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US4178203A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of increasing the strength of wet glass fiber mats made by the wet-laid process

Assignee: Building Materials Corp of America
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Filing: 1978-01-24
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Granted: 1979-12-11
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Expires: 1998-01-24
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Abstract

Abstract In accordance with the present invention, there is provided herein a method of increasing the strength of wet glass fiber mats prepared by the wet-laid process. The wet-strength of such freshly prepared glass fiber mats are improved in this invention by treating the wet mat with a dilute solution of an anionic surfactant. As a feature of the invention, the wet-strength of such mats are increased substantially so that they may be conveniently handled and transferred, even manually, for further processing, e.g. for applying binders and drying, into the finished glass fiber mat product.

Inventors

  • 👤 Paritosh M. Chakrabarti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:37
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/03; C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/25

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 222 words
In the manufacture of glass fiber mat products by the wet-laid process at a high rate of production wherein an aqueous dispersion of glass fibers which contains a surfactant dispersant is formed from bundles of glass fibers of about 1/4 to 3 inches in length and tertiary amine oxide or cationic quaternary ammonium dispersant compound at a concentration of about 5-500 ppm and at a fiber consistency of about 0.001 to 3%, which dispersion is passed through a matforming screen to form a freshly-prepared wet-mat of said fibers, the improvement which comprises: applying to said freshly-prepared wet-mat an anionic surfactant selected from the group consisting of (1) an anionic surfactant having at least (a) a hydrophobic segment containing from 8 to 30 carbon atoms selected from the groups consisting of alkyl, aryl, alkylaryl, substituted alkyl, and substituted alkenyl groups, said groups being straight or branched chain, saturated or unsaturated, and (b) an anionic segment selected from the groups consisting of carboxy, sulfate ester, phosphate ester, sulfonic acid and phosphonic acid, or (2) a soap selected from sodium, potassium, ammonium and alkylolammonium salts of higher C 10 -C 20 fatty acids, thereby to improve the wet-strength properties of said freshly-prepared wet-mat so that it can be readily handled and transferred during other steps in said process, into a finished glass fiber mat product.
Claim 2
Dependent Claim 222 words
In the manufacture of glass fiber mat products by the wet-laid process at a high rate of production wherein an aqueous dispersion of glass fibers which contains a surfactant dispersant is formed from bundles of glass fibers of about 1/4 to 3 inches in length and tertiary amine oxide or cationic quaternary ammonium dispersant compound at a concentration of about 5-500 ppm and at a fiber consistency of about 0.001 to 3%, which dispersion is passed through a matforming screen to form a freshly-prepared wet-mat of said fibers, the improvement which comprises: applying to said freshly-prepared wet-mat an anionic surfactant selected from the group consisting of (1) an anionic surfactant having at least (a) a hydrophobic segment containing from 8 to 30 carbon atoms selected from the groups consisting of alkyl, aryl, alkylaryl, substituted alkyl, and substituted alkenyl groups, said groups being straight or branched chain, saturated or unsaturated, and (b) an anionic segment selected from the groups consisting of carboxy, sulfate ester, phosphate ester, sulfonic acid and phosphonic acid, or (2) a soap selected from sodium, potassium, ammonium and alkylolammonium salts of higher C 10 -C 20 fatty acids, thereby to improve the wet-strength properties of said freshly-prepared wet-mat so that it can be readily handled and transferred during other steps in said process, into a finished glass fiber mat product.
Claim 3
Dependent Claim 12 words
The process according to claim 1 wherein said soap is sodium oleate.
Claim 4
Dependent Claim 40 words
A method according to claim 1 wherein the substitutent of the substituted groups of the hydrophobic segment of the anionic surfactant (a) is selected from the group consisting of hydroxy, alkoxy, acyoxy, carboxy lower alkyl, thio, alkylthio, acylamido and halogen.
Claim 5
Dependent Claim 35 words
A method according to claim 1 wherein the anionic segment of the anionic surfactant (a) further has a polyalkyleneoxy chain and wherein the number of alkyleneoxy units of said polyalkyleneoxy chain does not exceed 10.
Claim 6
Dependent Claim 12 words
The process according to claim 4 wherein said alkyleneoxy unit is ethyleneoxy.
Claim 7
Dependent Claim 41 words
The process according to claim 1 wherein said anionic surfactant (1) is selected from the group consisting of alkyl aryl sulfonates, sulfonated naphthalene formaldehyde condensates, alkane sulfonates, lauryl ether sulfates, alkyl phenoxypolyethyleneoxy ethyl sulfates, dialkyl esters of sulfosuccinates, and N-alkyl-N-acyl taurates.
Claim 8
Dependent Claim 88 words
The process according to claim 1 wherein said dispersion is formed by mixing said bundles of fibers in an aqueous medium with a tertiary amine oxide surfactant having the formula: ##STR2## where R 1 , R 2 and R 3 are selected from the group consisting of aliphatic and aromatic hydrocarbon radicals, substituted or unsubstituted, containing between 1 and 30 carbon atoms, being the same or different, the sum of the carbon atoms of R 1 , R 2 and R 3 being between about 14 to 40.
Claim 9
Dependent Claim 20 words
A method according to claim 7 wherein the R 1 , R 2 and R 3 radicals are aliphatic radicals.
Claim 10
Dependent Claim 15 words
A method according to claim 8 wherein said aliphatic radicals are selected from alkyl, hydroxyalkyl.
Claim 11
Dependent Claim 14 words
A method according to claim 7 wherein said sum is about 18 to 24.
Claim 12
Dependent Claim 39 words
A method according to claim 7 wherein at least one of said aliphatic radicals is lower alkyl or hydroxy lower alkyl, and at least other one of said aliphatic radicals is a long chain alkyl or alkyl substituted group.
Claim 13
Dependent Claim 31 words
A method according to claim 7 wherein said amine oxide is selected from the group consisting of dimethyl hydrogenated tallow amine oxide, dimethylstearylamine oxide, diemethylhexadecylamine oxide and bis(2-hydroxyethyl) tallow amine oxide.
Claim 14
Dependent Claim 29 words
A method according to claim 7 which further comprises: precoating said glass fibers with said amine oxide, having the formula of claim 7 prior to forming said aqueous dispersion.

References Cited (Backward Citations)

CA685665A Cited
CA787649A Cited
US2721139A Cited
US3228825A Cited
US3766003A Cited
US4007083A Cited
BE838373A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-10 1983-06-11 1983-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-10 1987-06-11 1987-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-10 1991-06-11 1991-12-11 $7700.00 Window Closed / Lapsed

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