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US4175972A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable epoxy compositions containing aromatic onium salts and hydroxy compounds

Assignee: General Electric Co
•
Filing: 1977-10-06
•
Granted: 1979-11-27
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Expires: 1997-10-06
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Abstract

Abstract Cationic polymerization of epoxy resin materials, such as epoxy monomers or prepolymers, can be achieved by use of certain radiation sensitive aromatic onium salts of Group VIa elements. Curable compositions are provided which can be used as sealants, coating compounds, encapsulants, etc.

Inventors

  • 👤 James V. Crivello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 02:50
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; C; C08; C08F; C08F236/00; C08F236/02; C08F236/04; C08F236/14; C08F236/16; C08G; C08G59/00; C08G59/18; C08G59/68

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 211 words
Photocurable compositions consisting essentially of (A) an epoxy resin polymerizable to a higher molecular weight state containing a hydroxy functional flexibilizer, and (B) from 0.1% to 15% by weight of a radiation sensitive aromatic onium salt of a Group VIa element capable of effecting the cure of (A) by exposure to radiant energy, where the radiation sensitive aromatic onium salt has the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sub.d.sup.+ [MQ.sub.e ].sup.-(e-f), R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical selected from alkyl, cycloalkyl and substituted alkyl, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur, selenium and tellurium, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1 where the sum of a+b+c is a value equal to 3 or the valence of X, d=e-f, f=valence of M and is an integer equal to from 2 to 7 inclusive, e is >f and is an integer having a value up to 8.
Claim 2
Dependent Claim 211 words
Photocurable compositions consisting essentially of (A) an epoxy resin polymerizable to a higher molecular weight state containing a hydroxy functional flexibilizer, and (B) from 0.1% to 15% by weight of a radiation sensitive aromatic onium salt of a Group VIa element capable of effecting the cure of (A) by exposure to radiant energy, where the radiation sensitive aromatic onium salt has the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sub.d.sup.+ [MQ.sub.e ].sup.-(e-f), R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical selected from alkyl, cycloalkyl and substituted alkyl, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur, selenium and tellurium, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1 where the sum of a+b+c is a value equal to 3 or the valence of X, d=e-f, f=valence of M and is an integer equal to from 2 to 7 inclusive, e is >f and is an integer having a value up to 8.
Claim 3
Dependent Claim 16 words
A curable composition in accordance with claim 1, where the onium salt is a sulfonium salt.
Claim 4
Dependent Claim 16 words
A curable composition in accordance with claim 1, where the onium salt is a selenium salt.
Claim 5
Dependent Claim 16 words
A curable composition in accordance with claim 1, where the onium salt is a tellurium salt.
Claim 6
Dependent Claim 18 words
A curable composition in accordance with claim 2, where the sulfonium salt is a dialkyl phenacyl sulfonium salt.
Claim 7
Dependent Claim 13 words
A curable composition in accordance with claim 1, having a sulfonium tetrafluoroborate salt.
Claim 8
Dependent Claim 15 words
A composition in accordance with claim 1, where a mixture of onium salts are employed.
Claim 9
Dependent Claim 16 words
A curable composition in accordance with claim 1, where the flexibilizer is a hydroxy functional polyester.

References Cited (Backward Citations)

US2935488A Cited
US3412046A Cited
US3826650A Cited
US3816280A Cited
US3729313A Cited
US3816281A Cited
US4058400A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-11-26 1983-05-28 1983-11-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-11-26 1987-05-28 1987-11-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-11-26 1991-05-28 1991-11-27 $7700.00 Window Closed / Lapsed

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