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US4177319A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass for the production of optical elements with refractive index gradients

Assignee: Schott AG
•
Filing: 1978-11-07
•
Granted: 1979-12-04
•
Expires: 1998-11-07
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Abstract

Abstract An optical quality glass composition suitable for the production of optical elements with a refractive index gradient delta n of at least 100×10 -4 by utilizing an ion exchange, consisting essentially of the following synthesis composition, in % by weight: ______________________________________ SiO 2 56-78 MgO 6-15 Li 2 O 5-14 Na 2 O 3-14 K 2 O 0- 9 ______________________________________ wherein the total of MgO plus Li 2 O is 12-23.

Inventors

  • 👤 Walter Jahn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:11
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/04; C03C3/076; C03C3/083; C03C3/085; C03C3/087; C03C21/00; C03C21/001; C03C21/002; C03C3/078; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10T; Y10T428/00; Y10T428/31; Y10T428/315

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 67 words
An optical quality glass composition suitable for the production of optical elements with a refractive index gradient delta n of at least 100×10 -4 by utilizing an ion exchange, consisting essentially of the following synthesis composition, in % by weight: ______________________________________ SiO.sub.2 56-78 MgO 6-15 Li.sub.2 O 5-14 Na.sub.2 O 3-14 K.sub.2 O 0- 9 ______________________________________ wherein the total of MgO plus Li 2 O is 12-23.
Claim 2
Dependent Claim 67 words
An optical quality glass composition suitable for the production of optical elements with a refractive index gradient delta n of at least 100×10 -4 by utilizing an ion exchange, consisting essentially of the following synthesis composition, in % by weight: ______________________________________ SiO.sub.2 56-78 MgO 6-15 Li.sub.2 O 5-14 Na.sub.2 O 3-14 K.sub.2 O 0- 9 ______________________________________ wherein the total of MgO plus Li 2 O is 12-23.
Claim 3
Dependent Claim 62 words
A glass composition according to claim 1, suitable for the production of a particularly high refractive index gradient delta n of at least 200×10 -4 , consisting essentially of the following composition, in % by weight: ______________________________________ SiO.sub.2 65-75 MgO 9-13 Li.sub.2 O 8-12 Na.sub.2 O 4-10 K.sub.2 O 0-8 ______________________________________ wherein the total of MgO plus Li 2 O is 16-22.
Claim 4
Dependent Claim 25 words
A glass composition according to claim 1, wherein up to 18% by weight of SiO 2 has been replaced by Al 2 O 3 .
Claim 5
Dependent Claim 25 words
A glass composition according to claim 2, wherein up to 18% by weight of SiO 2 has been replaced by Al 2 O 3 .
Claim 6
Dependent Claim 62 words
A glass composition according to any one of claim 1, 2, 3, or 4 which further contains a stabilizing amount of about 1-6% by weight of at least one of the following oxides is a stabilizing additive: ______________________________________ B.sub.2 O.sub.3 0-5 PbO 0-5 CaO 0-6 SrO 0-6 BaO 0-6 La.sub.2 O.sub.3 0-3 ZrO.sub.2 0-3 Ta.sub.2 O.sub.5 0-2 WO.sub.3 0-2 TiO.sub.2 0-2 ______________________________________
Claim 7
Dependent Claim 45 words
An optical glass having a refractive index gradient of at least 100×10 -4 produced by the ion exchange of a composition according to claim 1 with a molten inorganic sodium salt for a time and at a temperature sufficient to achieve said refractive index gradient.

References Cited (Backward Citations)

US3959000A Cited
US3790430A Cited
US3464806A Cited
US3464880A Cited
US3428513A Cited
US3357876A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-03 1983-06-04 1983-12-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-03 1987-06-04 1987-12-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-03 1991-06-04 1991-12-04 $7700.00 Window Closed / Lapsed

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