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US4177076A Expired / Lapsed US ⏱️ 0.0 years remaining

Water or alcohol soluble printing ink composition

Assignee: Eneos Corp
•
Filing: 1978-04-10
•
Granted: 1979-12-04
•
Expires: 1998-04-10
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Abstract

Abstract A water soluble or alcohol soluble printing ink composition comprising: (A) 10 to 50% by weight of a resin, said resin being prepared by radical - polymerizing a mixture of (a) an unsaturated aromatic hydrocarbon, (b) a monoacrylate or monomethacrylate of a polyhydric alcohol and (c) an A,B- unsaturated carboxylic acid in the presence of an organic solvent, said resin having an acid value of 5 to 150 and a hydroxyl value of 30 to 120; (B) 30 to 80% by weight of a solvent (C) 1 to 40% by weight of a pigment or dye.

Inventors

  • 👤 Hisatake Sato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 09:20
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/04; C08F212/00; C08F212/02; C08F212/04; C08F212/06; C08F222/00; C08F240/00; C09; C09D; C09D125/00; C09D133/00; C09D133/02; C09D133/04; C09D133/14; C08F220/10; C08F220/20

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 127 words
A water soluble or alcohol soluble printing ink composition comprising: (A) 10 to 50% by weight of a resin, said resin being prepared by radical-polymerizing a mixture consisting essentially of (a) an unsaturated aromatic hydrocarbon, (b) a monoacrylate or monomethacrylate of a polyhydric alcohol and (c) an α,β-unsaturated carboxylic acid in the presence of an organic solvent, said resin having an acid value of 5 to 150 and a hydroxyl value of 30 to 120; (B) 30 to 80% by weight of a solvent selected from the group consisting of an alcohol having 1 to 10 carbon atoms, a mixed solvent of alcohol aqueous solution of an alkali and an aqueous solution of an alkali; and (c) 1 to 40% by weight of a pigment or die.
Claim 2
Dependent Claim 127 words
A water soluble or alcohol soluble printing ink composition comprising: (A) 10 to 50% by weight of a resin, said resin being prepared by radical-polymerizing a mixture consisting essentially of (a) an unsaturated aromatic hydrocarbon, (b) a monoacrylate or monomethacrylate of a polyhydric alcohol and (c) an α,β-unsaturated carboxylic acid in the presence of an organic solvent, said resin having an acid value of 5 to 150 and a hydroxyl value of 30 to 120; (B) 30 to 80% by weight of a solvent selected from the group consisting of an alcohol having 1 to 10 carbon atoms, a mixed solvent of alcohol aqueous solution of an alkali and an aqueous solution of an alkali; and (c) 1 to 40% by weight of a pigment or die.
Claim 3
Dependent Claim 21 words
A water soluble printing ink composition according to claim 1, wherein said resin had an acid value of 60 to 150.
Claim 4
Dependent Claim 29 words
An alcohol soluble printing ink composition according to claim 1, wherein said resin has an acid value of 5 to 80 and a hydroxyl value of 30 to 100.
Claim 5
Dependent Claim 56 words
A water soluble or alcohol soluble printing ink composition according to claim 1, 2 or 3, wherein said unsaturated aromatic hydrocarbon is selected from the group consisting of styrene, vinyltoluene, α-methylstyrene and a cracked oil fraction of naphtha which has a boiling point of 140° to 220° C. and which contains styrene, indene and derivatives thereof.
Claim 6
Dependent Claim 54 words
A water soluble or alcohol soluble printing ink composition according to claim 1, 2 or 3, wherein said monoacrylate or monomethacrylate is a monoester prepared from acrylic or methacrylic acid and a polyhydric alcohol selected from the group consisting of ethylene glycol, propylene glycol, butanediol, glycerol, pentaerythritol, diethylene glycol, dipropylene glycol and triethylene glycol.
Claim 7
Dependent Claim 37 words
A water soluble or alcohol soluble printing ink composition according to claim 1, 2 or 3, wherein said α,β-unsaturated carboxylic acid is selected from the group consisting of maleic anhydride, itaconic anhydride, acrylic acid, and methacrylic acid.

References Cited (Backward Citations)

US3661827A Cited
US3655629A Cited
US3764587A Cited
US3887513A Cited
US4013609A Cited
US3951892A Cited
US4028119A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-03 1983-06-04 1983-12-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-03 1987-06-04 1987-12-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-03 1991-06-04 1991-12-04 $7700.00 Window Closed / Lapsed

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