US4178352A
Expired / Lapsed
US
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Synthesis of type Y zeolite
Assignee: WR Grace and Co Conn
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Filing: 1978-09-21
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Granted: 1979-12-11
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Expires: 1998-09-21
Abstract
Abstract Type Y zeolite is prepared using a minimum excess of reactants by a method wherein required sodium hydroxide, silica, alumina and water reactants are combined in multi-stage procedure to obtain a uniform fluid reaction slurry. The procedure permits the efficient commercial production of high quality type Y zeolite and minimizes the formation of excess silicate containing by-product effluent.
Inventors
- 👤 David E. W. Vaughan
- 👤 Grant C. Edwards
- 👤 Michael G. Barrett
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 18:05
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/20; C01B33/26; C01B33/28; C01B33/2807; C01B33/2838; C01B33/2853; Y; Y10; Y10S; Y10S423/00; Y10S423/21
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
260 words
A process for preparing type Y zeolite comprising: (a) preparing a slurry of zeolitic nucleation centers having an average particle size below about 0.1 micron, said slurry having the following mol ratio composition: 12 to 19 Na 2 O; 0.7 to 9 Al 2 O 3 ; 12 to 19 SiO 2 ; 220 to 900 H 2 O; (b) preparing an intermediate reaction mixture by combining the nucleation center composition of step (a) with additional sources of Na 2 O, Al 2 O 3 , SiO 2 and H 2 O to obtain a mixture having the following mol ratio composition: 2 to 6 Na 2 O; 4.5 to 11 SiO 2 ; Al 2 O 3 ; 30 to 200 H 2 O; (c) agitating and heating said intermediate reaction mixture of step (b) at a temperature of from about 30° to 80° C.; (d) mixing an acid compound selected from the group comprising mineral acids, aluminum salts of mineral acids and mixtures thereof to the reaction mixture of step (c) to obtain a final reaction mixture having the following mol ratio composition: 0.5 to 2.5 Na n (A); 1.2 to 3 Na 2 O; 4 to 7.5 SiO 2 ; Al 2 O 3 ; 40 to 200 H 2 O; wherein A is a mineral acid anion and n is the valence of A; and (e) heating the final reaction mixture of step (d) to a temperature of from about 80° to 150° C. for from about 2 to 40 hours to obtain type Y zeolite.
Claim 2
Dependent Claim
260 words
A process for preparing type Y zeolite comprising: (a) preparing a slurry of zeolitic nucleation centers having an average particle size below about 0.1 micron, said slurry having the following mol ratio composition: 12 to 19 Na 2 O; 0.7 to 9 Al 2 O 3 ; 12 to 19 SiO 2 ; 220 to 900 H 2 O; (b) preparing an intermediate reaction mixture by combining the nucleation center composition of step (a) with additional sources of Na 2 O, Al 2 O 3 , SiO 2 and H 2 O to obtain a mixture having the following mol ratio composition: 2 to 6 Na 2 O; 4.5 to 11 SiO 2 ; Al 2 O 3 ; 30 to 200 H 2 O; (c) agitating and heating said intermediate reaction mixture of step (b) at a temperature of from about 30° to 80° C.; (d) mixing an acid compound selected from the group comprising mineral acids, aluminum salts of mineral acids and mixtures thereof to the reaction mixture of step (c) to obtain a final reaction mixture having the following mol ratio composition: 0.5 to 2.5 Na n (A); 1.2 to 3 Na 2 O; 4 to 7.5 SiO 2 ; Al 2 O 3 ; 40 to 200 H 2 O; wherein A is a mineral acid anion and n is the valence of A; and (e) heating the final reaction mixture of step (d) to a temperature of from about 80° to 150° C. for from about 2 to 40 hours to obtain type Y zeolite.
Claim 3
Dependent Claim
35 words
The process of claim 1 wherein the intermediate reaction mixture of step (b) is obtained by combining the nucleation center composition of step (a) with sodium silicate, sodium aluminate, sodium hydroxide, water and mixtures thereof.
Claim 4
Dependent Claim
22 words
The process of claim 1 wherein said mineral acids are selected from the group comprising sulfuric, nitric, hydrochloric acids and mixtures thereof.
Claim 5
Dependent Claim
38 words
The process of claim 1 wherein the mols of SiO 2 in the reaction mixture resulting from step (e) less the number of mols of SiO 2 in said type Y zeolite range from about 0 to 3.
Claim 6
Dependent Claim
21 words
The process of claim 4 wherein said mols of SiO 2 in the reaction mixture range from about 0 to 11/2.
References Cited (Backward Citations)
US3433589A
Cited
US3574538A
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US3639099A
Cited
US3671191A
Cited
US3808326A
Cited
US3789107A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-12-10 | 1983-06-11 | 1983-12-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-12-10 | 1987-06-11 | 1987-12-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-12-10 | 1991-06-11 | 1991-12-11 | $7700.00 | Window Closed / Lapsed |