US ⏱️ 0.0 years remaining

Cationically modified, cellulose-containing materials

Assignee: BASF Corp
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Filing: 1978-09-11
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Granted: 1979-12-11
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Expires: 1998-09-11
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Abstract

Abstract A novel process for the purification of industrial effluents, wherein the effluents are brought into contact with cationically modified, cellulose-containing materials, the cationic constituent of which is bonded to the cellulose part via the grouping of the general formula --O--CH.sub.2 --N< in which the nitrogen belongs to an amide group of the cationic constituent and the oxygen is bonded to the cellulose part, and the cationically modified, cellulose-containing materials possessing such a constituent, are disclosed.

Inventors

  • 👤 Jaroslav Haase
  • 👤 Peter Liechti
  • 👤 Hans Wegmuller
  • 👤 Rudolf F. Wurster
  • 👤 Quentin Bowes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:18
CPC Classifications
C; C08; C08B; C08B11/00; C08B11/02; C08B11/04; C08B11/14; C08B11/145; B; B01; B01J; B01J39/00; B01J39/08; B01J39/16; B01J39/18; B01J39/22; C02; C02F; C02F1/00; C02F1/28; C02F1/286; Y; Y10; Y10S; Y10S210/00; Y10S210/902; Y10S210/917

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 109 words
Cationically modified cellulose material which contains at least 0.4% by weight of basic nitrogen and has a cationic constituent derived from a basic amide compound of the formula wherein R" represents hydrogen or C 1 -C 4 -alkyl, R 1 and R 2 independently of one another represent hydrogen, lower alkyl which is unsubstituted or substituted by halogen, hydroxyl, lower alkoxy or cyano, or cycloalkyl or benzyl, or R 1 and R 2 , together with the nitrogen atom which links them, denote a 5-membered or 6-membered heterocyclic radical, Q denotes alkylene or alkyl-substituted alkylene each with up to 8 carbon atoms and Y denotes hydrogen, lower alkyl or
Claim 2
Dependent Claim 109 words
Cationically modified cellulose material which contains at least 0.4% by weight of basic nitrogen and has a cationic constituent derived from a basic amide compound of the formula wherein R" represents hydrogen or C 1 -C 4 -alkyl, R 1 and R 2 independently of one another represent hydrogen, lower alkyl which is unsubstituted or substituted by halogen, hydroxyl, lower alkoxy or cyano, or cycloalkyl or benzyl, or R 1 and R 2 , together with the nitrogen atom which links them, denote a 5-membered or 6-membered heterocyclic radical, Q denotes alkylene or alkyl-substituted alkylene each with up to 8 carbon atoms and Y denotes hydrogen, lower alkyl or
Claim 3
Dependent Claim 62 words
Cationically modified cellulose material according to claim 1 wherein the cationic constituent is derived from a compound of the formula (4) in which R 1 and R 2 both denote lower alkyl or lower alkoxy-lower alkyl, or R 1 and R 2 , together with the common nitrogen atom, denote a morpholino radical, Q denotes C 1 -C 3 -alkylene and Y
Claim 4
Dependent Claim 36 words
Cationically modified cellulose material according to claim 2, wherein the cationic constituent is derived from a compound of the formula (4) in which R 1 and R 2 both denote methyl or ethyl, Q denotes ethylene
Claim 5
Dependent Claim 48 words
Cationically modified cellulose material according to claim 2, wherein the cationic constituent is derived from a compound of the formula (4) in which R 1 and R 2 , together with the nitrogen atom which links them, denote morpholino, Q denotes ethylene and Y and R" denote hydrogen.
Claim 6
Dependent Claim 36 words
Cationically modified cellulose material according to claim 1, wherein the cationic constituent is derived from a compound of the formula (4) in which R 1 and R 2 both denote ethyl, Q denotes ethylene, Y denotes
Claim 7
Dependent Claim 36 words
Cationically modified cellulose material according to claim 1, wherein the cationic constituent is derived from a compound of the formula (4) in which R 1 and R 2 both denote ethyl, Q denotes ethylene, Y denotes
Claim 8
Dependent Claim 20 words
Cationically modified cellulose material wherein the cationic constituent is derived from a compound of the formula (CH 3 ) 3
Claim 9
Dependent Claim 20 words
Cationically modified cellulose material wherein the cationic constituent is derived from a compound of the formula (CH 3 ) 3
Claim 10
Dependent Claim 350 words
Cationically modified cellulose material which contains at least 0.4% by weight of basic nitrogen and has a cationic constituent derived from a quaternary ammonium of the formula ##STR32## in which V 2 and V 3 independently of one another denote hydrogen, lower alkyl which is optionally substituted by halogen, cyano, hydroxy or lower alkoxy, or benzyl or the group of the formula (5) ##STR33## any two of R 3 , R 4 and V 2 , together with the nitrogen atom which links them, denote a pyridine ring which is optionally substituted by lower alkyl and An.sup.⊖ denotes the anion of an organic or inorganic acid and R 3 , R 4 , R 5 and R 6 independently of one another denote hydrogen, lower alkyl which is unsubstituted or substituted by hydroxyl, cyano, halogen or lower alkoxy, or cycloalkyl, benzyl or the group of the formula (5) ##STR34## or R 3 and R 4 , together with the nitrogen atom which links them, denote a 5-membered or 6-membered heterocyclic radical or, if n is 1, R 4 and R 5 , together with the grouping >N-Q 1 -N< which links them, also denote a divalent heterocyclic radical, especially a piperazino ring, R" represents hydrogen or C 1 -C 4 -alkyl, Q and Q 1 represent alkylene or alkyl-substituted alkylene and with up to 8 carbon atoms Y represents hydrogen, lower alkyl or --CH 2 OR"--, and n denotes 1 to 1000, and at least one of R 3 , R 4 , R 5 , R 6 , V 2 and V 3 represents the group of the formula (5) and, if n denotes more than 1, each R 5 , or each V 3 , independently of the others, can represent hydrogen, lower alkyl which is optionally substituted by halogen, cyano, hydroxyl or lower alkoxy, or benzyl or the group of the formula (5), or each R 5 , or individual R 5 s, together with the adjacent R 5 and with the common grouping >N-Q 1 -N<, also represent a divalent heterocyclic radical, especially a piperazino ring.
Claim 11
Dependent Claim 350 words
Cationically modified cellulose material which contains at least 0.4% by weight of basic nitrogen and has a cationic constituent derived from a quaternary ammonium of the formula ##STR32## in which V 2 and V 3 independently of one another denote hydrogen, lower alkyl which is optionally substituted by halogen, cyano, hydroxy or lower alkoxy, or benzyl or the group of the formula (5) ##STR33## any two of R 3 , R 4 and V 2 , together with the nitrogen atom which links them, denote a pyridine ring which is optionally substituted by lower alkyl and An.sup.⊖ denotes the anion of an organic or inorganic acid and R 3 , R 4 , R 5 and R 6 independently of one another denote hydrogen, lower alkyl which is unsubstituted or substituted by hydroxyl, cyano, halogen or lower alkoxy, or cycloalkyl, benzyl or the group of the formula (5) ##STR34## or R 3 and R 4 , together with the nitrogen atom which links them, denote a 5-membered or 6-membered heterocyclic radical or, if n is 1, R 4 and R 5 , together with the grouping >N-Q 1 -N< which links them, also denote a divalent heterocyclic radical, especially a piperazino ring, R" represents hydrogen or C 1 -C 4 -alkyl, Q and Q 1 represent alkylene or alkyl-substituted alkylene and with up to 8 carbon atoms Y represents hydrogen, lower alkyl or --CH 2 OR"--, and n denotes 1 to 1000, and at least one of R 3 , R 4 , R 5 , R 6 , V 2 and V 3 represents the group of the formula (5) and, if n denotes more than 1, each R 5 , or each V 3 , independently of the others, can represent hydrogen, lower alkyl which is optionally substituted by halogen, cyano, hydroxyl or lower alkoxy, or benzyl or the group of the formula (5), or each R 5 , or individual R 5 s, together with the adjacent R 5 and with the common grouping >N-Q 1 -N<, also represent a divalent heterocyclic radical, especially a piperazino ring.
Claim 12
Dependent Claim 56 words
Cationically modified cellulose material according to claim 8, wherein the cationic constituent is derived from a quaternary ammonium compound of the formula ##STR35## in which R 1 , R 2 , R 3 , R", V 1 , Q, Q 1 , Y and An.sup.⊖ have the meaning indicated in claim 8 and m is 2.
Claim 13
Dependent Claim 73 words
Cationically modified cellulose material according to claim 9, wherein the cationic constituent is derived from a quaternary ammonium compoud of the formula ##STR36## in which R 1 " and R 2 " each denote lower alkyl, R 3 ' denotes hydrogen or the group of the formula -Q"-CO-NH-CH 2 OH, Q 1 ' represents ethylene or propylene, Q" represents C 1 -C 3 -alkylene and An.sup.⊖ has the meaning indicated in claim 8.
Claim 14
Dependent Claim 61 words
Cationically modified cellulose material according to claim 10, wherein the cationic constituent is derived from a compound of the formula (13) in which R 1 ", R 2 " and V 1 ' each denote ethyl, R 3 ' denotes the group --Q'--CO--NH--CH 2 OH, Q' denotes ethylene, Q 1 ' denotes propylene and An.sup.⊖ denotes a chloride or bromide ion.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-10 1983-06-11 1983-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-10 1987-06-11 1987-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-10 1991-06-11 1991-12-11 $7700.00 Window Closed / Lapsed

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