Patent US4443776A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4178282A Expired / Lapsed US ⏱️ 0.0 years remaining

Vinyl resin stabilizer

Assignee: Claremont Polychemical Corp
•
Filing: 1978-03-16
•
Granted: 1979-12-11
•
Expires: 1998-03-16
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract This invention comprises novel compositions of matter for use as stabilizers for polyvinyl chloride resins. These compositions comprise alkali metal soap and/or phenolate complexes or solutions (sodium and potassium preferred) and alkaline earth metal soap and/or phenolate complexes or solutions with soluble zinc chloride and hydroxy compounds (or other suitable solutions of zinc chloride) and organophosphites. These combinations of materials have not previously been described as useful for these purposes.

Inventors

  • 👤 Kook J. Bae

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 09:21
CPC Classifications
C; C08; C08K; C08K13/00; C08K13/02; C08K3/00; C08K3/16; C08K5/00; C08K5/04; C08K5/06; C08K5/09; C08K5/13; C08K5/49; C08K5/51; C08K5/52

Claims Analysis

Total Claims: 48
Claim 1
Independent Claim 84 words
A stabilizer composition especially adapted for use as a stabilizer for halogenated hydrocarbon resins which comprises at least one alkali metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, at least one alkaline earth metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, zinc chloride dissolved in an organic hydroxyl containing compound or an organic diphosphite, at least one organophosphite, and at least one inert organic solvent therefor.
Claim 2
Dependent Claim 84 words
A stabilizer composition especially adapted for use as a stabilizer for halogenated hydrocarbon resins which comprises at least one alkali metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, at least one alkaline earth metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, zinc chloride dissolved in an organic hydroxyl containing compound or an organic diphosphite, at least one organophosphite, and at least one inert organic solvent therefor.
Claim 3
Dependent Claim 16 words
The stabilizer composition of claim 1 in which the alkali metal salt is a potassium salt.
Claim 4
Dependent Claim 16 words
The stabilizer composition of claim 1, in which the alkali metal salt is a lithium salt.
Claim 5
Dependent Claim 16 words
The stabilizer composition of claim 1 in which the alkali metal salt is a sodium salt.
Claim 6
Dependent Claim 17 words
The stabilizer composition of claim 1 in which the alkaline earth metal salt is a strontium salt.
Claim 7
Dependent Claim 17 words
The stabilizer composition of claim 1 in which the alkaline earth metal salt is a calcium salt.
Claim 8
Dependent Claim 17 words
The stabilizer composition of claim 1 in which the alkaline earth metal salt is a magnesium salt.
Claim 9
Dependent Claim 16 words
The stabilizer composition of claim 1 in which the organic acidic compound is an aliphatic acid.
Claim 10
Dependent Claim 15 words
The stabilizer composition of claim 1 in which the organic acid compound is a phenol.
Claim 11
Dependent Claim 26 words
The stabilizer composition of claim 1 in which the organic acid compound is a mixture of at least one aliphatic acid and at least one phenol.
Claim 12
Dependent Claim 17 words
The stabilizer composition of claim 1 in which the zinc chloride is dissolved in an aliphatic alcohol.
Claim 13
Dependent Claim 17 words
The stabilizer composition of claim 1 in which the zinc chloride is dissolved in a dihydroxyl compound.
Claim 14
Dependent Claim 17 words
The stabilizer composition of claim 1 in which the zinc chloride is dissolved in an organic diphosphite.
Claim 15
Dependent Claim 17 words
The stabilizer composition of claim 1 in which the zinc chloride is dissolved in a glycol ether.
Claim 16
Dependent Claim 13 words
The stabilizer composition of claim 1 in which the organophosphite is a diphosphite.
Claim 17
Dependent Claim 13 words
The stabilizer composition of claim 1 in which the organophosphite is a triphosphite.
Claim 18
Dependent Claim 32 words
The stabilizer composition of claim 1 in which the alkaline earth metal salt is a strontium salt of an aliphatic acid, and the zinc chloride is dissolved in an aliphatic hydroxyl compound.
Claim 19
Dependent Claim 65 words
A stabilized vinyl chloride resin composition which has incorporated therein at least one alkali metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, at least one alkaline earth metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, zinc chloride, an organic hydroxyl containing compound and at least one organophosphite.
Claim 20
Dependent Claim 65 words
A stabilized vinyl chloride resin composition which has incorporated therein at least one alkali metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, at least one alkaline earth metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, zinc chloride, an organic hydroxyl containing compound and at least one organophosphite.
Claim 21
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which the vinyl chloride resin is a vinyl chloride homopolymer.
Claim 22
Dependent Claim 21 words
The stabilized vinyl chloride resin chloride resin of claim 18 in which the vinyl chloride resin is a vinyl chloride copolymer.
Claim 23
Dependent Claim 18 words
The stabilized vinyl chloride resin of claim 18 in which the alkali metal salt is a potassium salt.
Claim 24
Dependent Claim 18 words
The stabilized vinyl chloride resin of claim 18 in which the alkali metal salt is a lithium salt.
Claim 25
Dependent Claim 18 words
The stabilized vinyl chloride resin of claim 18 in which the alkali metal salt is a sodium salt.
Claim 26
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which the alkaline earth metal salt is a strontium salt.
Claim 27
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which the alkaline earth metal salt is a calcium salt.
Claim 28
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which the alkaline earth metal salt is a magnesium salt.
Claim 29
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which the aliphatic organic hydroxyl-containing compound is an aliphatic alcohol.
Claim 30
Dependent Claim 18 words
The stabilized vinyl chloride resin of claim 18 in which the aliphatic organic hydroxyl-containing compound is a diol.
Claim 31
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which the aliphatic organic hydroxyl-containing compound is a glycol ether.
Claim 32
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which at least one of the organophosphites is a diphosphite.
Claim 33
Dependent Claim 19 words
The stabilized vinyl chloride resin of claim 18 in which at least one of the organophosphites is a triphosphite.
Claim 34
Dependent Claim 88 words
A stabilizer composition for vinyl chloride resins which comprises a potassium salt of a carboxylic acid, a strontium salt of a phenol, zinc chloride dissolved in an organic hydroxyl-containing compound, at least one organophosphite and at least one inert, non-reactive-organic solvent therefor, the potassium to strontium ratio in the composition being from about 0.02 to about 0.2, the strontium to zinc chloride ratio in the composition being from about 2.0 to about 10.0, and the zinc chloride to hydroxyl-containing compound ratio being from about 0.06 to about 0.3.
Claim 35
Dependent Claim 88 words
A stabilizer composition for vinyl chloride resins which comprises a potassium salt of a carboxylic acid, a strontium salt of a phenol, zinc chloride dissolved in an organic hydroxyl-containing compound, at least one organophosphite and at least one inert, non-reactive-organic solvent therefor, the potassium to strontium ratio in the composition being from about 0.02 to about 0.2, the strontium to zinc chloride ratio in the composition being from about 2.0 to about 10.0, and the zinc chloride to hydroxyl-containing compound ratio being from about 0.06 to about 0.3.
Claim 36
Independent Claim 83 words
A method of light and heat stabilization for vinyl chloride resins which comprises incorporating therein a composition consisting essentially of at least one alkali metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, at least one alkaline earth metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, zinc chloride dissolved in an organic hydroxyl containing compound, at least one organophosphite, and at least one inert, non-reactive solvent.
Claim 37
Independent Claim 83 words
A method of light and heat stabilization for vinyl chloride resins which comprises incorporating therein a composition consisting essentially of at least one alkali metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, at least one alkaline earth metal salt of an organic acidic compound selected from the group consisting of carboxylic acids and phenols, zinc chloride dissolved in an organic hydroxyl containing compound, at least one organophosphite, and at least one inert, non-reactive solvent.
Claim 38
Dependent Claim 24 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the alkali metal salt is a potassium salt.
Claim 39
Dependent Claim 24 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the alkali metal salt is a sodium salt.
Claim 40
Dependent Claim 24 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the alkali metal salt is a lithium salt.
Claim 41
Dependent Claim 25 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the alkaline earth metal salt is a strontium salt.
Claim 42
Dependent Claim 25 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the alkaline earth metal salt is a calcium salt.
Claim 43
Dependent Claim 25 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the alkaline earth metal salt is a magnesium salt.
Claim 44
Dependent Claim 25 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the organic hydroxyl containing compound is an aliphatic alcohol.
Claim 45
Dependent Claim 24 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the organic hydroxyl containing compound is a diol.
Claim 46
Dependent Claim 25 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the organic hydroxyl containing compound is a glycol ether.
Claim 47
Dependent Claim 21 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the organophosphite is a diphosphite.
Claim 48
Dependent Claim 21 words
The method of light and heat stabilization for vinyl chloride resins of claim 33 in which the organophosphite is a triphosphite.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-10 1983-06-11 1983-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-10 1987-06-11 1987-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-10 1991-06-11 1991-12-11 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag