US4177160A
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Catalytic components and catalysts for the polymerization of olefins
Assignee: Montedison SpA
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Filing: 1978-11-14
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Granted: 1979-12-04
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Expires: 1998-11-14
Abstract
Abstract There are disclosed new catalysts for the stereospecific polymerization of alpha-olefins having the formula CH 2 ═CHR in which R is an alkyl radical containing from 1 to 4 carbon atoms and the starting components of which comprise (a) a halogenated organometallic Al compound and (b) reduction products of TiCl 4 comprising TiCl 3 in the crystalline beta form.
Inventors
- 👤 Giuliano Cecchin
- 👤 Luciano Luciani
- 👤 Pier Luigi Griselli
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 10:10
CPC Classifications
C; C08; C08F; C08F10/00; Y; Y10; Y10S; Y10S526/00; Y10S526/904
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
215 words
Catalyst-forming components for use in preparing catalysts for polymerization of olefins, said components consisting of a product of the following composition: TiCl.sub.3.(AlR.sub.m X.sub.3-m).sub.a A.sub.p wherein: R is a hydrocarbon radical containing from 1 to 20 carbon atoms; O ≦m≦2.5; X is halogen; a is a number lower than 0.4; A is an ether selected from the group consisting of monoethers of formula R'OR" wherein R' and R" are alkyls containing from 1 to 10 carbon atoms, aryls, cycloalkyls, alkylaryls or aralkyls, and polyethers of the class of polyalkylenglycol-dialkyl-ethers and 1,2-diphenoxyehtane, said ether being capable of forming complexes or coordination products with Al halides or alkyl-Al halides, which complexes or coordination products are soluble in the ether itself or in aromatic or aliphatic hydrocarbons or in the halogenated derivatives thereof; and p is zero or a number greater than zero but lower than 0.5 and said catalyst-forming components being characterized in that, in the X-rays spectrum thereof, diffraction lines apper at the following lattice distances: d=5.4 A (intense line); d=2.75 A (line of medium intensity); d=2.12 A (line of medium to weak intensity); d=1.98 A (very weak line); d=1.77 A (medium line), and in that the surface area thereof is comprised between 2 and 20 m 2 /g and the porosity is lower than 0.1 cc/g.
Claim 2
Dependent Claim
215 words
Catalyst-forming components for use in preparing catalysts for polymerization of olefins, said components consisting of a product of the following composition: TiCl.sub.3.(AlR.sub.m X.sub.3-m).sub.a A.sub.p wherein: R is a hydrocarbon radical containing from 1 to 20 carbon atoms; O ≦m≦2.5; X is halogen; a is a number lower than 0.4; A is an ether selected from the group consisting of monoethers of formula R'OR" wherein R' and R" are alkyls containing from 1 to 10 carbon atoms, aryls, cycloalkyls, alkylaryls or aralkyls, and polyethers of the class of polyalkylenglycol-dialkyl-ethers and 1,2-diphenoxyehtane, said ether being capable of forming complexes or coordination products with Al halides or alkyl-Al halides, which complexes or coordination products are soluble in the ether itself or in aromatic or aliphatic hydrocarbons or in the halogenated derivatives thereof; and p is zero or a number greater than zero but lower than 0.5 and said catalyst-forming components being characterized in that, in the X-rays spectrum thereof, diffraction lines apper at the following lattice distances: d=5.4 A (intense line); d=2.75 A (line of medium intensity); d=2.12 A (line of medium to weak intensity); d=1.98 A (very weak line); d=1.77 A (medium line), and in that the surface area thereof is comprised between 2 and 20 m 2 /g and the porosity is lower than 0.1 cc/g.
Claim 3
Dependent Claim
123 words
The product of claim 1, further characterized in being prepared by the following steps, in the order stated: (I) reduction of TiCl 4 by an organometallic compound of Al having the formula AlRX 2 , AlR 2 X or Al 2 R 3 X 3 in which R is a hydrocarbon radical containing from 1 to 20 carbon atoms and X is halogen, the quantity of Al compound being such that the molar ratio Al/Ti is comprised between 1:1 to 1:5, (II) treatment of the reduction product of step (I), with the mono- or poly-ether defined in claim 1, at a temperature comprised between 70° C. and 120° C; and (III) washing of the product of step (II) with an inert hydrocarbon solvent.
Claim 4
Dependent Claim
165 words
The product of claim 1, further characterized in being prepared by the following steps, in the order stated: (I) reduction of TiCl 4 by an organometallic compound of Al having the formula AlRX 2 , AlR 2 X or Al 2 R 3 X 3 , in which R is a hydrocarbon radical containing from 1 to 20 carbon atoms and X is halogen, the quantity of Al compound being such that the molar ratio Al/Ti is comprised between 1:1 and 1:5; (II) thermal pretreatment of the reduction product of step (I) at a temperature comprised between 60° C. and 90° C. for a time varying with the temperature and comprised between 10 minutes and 5 hours; (III) treatment of the reduction product of step (I), thermally pretreated according to step (II), with the mono- or poly-ether defined in claim 1, at a temperature comprised between 70° C. and 120° C.; and (IV) washing of the product of step (III) with an inert hydrocarbon solvent.
Claim 5
Dependent Claim
98 words
The product of claim 1, further characterized in being prepared by the following steps, in the order stated: (I) reduction of TiCl 4 by an organometallic compound of Al having the formula AlRCl 2 in which R is a hydrocarbon radical containing from 1 to 20 carbon atoms, at a temperature comprised between 10° and 30° C.; (II) treatment of the reduction product of step (I), with the mono- or poly-ether defined in claim 1, at a temperature comprised between 70° and 120° C.; and (III) washing of the product of step (II) with an inert hydrocarbon solvent.
Claim 6
Dependent Claim
37 words
Catalyst-forming components according to claim 1, further characterized in that: R is an alkyl, aryl, cycloalkyl, alkylaryl or aralkyl radical; a is a number lower than 0.2; and p is a number comprised between 0.001 and 0.5.
Claim 7
Dependent Claim
31 words
Catalyst-forming components according to claim 1, in which, in the formula R'OR", R' and R", which are the same or different, are alkyl radicals containing from 4 to 6 carbon atoms.
Claim 8
Dependent Claim
15 words
Catalyst-forming components according to claim 1, characterized in that the monoether is di-n-butylether or di-iso-amylether.
Claim 9
Dependent Claim
51 words
Catalysts for the stereoregular polymerization of alpha-olefins of the formula CH 2 ═CHR wherein R is an alkyl radical containing from 1 to 4 carbon atoms, obtained by bringing into contact starting components comprising (a) dialkyl aluminum halides or alkyl aluminum sesquihalides with (b) catalyst-forming components as defined in claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-12-03 | 1983-06-04 | 1983-12-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-12-03 | 1987-06-04 | 1987-12-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-12-03 | 1991-06-04 | 1991-12-04 | $7700.00 | Window Closed / Lapsed |