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US4178253A Expired / Lapsed US ⏱️ 0.0 years remaining

Corrosion inhibited lubricant compositions

Assignee: BASF Corp
•
Filing: 1978-04-03
•
Granted: 1979-12-11
•
Expires: 1998-04-03
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Abstract

Abstract A lubricating oil composition comprising 0.001% to 10%, based on the total lubricating composition, of a compound of formula I: ##STR1## wherein x is an integer from 1 to 25; R, R 1 and R" are the same or different and each is hydrogen, an optionally substituted straight- or branched-chain alkyl residue having from 1 to 20 carbon atoms, an alkenyl or alkynyl residue having from 2 to 12 carbon atoms, an optionally substituted cycloalkyl residue having from 3 to 12 carbon atoms, an optionally substituted aryl residue having from 6 to 10 carbon atoms, an optionally substituted aralkenyl or aralkynyl residue each having from 8 to 12 carbon atoms, an optionally substituted aralkyl residue having from 7 to 20 carbon atoms or an optionally substituted heterocyclic residue having from 3 to 10 ring members, an alkylene residue having from 2 to 12 carbon atoms, a cycloalkylene residue having from 5 to 12 carbon atoms or an arylene residue having from 6 to 10 carbon atoms; or R is the group -(S) x R" and when R and R' are different from R", R" can also be one of the following residues: (a) a residue of formula: ##STR2## wherein Z is the atom grouping necessary to complete, with the carbon atom, a heterocyclic ring, or (b) a quaternary ammonium cation derived from the reaction of a compound of formula I, wherein R" is hydrogen, with ammonia or an amine; and when R" is hydrogen, R or R' can also be an organic residue which links two triazole residues of formula I, wherein R' is in the 4-position.

Inventors

  • 👤 Peter I. Lee
  • 👤 Brian Holt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:32
CPC Classifications
C; C07; C07D; C07D249/00; C07D249/02; C07D249/08; C07D249/10; C07D249/12; C10; C10M; C10M135/00; C10M135/32; C10M2201/00; C10M2201/085; C10M2205/00; C10M2205/02; C10M2205/026; C10M2205/06; C10M2207/00; C10M2207/02; C10M2207/023; C10M2207/025; C10M2207/026; C10M2207/027; C10M2207/10; C10M2207/12; C10M2207/121; C10M2207/123; C10M2207/129; C10M2207/16; C10M2207/22; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/284; C10M2207/285; C10M2207/286; C10M2207/287; C10M2207/289; C10M2207/30; C10M2207/34; C10M2209/00; C10M2209/02; C10M2209/08; C10M2209/084; C10M2209/10; C10M2209/102; C10M2209/103; C10M2211/00; C10M2211/04; C10M2211/042; C10M2211/06; C10M2211/08; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/06; C10M2215/064; C10M2215/065; C10M2215/066; C10M2215/08; C10M2215/082; C10M2215/086; C10M2215/10; C10M2215/14; C10M2215/22; C10M2215/221; C10M2215/223; C10M2215/224; C10M2215/225; C10M2215/226; C10M2215/227; C10M2215/24; C10M2215/26; C10M2215/28; C10M2215/30; C10M2217/00; C10M2217/02; C10M2217/028; C10M2217/06; C10M2219/00; C10M2219/02; C10M2219/022; C10M2219/024; C10M2219/04; C10M2219/044; C10M2219/06; C10M2219/062; C10M2219/066; C10M2219/068; C10M2219/08; C10M2219/082; C10M2219/085; C10M2219/087; C10M2219/088; C10M2219/089; C10M2219/09; C10M2219/10; C10M2219/102; C10M2219/104; C10M2219/106; C10M2219/108; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10M2223/042; C10M2223/045; C10M2223/047; C10M2223/06; C10M2223/065; C10M2223/12; C10M2225/00; C10M2225/04; C10M2227/00; C10M2227/02; C10M2229/00; C10M2229/02; C10M2229/04; C10M2229/05; C10N; C10N2010/00; C10N2010/02; C10N2010/04; C10N2010/08; C10N2010/10

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 299 words
A lubricant composition comprising a major proportion of an oil of lubricating viscosity and from 0.001 to 10% by weight, based on the total composition, of a compound of the formula ##STR7## wherein X is an integer from 1 to 25; R, R' and R" are the same or different and each is hydrogen, a straight- or branched-chain alkyl having 1 to 20 carbon atoms; or said alkyl substituted by one or more halogen atoms or alkoxy groups having 1 to 12 carbon atoms; a straight- or branched-chain alkenyl having 2 to 12 carbon atoms; a straight- or branched-chain alkynyl having 2 to 12 carbon atoms; cycloalkyl having 3 to 12 carbon atoms; aryl having 6 to 10 carbon atoms; aralkenyl having 8 to 12 carbon atoms; aralkynyl having 8 to 12 carbon atoms; aralkyl having 7 to 20 carbon atoms; piperidyl, pyridyl; furyl; or said cycloalkyl, aryl, aralkenyl, aralkynyl, aralkyl, piperidyl, pyridyl or furyl substituted by one or more straight or branched alkyl having from 1 to 12 carbon atoms which alkyl groups may be substituted by halogen atoms, by alkoxy having 1 to 12 carbon atoms, by alkylthio having 1 to 18 carbon atoms, by alkylamino having 1 to 24 carbon atoms, by dialkylamino having 1 to 24 carbon atoms, by hydroxy, by cyano or by mixtures of said substituents; or R is the group--(S) x R"; or when R and R' are different from R", (a) R" can be ##STR8## (b) R" is the ammonium cation or a quaternary ammonium cation having 2 to 22 carbon atoms; R 2 is ##STR9## R 3 is ##STR10## or R 2 and R 4 are alkylene having 1 to 12 carbon atoms; cycloalkylene having 5 to 12 carbon atoms, arylene having 6 to 10 carbon atoms, furandiyl or thiophenediyl.
Claim 2
Dependent Claim 299 words
A lubricant composition comprising a major proportion of an oil of lubricating viscosity and from 0.001 to 10% by weight, based on the total composition, of a compound of the formula ##STR7## wherein X is an integer from 1 to 25; R, R' and R" are the same or different and each is hydrogen, a straight- or branched-chain alkyl having 1 to 20 carbon atoms; or said alkyl substituted by one or more halogen atoms or alkoxy groups having 1 to 12 carbon atoms; a straight- or branched-chain alkenyl having 2 to 12 carbon atoms; a straight- or branched-chain alkynyl having 2 to 12 carbon atoms; cycloalkyl having 3 to 12 carbon atoms; aryl having 6 to 10 carbon atoms; aralkenyl having 8 to 12 carbon atoms; aralkynyl having 8 to 12 carbon atoms; aralkyl having 7 to 20 carbon atoms; piperidyl, pyridyl; furyl; or said cycloalkyl, aryl, aralkenyl, aralkynyl, aralkyl, piperidyl, pyridyl or furyl substituted by one or more straight or branched alkyl having from 1 to 12 carbon atoms which alkyl groups may be substituted by halogen atoms, by alkoxy having 1 to 12 carbon atoms, by alkylthio having 1 to 18 carbon atoms, by alkylamino having 1 to 24 carbon atoms, by dialkylamino having 1 to 24 carbon atoms, by hydroxy, by cyano or by mixtures of said substituents; or R is the group--(S) x R"; or when R and R' are different from R", (a) R" can be ##STR8## (b) R" is the ammonium cation or a quaternary ammonium cation having 2 to 22 carbon atoms; R 2 is ##STR9## R 3 is ##STR10## or R 2 and R 4 are alkylene having 1 to 12 carbon atoms; cycloalkylene having 5 to 12 carbon atoms, arylene having 6 to 10 carbon atoms, furandiyl or thiophenediyl.
Claim 3
Dependent Claim 30 words
A composition as claimed in claim 1 wherein the amount of compound I, Ia, Ib or Ic is from 0.01% to 5% by weight, based on the total lubricant composition.
Claim 4
Dependent Claim 18 words
A composition as claimed in claim 1 wherein R is a group--(S) x R" and x is 1.
Claim 5
Dependent Claim 16 words
A composition as claimed in claim 1 wherein the lubricating oil component is a mineral oil.
Claim 6
Dependent Claim 273 words
A compound having the formula ##STR11## wherein x is an integer from 2 to 25; R, R' and R" are the same or different and each is hydrogen, a straight- or branched-chain alkyl having 1 to 20 carbon atoms; or said alkyl substituted by one or more halogen atoms or alkoxy groups having 1 to 12 carbon atoms; a straight- or branched-chain alkenyl having 2 to 12 carbon atoms; a straight- or branched-chain alkynyl having 2 to 12 carbon atoms; cycloalkyl having 3 to 12 carbon atoms; aryl having 6 to 10 carbon atoms; aralkenyl having 6 to 12 carbon atoms; aralkynyl having 8 to 12 carbon atoms; aralkyl having 7 to 20 carbon atoms; piperidyl, pyridyl; furyl; or said cycloalkyl, aryl, aralkenyl, aralkynyl, aralkyl, piperidyl, pyridyl or furyl substituted by one or more straight or branched alkyl having from 1 to 12 carbon atoms which alkyl groups may be substituted by halogen atoms, by alkoxy having 1 to 12 carbon atoms, by alkylthio having 1 to 18 carbon atoms, by alkylamino having 1 to 24 carbon atoms, by dialkylamino having 1 to 24 carbon atoms, by hydroxy, by cyano or by mixtures of said substituents; or R is the group--(S) x R"; or when R and R' are different from R", (a) R" can be ##STR12## (b) R" is the ammonium cation or a quaternary ammonium cation having 2 to 22 carbon atoms; R 2 is ##STR13## R 3 is ##STR14## or R 2 and R 4 are alkylene having 1 to 12 carbon atoms; cycloalkylene having 5 to 12 carbon atoms, arylene having 6 to 10 carbon atoms, furandiyl or thiophenediyl.
Claim 7
Dependent Claim 273 words
A compound having the formula ##STR11## wherein x is an integer from 2 to 25; R, R' and R" are the same or different and each is hydrogen, a straight- or branched-chain alkyl having 1 to 20 carbon atoms; or said alkyl substituted by one or more halogen atoms or alkoxy groups having 1 to 12 carbon atoms; a straight- or branched-chain alkenyl having 2 to 12 carbon atoms; a straight- or branched-chain alkynyl having 2 to 12 carbon atoms; cycloalkyl having 3 to 12 carbon atoms; aryl having 6 to 10 carbon atoms; aralkenyl having 6 to 12 carbon atoms; aralkynyl having 8 to 12 carbon atoms; aralkyl having 7 to 20 carbon atoms; piperidyl, pyridyl; furyl; or said cycloalkyl, aryl, aralkenyl, aralkynyl, aralkyl, piperidyl, pyridyl or furyl substituted by one or more straight or branched alkyl having from 1 to 12 carbon atoms which alkyl groups may be substituted by halogen atoms, by alkoxy having 1 to 12 carbon atoms, by alkylthio having 1 to 18 carbon atoms, by alkylamino having 1 to 24 carbon atoms, by dialkylamino having 1 to 24 carbon atoms, by hydroxy, by cyano or by mixtures of said substituents; or R is the group--(S) x R"; or when R and R' are different from R", (a) R" can be ##STR12## (b) R" is the ammonium cation or a quaternary ammonium cation having 2 to 22 carbon atoms; R 2 is ##STR13## R 3 is ##STR14## or R 2 and R 4 are alkylene having 1 to 12 carbon atoms; cycloalkylene having 5 to 12 carbon atoms, arylene having 6 to 10 carbon atoms, furandiyl or thiophenediyl.
Claim 8
Dependent Claim 18 words
A compound as claimed in claim 5 wherein R is a group--(S) x R" and x is 1.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-10 1983-06-11 1983-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-10 1987-06-11 1987-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-10 1991-06-11 1991-12-11 $7700.00 Window Closed / Lapsed

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