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US4178184A Expired / Lapsed US ⏱️ 0.0 years remaining

Color photographic materials containing dye-fading inhibitors

Assignee: Konica Minolta Inc
•
Filing: 1977-10-18
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Granted: 1979-12-11
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Expires: 1997-10-18
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Abstract

Abstract The present invention is directed to a color photographic material which is characterized as containing a compound represented by the following formula I in combination with a compound represented by the following formula II ##STR1## wherein R represents an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group or a heterocyclic ring; R 1 , R 2 and R 3 individually represent hydrogen, halogen, an alkyl group, an alkylthio group, an alkoxy group, an aryl group, an aryloxy group, an arylthio group, an acyl group, an acylamino group, a diacylamino group, an acyloxy group, a sulfonamido group, an alkylamino group, a cycloalkyl group or an alkoxycarbonyl group; and Z represents an atomic group or groups necessary for forming a chroman or coumaran ring; provided that R and R 1 can cooperatively be cyclized to form a chroman or cumaran ring. ##STR2## wherein A 1 , A 2 , A 3 and A 4 are individually alkyl having 1-18 carbon atoms, the total number of carbon atoms of A 1 , A 2 , A 3 and A 4 being not more than 32; and X is a simple bond, oxygen, sulfur, sulfonyl or ##STR3## in which A 5 is hydrogen or alkyl having 1-10 carbon atoms and n is an integer of 1-3.

Inventors

  • 👤 Masahiko Taguchi
  • 👤 Katsuo Mogaki
  • 👤 Syun Takada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 00:09
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/392; G03C7/39296

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 217 words
A color photosensitive material comprising a support and a silver halide photosensitive layer, said material containing a first compound represented by formulas (Ia), (Ib), or (c) in combination with a second compound represented by formula (II) ##STR17## ##STR18## ##STR19## wherein R, R' and R' 1 , individually represent an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, or a heterocyclic ring; and R 4 , R 5 , R 6 , R 7 , R 8 and R 9 individually represent hydrogen, an alkyl group, an alkoxy group, an alkylthio group, an alkenyl group, an alkenyloxy group, an aryl group, an aryloxy group, an amino group or a heterocyclic group selected from piperadine, morpholine, imidazoline, thiazoline, pyridine, pyrimidine, and triazine; provided that R 8 and R 9 can cooperatively be cyclized to form a cyclohexane ring which may be substituted with alkyl; ##STR20## wherein A 1 , A 2 , A 3 and A 4 are individually alkyl having 1-18 carbon atoms, the total number of carbon atoms of A 1 , A 2 , A 3 and A 4 being not more than 32; and X is a simple bond, oxygen, sulfur, or ##STR21## in which A 5 is hydrogen or alkyl having 1-10 carbon atoms and n is an integer of 1-3.
Claim 2
Dependent Claim 217 words
A color photosensitive material comprising a support and a silver halide photosensitive layer, said material containing a first compound represented by formulas (Ia), (Ib), or (c) in combination with a second compound represented by formula (II) ##STR17## ##STR18## ##STR19## wherein R, R' and R' 1 , individually represent an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, or a heterocyclic ring; and R 4 , R 5 , R 6 , R 7 , R 8 and R 9 individually represent hydrogen, an alkyl group, an alkoxy group, an alkylthio group, an alkenyl group, an alkenyloxy group, an aryl group, an aryloxy group, an amino group or a heterocyclic group selected from piperadine, morpholine, imidazoline, thiazoline, pyridine, pyrimidine, and triazine; provided that R 8 and R 9 can cooperatively be cyclized to form a cyclohexane ring which may be substituted with alkyl; ##STR20## wherein A 1 , A 2 , A 3 and A 4 are individually alkyl having 1-18 carbon atoms, the total number of carbon atoms of A 1 , A 2 , A 3 and A 4 being not more than 32; and X is a simple bond, oxygen, sulfur, or ##STR21## in which A 5 is hydrogen or alkyl having 1-10 carbon atoms and n is an integer of 1-3.
Claim 3
Dependent Claim 238 words
A color photosensitive material comprising a support, a cyan coupler containing silver halide photosensitive emulsion layer, a magenta coupler containing silver halide photosensitive emulsion layer, and a yellow coupler containing silver halide photosensitive emulsion layer, said material containing a first compound represented by formulas (Ia), (Ib), or (Ic) in combination with a second compound represented by formula (II) ##STR22## ##STR23## ##STR24## wherein R, R', and R' 1 individually represent an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, or a heterocyclic ring; and R 4 , R 5 , R 6 , R 7 , R 8 and R 9 individually represent hydrogen, an alkyl group, an alkoxy group, an alkylthio group, an alkenyl group, an alkenyloxy group, an aryl group, an aryloxy group, an amino group or a heterocyclic group selected from piperadine, morpholine, imidazoline, thiazoline, pyridine, pyrimidine, and triazine; provided that R 8 and R 9 can cooperatively be cyclized to form a cyclohexane ring which may be substituted with alkyl; ##STR25## wherein A 1 , A 2 , A 3 and A 4 are individually alkyl having 1-18 carbon atoms, the total number of carbon atoms of A 1 , A 2 , A 3 and A 4 being not more than 32; and X is a simple bond, oxygen, sulfur, or ##STR26## in which A 5 is hydrogen or alkyl having 1-10 carbon atoms and n is an integer of 1-3.
Claim 4
Dependent Claim 238 words
A color photosensitive material comprising a support, a cyan coupler containing silver halide photosensitive emulsion layer, a magenta coupler containing silver halide photosensitive emulsion layer, and a yellow coupler containing silver halide photosensitive emulsion layer, said material containing a first compound represented by formulas (Ia), (Ib), or (Ic) in combination with a second compound represented by formula (II) ##STR22## ##STR23## ##STR24## wherein R, R', and R' 1 individually represent an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, or a heterocyclic ring; and R 4 , R 5 , R 6 , R 7 , R 8 and R 9 individually represent hydrogen, an alkyl group, an alkoxy group, an alkylthio group, an alkenyl group, an alkenyloxy group, an aryl group, an aryloxy group, an amino group or a heterocyclic group selected from piperadine, morpholine, imidazoline, thiazoline, pyridine, pyrimidine, and triazine; provided that R 8 and R 9 can cooperatively be cyclized to form a cyclohexane ring which may be substituted with alkyl; ##STR25## wherein A 1 , A 2 , A 3 and A 4 are individually alkyl having 1-18 carbon atoms, the total number of carbon atoms of A 1 , A 2 , A 3 and A 4 being not more than 32; and X is a simple bond, oxygen, sulfur, or ##STR26## in which A 5 is hydrogen or alkyl having 1-10 carbon atoms and n is an integer of 1-3.
Claim 5
Dependent Claim 23 words
The color photosensitive material according to claim 1 wherein said first compound is selected from the compounds represented by formulas (Ib) and (Ic).
Claim 6
Dependent Claim 27 words
The color photosensitive material according to claim 2 wherein at least one of the three emulsion layers contains said first compound in combination with said second compound.
Claim 7
Dependent Claim 28 words
The color photosensitive material according to claim 4 wherein the magenta coupler containing silver halide photosensitive emulsion layer contains said first compound in combination with said second compound.
Claim 8
Dependent Claim 21 words
The color photosensitive material according to claim 3 wherein R in formula (Ib) is an alkyl group having 8-32 carbon atoms.
Claim 9
Dependent Claim 21 words
The color photosensitive material according to claim 6 wherein R in formula (Ib) is an alkyl group having 12-32 carbon atoms.
Claim 10
Dependent Claim 94 words
The color photosensitive material according to claim 2 wherein the compound of formula (II) is represented by the following formula: ##STR27## ##STR28## wherein A 1 , A 2 , A 3 and A 4 are individually alkyl having 1-18 carbon atoms, the total number of carbon atoms of A 1 , A 2 , A 3 and A 4 being not more than 32, and X is a simple bond, oxygen, sulfur, sulfonyl or ##STR29## in which A 5 is hydrogen or alkyl having 1-10 carbon atoms and n is an integer of 1-3.
Claim 11
Dependent Claim 22 words
The color photosensitive material of claim 8 wherein at least one of A 1 and A 2 is a tertiary alkyl group.

References Cited (Backward Citations)

US2735765A Cited
US3432300A Cited
US3700455A Cited
US3764337A Cited
US3930866A Cited
US4015990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-10 1983-06-11 1983-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-10 1987-06-11 1987-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-10 1991-06-11 1991-12-11 $7700.00 Window Closed / Lapsed

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