Thiazolyl coupler compositions and photographic elements suited to forming integral sound tracks

Claim 2

In a silver halide photographic element comprising a support and, coated thereon, at least one layer unit which comprises a photographic silver halide emulsion layer and coupler solvent particles dispersed in a photographically useful amount in said emulsion layer or in an adjacent hydrophilic colloid layer, the improvement wherein said coupler solvent particles are comprised of a combination, capable of permitting the formation of a microcrystalline dye, of a coupler of the formula ##STR7## wherein R is a coupling-off group and Ballast is a hydrophobic photographic ballasting group and a coupler solvent chosen from the group consisting of ##STR8## wherein R 4 is alkyl of from 1 to 6 carbon atoms; said coupler and said coupler solvent being present in a weight ratio of from 5:1 to 1:2.

Claim 3

An improved photographic element according to claim 1 wherein said Ballast is an alkyl group of from 8 to 30 carbon atoms.

Claim 4

An improved photographic element according to claim 1 wherein said polar group R 2 is a hydroxy group or a carboxylic acid, salt or ester group.

Claim 5

An improved photographic element according to claim 1 wherein said coupler and said coupler solvent are present in a weight ratio of from 4:1 to 1:1.

Claim 6

An improved photographic element according to claim 1 wherein said silver halide emulsion layer is sensitized to the infrared portion of the spectrum.

Claim 7

An improved photographic element according to claim 1 wherein said silver halide emulsion layer is sensitized in the region of the spectrum from 470 to 500 nm.

Claim 8

An improved photographic element according to claim 1 wherein said element includes at least three layer units, one spectrally responsive to the blue region of the spectrum and containing a yellow dye-forming coupler, one spectrally responsive to the green region of the spectrum and containing a magenta dye-forming coupler and one spectrally responsive to the red region of the spectrum and containing a cyan dye-forming coupler.

Claim 9

An improved photographic element according to claim 1 wherein said coupler is present in a concentration sufficient to yield a dye density of at least 1 in the 800 nm region of the spectrum.

Claim 10

An improved photographic element according to claim 2 wherein said coupler is present in a concentration of from 0.40 to 1.30 grams per square meter.

Claim 11

A photographic element adapted to form a multicolor photographic image and an integral infrared absorbing dye sound track capable of producing a maximum density in excess of 1 throughout the spectral region of from 750 to 850 nm comprising a transparent film support, a first layer unit coated on said film support comprising a gelatino-silver halide emulsion layer having a peak sensitivity to a portion of the spectrum within the blue region at a wavelength shorter than 470 nm and containing a yellow dye-forming coupler, a second layer unit coated over said first layer unit comprising a gelatino-silver halide emulsion layer having a peak sensitivity to the red portion of the spectrum and containing a cyan dye-forming coupler, a third layer unit coated over said second layer unit comprising a gelatino-silver halide emulsion layer having a peak sensitivity to the green portion of the spectrum and containing a magenta dye-forming coupler, and a fourth layer unit coated over said third layer unit comprising a gelatino-silver halide emulsion layer having a peak sensitivity within the 470 to 500 nm region of the spectrum and containing coupler solvent particles comprised of a combination, capable of permitting the formation of a microcrystalline dye, of an infrared absorbing dye-forming coupler in a concentration of from 0.65 to 1.05 grams per square meter of the formula ##STR9## wherein Ballast is a straight-chain alkyl group of from 10 to 20 carbon atoms and a coupler solvent chosen from the group consisting of ##STR10## wherein R 4 is alkyl of from 1 to 6 carbon atoms, said coupler and said coupler solvent being present in said particles in a ratio of from 4:1 to 1:1.

Claim 12

A photographic element adapted to form a multicolor photographic image and an integral infrared absorbing dye sound track capable of producing a maximum density in excess of 1 throughout the spectral region of from 750 to 850 nm comprising a transparent film support, a first layer unit coated on said film support comprising a gelatino-silver halide emulsion layer having a peak sensitivity to a portion of the spectrum within the blue region at a wavelength shorter than 470 nm and containing a yellow dye-forming coupler, a second layer unit coated over said first layer unit comprising a gelatino-silver halide emulsion layer having a peak sensitivity to the red portion of the spectrum and containing a cyan dye-forming coupler, a third layer unit coated over said second layer unit comprising a gelatino-silver halide emulsion layer having a peak sensitivity to the green portion of the spectrum and containing a magenta dye-forming coupler, and a fourth layer unit coated over said third layer unit comprising a gelatino-silver halide emulsion layer having a peak sensitivity within the 470 to 500 nm region of the spectrum and containing coupler solvent particles comprised of a combination, capable of permitting the formation of a microcrystalline dye, of an infrared absorbing dye-forming coupler in a concentration of from 0.65 to 1.05 grams per square meter of the formula ##STR9## wherein Ballast is a straight-chain alkyl group of from 10 to 20 carbon atoms and a coupler solvent chosen from the group consisting of ##STR10## wherein R 4 is alkyl of from 1 to 6 carbon atoms, said coupler and said coupler solvent being present in said particles in a ratio of from 4:1 to 1:1.

Claim 13

A photographic element according to claim 10 wherein Ballast is a straight chain alkyl group from 12 to 16 carbon atoms, R 4 is butyl or amyl and the ratio of said infrared absorbing dye-forming coupler to said coupler solvent is from 2.5:1 to 1.5:1.

Claim 14

A composition which can be coated to form a layer of a photographic element comprising a hydrophilic colloid and coupler solvent particles dispersed therein in a photographically useful amount comprised of a combination, capable of permitting the formation of a microcrystalline dye, of a coupler of the formula ##STR11## wherein R is a coupling-off group and Ballast is a hydrophobic photographic ballasting group and a coupler solvent is chosen from the group consisting of ##STR12## wherein R 4 is an alkyl group of from 1 to 6 carbon atoms; and said coupler and said solvent being present in a weight ratio of from 5:1 to 1:2.

Claim 15

A composition which can be coated to form a layer of a photographic element comprising a hydrophilic colloid and coupler solvent particles dispersed therein in a photographically useful amount comprised of a combination, capable of permitting the formation of a microcrystalline dye, of a coupler of the formula ##STR11## wherein R is a coupling-off group and Ballast is a hydrophobic photographic ballasting group and a coupler solvent is chosen from the group consisting of ##STR12## wherein R 4 is an alkyl group of from 1 to 6 carbon atoms; and said coupler and said solvent being present in a weight ratio of from 5:1 to 1:2.

Claim 16

A gelatino-silver halide emulsion which can be coated to form a layer of a photographic element comprising coupler solvent particles dispersed therein in a photographically useful amount comprised of a combination, capable of permitting the formation of a microcrystalline dye, of a coupler of the formula ##STR13## wherein Ballast is a straight-chain alkyl group of from 10 to 20 carbon atoms and a coupler solvent is chosen from the group consisting of ##STR14## wherein R 4 is an alkyl group of from 1 to 6 carbon atoms; said coupler and said coupler solvent is present in a weight ratio of from 4:1 to 1:1.

Claim 17

A gelatino-silver halide emulsion which can be coated to form a layer of a photographic element comprising coupler solvent particles dispersed therein in a photographically useful amount comprised of a combination, capable of permitting the formation of a microcrystalline dye, of a coupler of the formula ##STR13## wherein Ballast is a straight-chain alkyl group of from 10 to 20 carbon atoms and a coupler solvent is chosen from the group consisting of ##STR14## wherein R 4 is an alkyl group of from 1 to 6 carbon atoms; said coupler and said coupler solvent is present in a weight ratio of from 4:1 to 1:1.

Claim 18

An improved silver halide emulsion according to claim 13 wherein said emulsion is spectrally sensitized to the infrared region of the spectrum.

Claim 19

An improved silver halide emulsion according to claim 13 wherein said emulsion is spectrally sensitized to have a peak sensitivity within the 470 to 500 nm region of the spectrum.

Claim 20

An improved silver halide emulsion according to claim 13 wherein Ballast is a straight-chain alkyl group of from 12 to 16 carbon atoms.

Claim 21

In a gelatino-silver halide emulsion which can be coated to form a layer of a photographic element comprising coupler solvent particles dispersed therein in a photographically useful amount comprised of a coupler and a coupler solvent, the improvement wherein said coupler is 1-hydroxy-N-(2-phenyl-3-tetradecylthiazolyl)-2-naphthamide; said coupler solvent is chosen from the group consisting of dibutyl phthalate and 2,4-diamylphenol; and said coupler and said coupler solvent are present in a weight ratio of from 2.5:1 to 1.5:1.

Claim 22

In a gelatino-silver halide emulsion which can be coated to form a layer of a photographic element comprising coupler solvent particles dispersed therein in a photographically useful amount comprised of a coupler and a coupler solvent, the improvement wherein said coupler is 1-hydroxy-N-(2-phenyl-3-tetradecylthiazolyl)-2-naphthamide; said coupler solvent is chosen from the group consisting of dibutyl phthalate and 2,4-diamylphenol; and said coupler and said coupler solvent are present in a weight ratio of from 2.5:1 to 1.5:1.

Claim 23

An improved photographic element according to claim 1 wherein said coupling-off group is chosen from the class consisting of hydrogen and alkoxy, aryloxy, arylazo, thioether, oxazolyl, diazolyl, triazolyl and tetrazolyl coupling-off groups.

Claim 24

A composition according to claim 12 wherein said coupling-off group is chosen from the class consisting of hydrogen and alkoxy, aryloxy, arylazo, thioether, oxazolyl, diazolyl, triazolyl and tetrazolyl coupling-off groups.